影像科学与光化学 ›› 2006, Vol. 24 ›› Issue (5): 321-324.DOI: 10.7517/j.issn.1674-0475.2006.05.321

• 研究快讯 •    下一篇

Et3N·Mo(CO)5催化取代2,3-二氢呋喃衍生物的合成

陈玉哲, 吴骊珠, 张丽萍, 佟振合   

  1. 中国科学院, 理化技术研究所, 超分子光化学实验室, 北京, 100080
  • 收稿日期:2006-06-20 修回日期:2006-07-05 出版日期:2006-09-23 发布日期:2006-09-23
  • 通讯作者: 吴骊珠,E-mail:lzwu@mail.ipc.ac.cn;佟振合,E-mail:chtung@mail.ipc.ac.cn.
  • 基金资助:
    科技部国家重点基础研究发展规划项目(2003CB7168022004CB719903);国家自然科学基金资助项目(20125207,20333080,20332040);中科院基础局资助项目(KJCX2-SW-H15)

Synthesis of 2,3-Dihydrofuran Derivatives by Et3N·Mo(CO)5 Catalyst

CHEN Yu-zhe, WU Li-zhu, ZHANG Li-ping, TONG Zhen-he(TUNG Chen-ho)   

  1. Laboratory of Supramolecular Photochemistry, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100080, P. R. China
  • Received:2006-06-20 Revised:2006-07-05 Online:2006-09-23 Published:2006-09-23

摘要: 利用McDonald方法,制备了2-戊基-、2-(对-甲基)苯基-以及2-甲基-2-苯基-取代2,3-二氢呋喃化合物.实验表明,此种方法反应条件温和,后处理简单,适用范围广,可用以合成大量环内烯醇醚.

关键词: Et3N·Mo(CO)5, 2,3-二氢呋喃, McDonald方法

Abstract: 2-Pentyl-,2-(p-methyl-phenyl)-,and 2-methyl-2-phenyl-2,3-dihydrofurans were successfully prepared by using Et3N·Mo(CO)5 catalyst.The condition of the reaction is mild,the work-up is simple.This method can be applied to the synthesis of a large number of endocyclic enol ethers.

Key words: Et3N·Mo(CO)5, 2,3-dihydrofuran, McDonald method

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