光触发自修复聚合物研究进展

doi:10.7517/j.issn.1674-0475.2017.01.034

摘要/Abstract

摘要：

近几年，由于光触发自修复聚合物具有可控快速等优势，其在自修复聚合物领域中占据了重要的地位。光触发自修复聚合物实现自修复的方法主要分为3类，分别是基于光交联反应的自修复、基于光触发交换反应的自修复和基于光热效应的自修复。本文主要从光触发自修复聚合物的修复机制以及修复过程中涉及的化学本质两个方面，重点阐述了上述3类光触发自修复方法的最新研究进展，强调3种光触发自修复之间的联系和共同点。同时，对光触发自修复聚合物未来的发展前景进行了展望。

关键词: 光触发, 自修复, 聚合物

Abstract:

In recent years, light-triggered self-healing polymer has played an important role due to the controllable and fast ability to self-repair. It has three methods to achieve self-healing for light-triggered self-healing polymer:self-healing based on a photo-crosslinking reaction, self-healing based on a photo-triggered metathesis reaction and self-healing based on the photo-thermal effect. In this reiview, we highlight the recent progress made in light-controlled self-healing. We analyse the materials design, underlying mechanisms and chemistries involved in the different methods developed for this types of emerging photo-responsive materials. We also demonstrate the relationship and similarity between the three metheds. Possible future developments and perspectives of using light as a unique trigger for polymer self-healing is also discussed.

Key words: Light-triggered, self-healing, polymers

高菲, 曹建诚, 刘敬成, 刘仁, 袁妍, 李治全, 刘晓亚. 光触发自修复聚合物研究进展[J]. 影像科学与光化学, 2017, 35(1): 34-45.

GAO Fei, CAO Jiancheng, LIU Jingcheng, LIU Ren, YUAN Yan, LI Zhiquan, LIU Xiaoya. Research Progress of the Light-triggered Self-healing Polymers[J]. Imaging Science and Photochemistry, 2017, 35(1): 34-45.

