光致变色萘并吡喃化合物的拓展π结构研究进展

doi:10.7517/j.issn.1674-0475.2012.02.150

影像科学与光化学 ›› 2012, Vol. 30 ›› Issue (2): 150-158.DOI: 10.7517/j.issn.1674-0475.2012.02.150

• 应用与发展 • 上一篇

光致变色萘并吡喃化合物的拓展π结构研究进展

孟庆华¹, 方永增², 王珍¹, 黄德音¹

1. 上海交通大学化学化工学院, 上海 200240;
2. 合肥乐凯科技产业有限公司, 安徽合肥 230041

收稿日期:2011-11-24 修回日期:2011-12-27 出版日期:2012-03-15 发布日期:2012-03-15
通讯作者: 孟庆华,男(1971-),博士,副教授,研究生导师,研究方向为光化学信息材料及分子探针,E-mail: qhmeng@sjtu.edu.cn.
基金资助:
上海市科委纳米专项资助项目(0752nm016).

The Study of Extended π Conjugation Systems in Photochromic Naphthopyran Compounds

MENG Qing-hua¹, FANG Yong-zeng², WANG Zhen¹, HUANG De-yin¹

1. School of Chemistry and Chemical Engineering, Shanghai Jiaotong University, Shanghai 200240, P.R.China;
2. Hefei Lucky Science & Technology Industry Company Ltd., Hefei 230041, Anhui, P.R.China.

Received:2011-11-24 Revised:2011-12-27 Online:2012-03-15 Published:2012-03-15

摘要/Abstract

摘要： 研究了萘并吡喃的光致变色原理及结构特征,通过萘并吡喃类化合物光致结构互变时的关键化学结构点,分别考察了在萘环上引入含氮推电子基团,在3位苯环上引入含氮推电子基团,在吡喃部位稠合引入金属茂结构,通过碳原子或杂原子桥连的3-位苯环的稠合,对拓展π结构后的萘并吡喃化合物光致变色性能的影响也做了探讨.此外,还考察了引入取代基的共面控制及对共轭体系的影响.

关键词: 萘并吡喃, π结构, 共面, 光致变色

Abstract: The naphthopyrans compounds were structurally modified to extend π conjugation system by introducing N containing donating groups, metallocenyl groups, heterofused groups and thioxanthene groups. The photochromic properties and the conplanarity of substitutes to the main plane were discussed as well.

Key words: naphthopyran, π conjugation, conplanarity, photochromism

中图分类号:

孟庆华, 方永增, 王珍, 黄德音. 光致变色萘并吡喃化合物的拓展π结构研究进展[J]. 影像科学与光化学, 2012, 30(2): 150-158.

MENG Qing-hua, FANG Yong-zeng, WANG Zhen, HUANG De-yin. The Study of Extended π Conjugation Systems in Photochromic Naphthopyran Compounds[J]. Imaging Science and Photochemistry, 2012, 30(2): 150-158.

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光致变色萘并吡喃化合物的拓展π结构研究进展

The Study of Extended π Conjugation Systems in Photochromic Naphthopyran Compounds

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