卟啉降冰片烯聚合物的合成、表征及性质研究

doi:10.7517/j.issn.1674-0475.2012.06.429

影像科学与光化学 ›› 2012, Vol. 30 ›› Issue (6): 429-437.DOI: 10.7517/j.issn.1674-0475.2012.06.429

卟啉降冰片烯聚合物的合成、表征及性质研究

李辉^1,2, 冯科², 周力¹, 陈彬², 张丽萍², 佟振合², 吴骊珠²

1. 南昌大学化学系,江西南昌 330000;
2. 中国科学院理化技术研究所光化学转换与功能材料重点实验室, 北京 100190

收稿日期:2012-05-15 修回日期:2012-06-02 出版日期:2012-11-15 发布日期:2012-11-15
通讯作者: 冯科, 周力, 吴骊珠
基金资助:
科技部国家重点基础研究发展规划项目(2009CB220008,2013CB8343505);国家自然科学基金资助项目(21002108,91027041,20973189,21090343,50973125);中国科学院知识创新工程太阳能行动计划资助项目.

Syntheses, Characterization and Property Studies on Porphyrinic Polynorbornenes

LI Hui^1,2, FENG Ke², ZHOU Li¹, CHEN Bin², ZHANG Li-ping², TONG Zheng-he(TUNG Chen-ho)², WU Li-zhu²

1. Department of Chemistry, Nanchang University, Nanchang 330000, Jiangxi, P. R. China;
2. Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

Received:2012-05-15 Revised:2012-06-02 Online:2012-11-15 Published:2012-11-15

摘要/Abstract

摘要： 本文设计合成了卟啉的降冰片烯单体,采用Grubbs催化剂与长链烷基的降冰片烯单体开环易位聚合,直接得到了卟啉降冰片烯聚合物,通过紫外-可见吸收光谱、荧光光谱、电化学等手段研究了卟啉降冰片烯聚合物的性质,与小分子单体相比,所得卟啉高分子共聚物相当好地保持了卟啉应有的光物理、电化学等特性.

关键词: 卟啉, 降冰片烯聚合物, 开环易位聚合

Abstract: Porphyrinic and long-chain alkyl norbornene monomers have been designed and synthesized, and copolymers were obtained via ROMP (ring-opening metathesis polymerization) using a Grubbs' initiator. The properties of porphyrinic polynorbornenes have been investigated by UV-Vis absorption spectroscopy, steady-state fluorescence spectroscopy, lifetime measurements and electrochemistry. The copolymers exhibit almost identical characteristics as well as porphyrinic monomers in photophysics and electrochemistry.

Key words: porphyrin, polynorbornenes, ring-opening metathesis polymerization

中图分类号:

李辉, 冯科, 周力, 陈彬, 张丽萍, 佟振合, 吴骊珠. 卟啉降冰片烯聚合物的合成、表征及性质研究[J]. 影像科学与光化学, 2012, 30(6): 429-437.

LI Hui, FENG Ke, ZHOU Li, CHEN Bin, ZHANG Li-ping, TONG Zheng-he(TUNG Chen-ho), WU Li-zhu. Syntheses, Characterization and Property Studies on Porphyrinic Polynorbornenes[J]. Imaging Science and Photochemistry, 2012, 30(6): 429-437.

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卟啉降冰片烯聚合物的合成、表征及性质研究

Syntheses, Characterization and Property Studies on Porphyrinic Polynorbornenes

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