聚-4-偶氮磺酸基苯乙烯与四-(三甲氨基苯基)-卟啉的自组装膜及其光电转换性能

doi:10.7517/j.issn.1674-0475.2007.02.136

影像科学与光化学 ›› 2007, Vol. 25 ›› Issue (2): 136-141.DOI: 10.7517/j.issn.1674-0475.2007.02.136

聚-4-偶氮磺酸基苯乙烯与四-(三甲氨基苯基)-卟啉的自组装膜及其光电转换性能

杨朝晖, 张茂峰, 曹维孝

北京大学, 化学与分子工程学院, 教育部高分子化学与物理重点实验室, 北京, 100871

收稿日期:2006-09-14 修回日期:2006-11-03 出版日期:2007-03-23 发布日期:2007-03-23
通讯作者: 曹维孝,E-mail:wxcao@pku.edu.cn.
基金资助:
国家自然科学基金资助项目(90406018)

Self-Assembly Films of Poly(Diazosulfonate Styrene)/Tetra-Trimethylamino-Porphyrin and Their Photoelectron Conversion Properties

YANG Zhao-hui, ZHANG Mao-feng, CAO Wei-xiao

The Key lab of Polymer Chemistry and Physics of the Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Received:2006-09-14 Revised:2006-11-03 Online:2007-03-23 Published:2007-03-23

摘要/Abstract

摘要： 聚-4-重氮基苯乙烯(PDS)在碱性水溶液下通过与Na₂SO₃反应,制备了聚-4-偶氮磺酸基苯乙烯(PDSS).作为负离子聚电解质PDSS能与四-(三甲氨基苯基)-卟啉(TTMAP)通过离子相互作用进行层-层自组装.光照下该组装膜中的离子键转变为共价键,结果是组装膜对极性溶剂和盐水溶液变为非常稳定,从而能直接在KCl水溶液中测定其光电流.结果表明,该组装膜具有良好的光电转换性质.

关键词: 聚-4-偶氮磺酸基苯乙烯, 四-(三甲氨基苯基)-卟啉, 自组装, 光电转换

Abstract: Poly(diazosulfonate styrene)(PDSS) was synthesized with reaction of poly(diazonium styrene)(PDS) and Na₂SO₃ in an alkali aqueous solution.As an anionic polyelectrolyte PDSS can self-assemble(SA) with tetra-trimethylaminophenylporphyrin(TTMAP) layer-by-layer via ionic interaction. Under UV irradiation the ionic bonds of the film convert into covalent bonds resulting in the film becoming very stable towards polar solvents or salty aqueous solutions and can determine its photocurrent directly in KCl aqueous solution.The results show that the film possesses good photoelectron conversion properties.

Key words: poly(diazo-sulfonate styrene), tetra-trimethylaminophenylporphyrin, self-assemble, photo-electron conversion

中图分类号:

杨朝晖, 张茂峰, 曹维孝. 聚-4-偶氮磺酸基苯乙烯与四-(三甲氨基苯基)-卟啉的自组装膜及其光电转换性能[J]. 影像科学与光化学, 2007, 25(2): 136-141.

YANG Zhao-hui, ZHANG Mao-feng, CAO Wei-xiao. Self-Assembly Films of Poly(Diazosulfonate Styrene)/Tetra-Trimethylamino-Porphyrin and Their Photoelectron Conversion Properties[J]. Imaging Science and Photochemistry, 2007, 25(2): 136-141.

参考文献

[1] 黄春辉,李富友,黄岩谊.光电功能超薄膜[M].北京:北京大学出版社,2001.Huang C H,Li F Y,Huang Y Y.Photoelectron Functional Ultra-thin Films[M].Beijing:Peking University Press,2001.
[2] Enger O,Nuesch F,Fibbioli M,et al.Photocurrent generation at a fullerene self-assembled monolayer-modified gold electrode cast with a polyurethane membrane[J].J.Mater.Chem.,2000,10:2231.
[3] Choi H G,Min J H,Han K K,et al.Photoelectric conversion of bacteriorhodopsin films fabricated by self-assembly technique[J].Synth.Met.,2001,117:141.
[4] Zhang S,Dong D,Gan L B,et al.Photoelectric response of a gold dectrode modified with self-assembled monolayers of pyrrolidinofullerenes[J].New J.Chem.,2001,25:606.
[5] Baur J W,Durstock M F,Taylor B E,et al.Photovoltaic interface modification via electrostatic self-assembly[J].Synth.Met.,2001,121:1547.
[6] Durstock M F,Taylor B,Spry R J,et al.Electrostatic self-assembly as a means to create organic photovoltaic devices[J].Synth.Met.,2001,116:373.
[7] Cao T B,Yang S M,Cao J,et al.Nanoassembly film of carboxylic polyaniline with photosensitive diazoresin and its photoelectric conversion properties[J].J.Phys.Chem.B,2001,105:11941.
[8] Cao T B,Yang S M,Yang Y L,et al.Photoelectric conversion property of covalent-attached multilayer self-assembled films fabricated from diazoresin and fullerol[J].Langmuir,2001,17:6034.
[9] 张晶,王晓工.聚苯乙烯基偶氮聚合物的合成研究[J].高分子学报2002,2:180.Zhang J,Wang X G.Synthesis and characterization of polystyrene based on azo polymers[J].Acta Polymerica Sinica,2002,2:180.
[10] Yang Z H,Cao W X.Self-assemblies based on poly (4-diazonium styrene)[J].Macromol.Chem.Phys.,2004,205:241.
[11] Nuyken O,Voit B.The photoactive diazosulfonate group and its role in polymer chemistry[J].Macromol.Chem.Phys.,1997,198:2337.
[12] Patai S.The Chemistry of Diazonium and Diazo Group[M].New York:Wiley & Sons,1978.
[13] 罗嗥,曹维孝.二苯胺-4-偶氮磺酸盐及其树脂的制备和光、热分解性质[J].感光科学与光化学,2003,21:30.Luo H,Cao W X.Preparation of diphenylamine-4-diazosulfonate,diazosufonate resins and their photochemical,thermal decomposition[J].Photographic Science and Photochemistry,2003,21:30.