参考文献

[1] Jud K, Kausch H H, Williams J G. Fracture mechanics studies of crack healing and welding of polymers[J]. Journal of Materials Science, 1981,16(1):204-210.
[2] Heaton T H. Evidence for and implications of self-healing pulses of slip in earthquake rupture[J]. Physics of the Earth and Planetary Interiors, 1990,64(1):1-20.
[3] Hastings G W, Mahmud F A. Intelligent orthopaedic materials[J]. Journal of Intelligent Material Systems and Structures, 1993,4(4):452-456.
[4] White S R, Sottos N R, Geubelle P H, Moore J S, Kessler M R, Sriram S R, Brown E N, Viswanathan S. Autonomic healing of polymer composites[J]. Nature, 2001,409(6822):794-797.
[5] Williams G, Trask R S, Bond I P.A self-healing carbon fibre reinforced polymer for aerospace applications[J]. Composites, Part A:Applied Science and Manufacturing, 2007,38:1525-1532.
[6] Trask R S, Williams H R, Bond I P. Self-healing polymer composites:mimicking nature to enhance performance[J]. Bioinspiration & Biomimetics, 2007,2(1):1-9.
[7] Trask R S, Williams G J, Bond I P. Bioinspired self-healing of advanced composite structures using hollow glass fibres[J]. Journal of the Royal Society Interface, 2007,4(13):363-371.
[8] Toohey K S, Sottos N R, Lewis J A, Moore J S, White S R. Self-healing materials with microvascular networks[J]. Nature Materials, 2007,6(8):581-585.
[9] Hansen C J, Wu W, Toohey K S,Sottos N R, White S R, Lewis J A. Self-healing materials with interpenetrating microvascular networks[J]. Advanced Materials, 2009,21(41):4143-4147.
[10] Toohey K S, Hansen C J, Lewis J A, Moore J S, White S R. Delivery of two-part self-healing chemistry via microvascular networks[J]. Advanced Functional Materials, 2009,19(9):1399-1405.
[11] Liu Y L, Chuo T W. Self-healing polymers based on thermally reversible Diels-Alder chemistry[J]. Polymer Chemistry, 2013,4(7):2194-2205.
[12] Dohler D, Zare P, Binder W H. Hyperbranched polyisobutylenes for self-healing polymers[J]. Polymer Chemistry, 2014,5(3):992-1000.
[13] Pepels M, Filot I, Klumperman B, Goossens H. Self-healing systems based on disulfide-thiol exchange reactions[J].Polymer Chemistry, 2013,4(18):4955-4965.
[14] 杨小熠, 刘敬成, 袁妍, 刘仁, 刘晓亚. 自修复型光固化树脂的制备及其应用研究[J].涂料工业, 2016,46(6):1-5.Yang X Y, Liu J C, Yuan Y, Liu R, Liu X Y. Synthesis and application of UV curable self-healing resin[J]. Paint & Coating Industry, 2016,46(6):1-5.
[15] Varley R J, Shen S, van der Zwaag S. The effect of cluster plasticisation on the self healing behaviour of ionomers[J]. Polymer, 2010,51(3):679-686.
[16] Brunsveld L, Folmer B J B, Meijer E W, Sijbesma R P. Supramolecular polymers[J]. Chemical Reviews, 2001,101(12):4071-4098.
[17] 李思超, 韩朋, 许华平. 自修复高分子材料[J]. 化学进展, 2012,24(7):1346-1352.Li S C, Han P, Xu H P. Self-healing polymeric materials[J]. Progress in Chemistry, 2012,24(7):1346-1352.
[18] Wang W, Xu L K, Li X B, Lin Z F, Yang Y, AN E P. Self-healing mechanisms of water triggered smart coating in seawater[J]. Journal of Materials Chemistry A, 2014,2(6):1914-1921.
[19] Pianowski Z L, Karcher J, Schneider K. Photoresponsive self-healing supramolecular hydrogels for light-induced release of DNA and doxorubicin[J]. Chemical Communications, 2016,52(15):3143-3146.
[20] Yu C, Wang C F, Chen S. Robust self-healing host-guest gels from magnetocaloric radical polymerization[J]. Advanced Functional Materials, 2014,24(9):1235-1242.
[21] Lin Y L, Li G.J. An intermolecular quadruple hydrogen-bonding strategy to fabricate self-healing and highly deformable polyurethane hydrogels[J]. Journal of Materials Chemistry B, 2014,2(39):6878-6885.
[22] Ji S, Cao W, Yu Y, Xu H P. Visible-light-induced self-healing diselenide-containing polyurethane elastomer[J]. Advanced Materials, 2015,27(47):7740-7745.
[23] Habault D, Zhang H J, Zhao Y. Light-triggered self-healing and shape-memory polymers[J]. Chemical Society Reviews, 2013,42(17):7244-7256.
[24] Chung C M, Roh Y S, Cho S Y, Kim J G. Crack healing in polymeric materials via photochemical[2+2] cycloaddition[J]. Chemistry of Materials, 2004,16(21):3982-3984.
[25] Oya N, Sukarsaatmadja P, Ishida K, Yoshie N. Photoinduced mendable network polymer from poly (butylene adipate) end-functionalized with cinnamoyl groups[J]. Polymer Journal, 2012,44(7):724-729.
[26] Hu L, Cheng X, Zhang A. A facile method to prepare UV light-triggered self-healing polyphosphazenes[J]. Journal of Materials Science, 2015,50(5):2239-2246.
[27] Ling J, Rong M Z, Zhang M Q. Coumarin imparts repeated photochemical remendability to polyurethane[J]. Journal of Materials Chemistry, 2011,21(45):18373-18380.
