一种新型芳基硫盐光引发剂的合成及应用

doi:10.7517/j.issn.1674-0475.2015.02.177

影像科学与光化学 ›› 2015, Vol. 33 ›› Issue (2): 177-182.DOI: 10.7517/j.issn.1674-0475.2015.02.177

• 应用与发展 • 上一篇

一种新型芳基硫盐光引发剂的合成及应用

张变香, 郭一力, 杨丽花, 史瑞雪

山西大学化学化工学院, 山西太原 030006

收稿日期:2014-05-20 修回日期:2014-10-31 出版日期:2015-03-15 发布日期:2015-03-15
通讯作者: 张变香
基金资助:
山西省科技基础条件平台建设项目(2013091026)和山西省科技创新化项目(2014101011)资助

Synthesis and Application of Novel Arylsulfonium Salt Photoinitiators

ZHANG Bianxiang, GUO Yili, YANG Lihua, SHI Ruixue

School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, Shanxi, P.R.China

Received:2014-05-20 Revised:2014-10-31 Online:2015-03-15 Published:2015-03-15

摘要/Abstract

摘要：

将二苯二硫醚作为硫源与1-甲基-2-苯基吲哚反应合成了含杂原子环的硫醚类化合物,然后再与二芳基碘三氟甲磺酸盐反应,合成了一种新的芳基硫盐.采用¹HNMR、MS等技术对目标化合物进行了表征,并确定了最佳反应条件.在硫醚类化合物与二芳基碘三氟甲磺酸盐的摩尔比为1:1.2,催化剂为CuI/Cu,溶剂为1, 1, 2, 2-四氯乙烷的反应条件下,目标化合物的产率达到了62.0%.同时,对这类结构的芳基硫盐进行了紫外光固化性能测试,发现其能够在紫外光固化体系中作为阳离子光引发剂得到应用.

关键词: 光引发剂, 芳基硫盐, 二芳基碘三氟甲磺酸盐

Abstract:

A new kind of aryl sulfonium salts were prepared by diphenyliodonium triflate with thioether compounds which have been synthesized by reaction of diphenyl disulfide ether with 1-methyl-2-phenyl indole. The compounds are characterized by ¹HNMR and ESI TOF-MS. In addition, the optimum reaction conditions were determined. The yield of the product was up to 62% in 1,1,2,2- tetrachloroethane solvent under CuI / Cu as the catalysts, in molar ratio of 1:1.2 of thioether compounds to diphenyliodonium triflate. Further, the optical performance test of the aryl sulfur salts show that they can be applied as cationic photoinitiators in UV-curing system.

Key words: photoinitiators, aryl sulfonium salts, diaryliodonium triflate

张变香, 郭一力, 杨丽花, 史瑞雪. 一种新型芳基硫盐光引发剂的合成及应用[J]. 影像科学与光化学, 2015, 33(2): 177-182.

ZHANG Bianxiang, GUO Yili, YANG Lihua, SHI Ruixue. Synthesis and Application of Novel Arylsulfonium Salt Photoinitiators[J]. Imaging Science and Photochemistry, 2015, 33(2): 177-182.

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一种新型芳基硫盐光引发剂的合成及应用

Synthesis and Application of Novel Arylsulfonium Salt Photoinitiators

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