[1]	李冰, 李海波, Mark Neisser, Caleb L. Breaux, Clifford L. Henderson. 用于大分子定向自组装的新型嵌段共聚物的合成与表征[J]. 影像科学与光化学, 2018, 36(4): 306-314.
[2]	柏宇豪, 谭剑波, 张力. 水相光引发聚合诱导自组装制备嵌段共聚物纳米材料[J]. 影像科学与光化学, 2017, 35(6): 816-823.
[3]	张雪超, 谭剑波, 张力. 水相光引发聚合诱导自组装制备CO₂响应性聚合物囊泡[J]. 影像科学与光化学, 2017, 35(6): 833-842.
[4]	孟海凤, 张俊超, 叶冯俊, 张可佳, 赫英威, 张碧丰, 蔡川, 熊利民. 新型太阳电池光电转换效率测量技术研究进展[J]. 影像科学与光化学, 2016, 34(5): 389-401.
[5]	李莉, 鲁峰, 杨武. 银纳米微球和银纳米棒自组装膜的制备及SERS研究[J]. 影像科学与光化学, 2016, 34(4): 329-335.
[6]	万堂庆, 黎占亭. 从超分子聚合物到超分子有机框架:组装溶液相超分子结构的周期性[J]. 影像科学与光化学, 2015, 33(1): 3-14.
[7]	王安东, 阎云, 黄建滨. 光化学在自组装结构调控与探测中的应用[J]. 影像科学与光化学, 2015, 33(1): 15-27.
[8]	王秀凤, 杨东, 刘鸣华. 超分子凝胶中的光化学反应[J]. 影像科学与光化学, 2015, 33(1): 49-66.
[9]	马莹, 鱼春萌, 刘科, 蔡秀琴, 张少飞, 房喻. 杯[4]芳烃的表面化学组装及其在气态四氢呋喃荧光传感薄膜创制中的应用[J]. 影像科学与光化学, 2015, 33(1): 67-76.
[10]	李海洋, 张敬波, 魏刚, 孙丽娜, 林原, 付国柱. 电沉积法制备固态染料敏化太阳能电池[J]. 影像科学与光化学, 2014, 32(6): 514-522.
[11]	刘占芳, 宋恺, 佟振合. 胶体光子晶体的平面介电常数缺陷[J]. 影像科学与光化学, 2013, 31(6): 401-410.
[12]	李海霞, 高云燕, 欧植泽, 金和林, 曹璐, 陈晨. PMADQUAT/PSt-PAA聚离子复合物聚集体增强卟啉和富勒烯类衍生物单重态氧产率[J]. 影像科学与光化学, 2013, 31(3): 197-207.
[13]	王飞, 丁可伟, 吴飞鹏. 水体系中含卟啉基团的两亲高分子的自组装行为和性质的研究[J]. 影像科学与光化学, 2011, 29(5): 389-397.
[14]	王维康, 郑美玲, 赵震声, 段宣明. 酸碱度对金纳米结构形貌的调控及其机理研究[J]. 影像科学与光化学, 2011, 29(3): 203-211.
[15]	陈学成, 王航, 张珅, 何溥, 贺军辉. 柔软的球状和长方体状氧化硅中空结构的制备研究[J]. 影像科学与光化学, 2010, 28(1): 59-64.

聚-4-偶氮磺酸基苯乙烯与四-(三甲氨基苯基)-卟啉的自组装膜及其光电转换性能

Self-Assembly Films of Poly(Diazosulfonate Styrene)/Tetra-Trimethylamino-Porphyrin and Their Photoelectron Conversion Properties

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价