[28] Banerjee S, Tripathy R, Cozzens D, Nagy T, Keki S, Zsuga M, Fauft R. Photoinduced smart, self-healing polymer sealant for photovoltaics[J]. ACS Applied Materials & Interfaces, 2015,7(3):2064-2072.
[29] Froimowicz P, Frey H, Landfester K. Towards the generation of self-healing materials by means of a reversible photo-induced approach[J]. Macromolecular Rapid Communications, 2011,32(5):468-473.
[30] Radl S, Kreimer M, Griesser T. Oesterreicher A, Moser A, Kern W, Schlogl S. New strategies towards reversible and mendable epoxy based materials employing[4πs+4πs] photocycloaddition and thermal cycloreversion of pendant anthracene groups[J]. Polymer, 2015,80:76-87.
[31] Ghosh B, Urban M W. Self-repairing oxetane-substituted chitosan polyurethane networks[J]. Science, 2009,323(5920):1458-1460.
[32] Li R, Chen J Q, Zhou T S, Pei J Z. Preparation and characterization of novel light induced self-healing materials for cracks in asphalt pavements[J]. Construction and Building Materials, 2016,105:336-342.
[33] Amamoto Y, Kamada J, Otsuka H, Takahara A, Matyjaszewski K. Repeatable photoinduced self-healing of covalently cross-linked polymers through reshuffling of trithiocarbonate units[J]. Angewandte Chemie, 2011,123(7):1698-1701.
[34] Bowman C N, Kloxin C J. Covalent adaptable networks:reversible bond structures incorporated in polymer networks[J]. Angewandte Chemie International Edition, 2012,51(18):4272-4274.
[35] Amamoto Y, Otsuka H, Takahara A, Matyjaszewski K. Self-healing of covalently cross-linked polymers by reshuffling thiuram disulfide moieties in air under visible light[J]. Advanced Materials, 2012,24(29):3975-3980.
[36] Michal B T, Jaye C A, Spencer E J, Rowan S J. Inherently photohealable and thermal shape-memory polydisulfide networks[J]. ACS Macro Letters, 2013,2(8):694-699.
[37] Burnworth M, Tang L, Kumpfer J R, Duncan A J, Beyer F L, Fiore G L, Rowan S J, Weder C. Optically healable supramolecular polymers[J]. Nature, 2011,472(7343):334-337.
[38] Borre E, Stumbe J F, Bellemin-Laponnaz S, Mauro M. Light-powered self-healable metallosupramolecular soft actuators[J]. Angewandte Chemie International Edition, 2016,55(4):1313-1317.
[39] Kang H S, Kim H T, Park J K, Lee S. Light-powered healing of a wearable electrical conductor[J]. Advanced Functional Materials, 2014,24(46):7273-7283.
[40] Cao Z X, Wang R G, Hao L F, Jiao W C, Yang F, Wang Q, Liu W B, Zhang B Y, Lu X L, He X D. Interfacial healing of carbon fiber composites in the presence of gold nanoparticles as localized "nano-heaters"[J]. RSC Advances, 2015,5(8):5680-5685.
[41] Cao Z X, Wang R G, Yang F, Hao L F, Jiao W C, Liu W B, Zhang B Y. Photothermal healing of a glass fiber reinforced composite interface by gold nanoparticles[J]. RSC Advances, 2015,5(124):102167-102172.
[42] Peng P, Zhang B Y, Cao Z X, Hao L F, Yang F, Jiao W C, Liu W B, Wang R G. Photothermally induced scratch healing effects of thermoplastic nanocomposites with gold nanoparticles[J]. Composites Science and Technology, 2016,133:165-172.
[43] Xiong S, Wang Y, Zhu J, Yu J R, Hu Z M. Poly (ε-caprolactone)-grafted polydopamine particles for biocomposites with near-infrared light triggered self-healing ability[J]. Polymer, 2016,84:328-335.
[44] Kim J T, Kim B K, Kim E Y, Kwon S H, Jeong H M. Synthesis and properties of near IR induced self-healable polyurethane/graphene nanocomposites[J]. European Polymer Journal, 2013,49(12):3889-3896.
[45] Yang Y, Pei Z, Zhang X, Tao L, Wei Y, Ji Y. Carbon nanotube-vitrimer composite for facile and efficient photo-welding of epoxy[J]. Chemical Science, 2014,5(9):3486-3492.
[46] Hia I L, Vahedi V, Pasbakhsh P. Self-healing polymer composites:prospects, challenges, and applications[J]. Polymer Reviews, 2016,56(2):225-261.
[47] Van Tittelboom K, De Belie N. Self-healing in cementitious materials-A review[J]. Materials, 2013,6(6):2182-2217.
[48] Altuna F I, Antonacci J, Arenas G F, Pettarin V. Hoppe C E, Williams R J J. Photothermal triggering of self-healing processes applied to the reparation of bio-based polymer networks[J]. Materials Research Express, 2016,3(4):045003.
[49] Dai X, Zhang Y, Gao L, Bai T, Wang W, Cui Y L, Liu W G. A mechanically strong, highly stable, thermoplastic, and self-healable supramolecular polymer hydrogel[J]. Advanced Materials, 2015,27(23):3566-3571.
[50] Guo M, Pitet L M, Wyss H M, Vos M, Dankers P, Meijer E W. Tough stimuli-responsive supramolecular hydrogels with hydrogen-bonding network junctions[J]. Journal of the American Chemical Society, 2014,136(19):6969-6977.