改善高氯卤化银乳剂的高照度性能

doi:10.7517/j.issn.1674-0475.2003.02.107

影像科学与光化学 ›› 2003, Vol. 21 ›› Issue (2): 107-113.DOI: 10.7517/j.issn.1674-0475.2003.02.107

改善高氯卤化银乳剂的高照度性能

杨晓玲, 庄思永

华东理工大学, 影像技术联合研究所, 上海, 200237

收稿日期:2002-10-27 修回日期:2002-11-19 出版日期:2003-03-23 发布日期:2003-03-23
通讯作者: 杨晓玲(1973- ),女,华东理工大学化学与制药学院工程硕士研究生,中国乐凯胶片集团公司工程师,通讯联系人.
基金资助:
国家自然科学基金资助项目(20073013)

IMPROVEMENT OF PHOTOGRAPHIC PROPERTIES UNDER HIGH INTENSITY EXPOSURE IN HIGH CHLORIDE EMULSIONS

YANG Xiao-ling, ZHUANG Si-yong

The Combined Research Institute of Imaging Technology, East ChinaUniversity of Science and Technology, Shanghai, 200237, P. R. China

Received:2002-10-27 Revised:2002-11-19 Online:2003-03-23 Published:2003-03-23

摘要/Abstract

摘要： 本实验制备了高氯卤化银立方体系列乳剂和高氯卤化银(100)晶面T颗粒乳剂,对高氯卤化银立方体乳剂进行了不同种类掺杂剂的掺杂试验.通过测定以上各乳剂在常规曝光和高照度曝光下的照相性能,表明了在高氯卤化银乳剂中掺杂碘化物、掺杂铱络合物和掺杂浅电子陷阱掺杂剂都可以不同程度地改善乳剂的高照度性能,几种改进措施的结合效果更好.

关键词: 高氯卤化银乳剂, (100)晶面T颗粒, 高照度性能, 掺杂

Abstract: A series of high chloride cubic emulsions and a high chloride (100) tabular emusion were prepared and the high chloride cubic grains were doped with different dopants,iodide,(NH₄)₂IrCl₆ and K₄Fe(CN)₆,respectively.The photographic properties of these emulsions under normal exposure and high intensity exposure indicated that the photographic properties under high intensity exposure could be improved to varying contents by doping with iodide,or iridium coordination complex,or a shallow electron trapping dopant.The combination of the above methods worked more effectively.

Key words: high chloride emulsion, (100) tabular emulsion, high intensity exposure, doping

中图分类号:

TQ57

杨晓玲, 庄思永. 改善高氯卤化银乳剂的高照度性能[J]. 影像科学与光化学, 2003, 21(2): 107-113.

YANG Xiao-ling, ZHUANG Si-yong. IMPROVEMENT OF PHOTOGRAPHIC PROPERTIES UNDER HIGH INTENSITY EXPOSURE IN HIGH CHLORIDE EMULSIONS[J]. Imaging Science and Photochemistry, 2003, 21(2): 107-113.

参考文献

[1] Budz J A,Ligtenberg J K,Roberts M R,et al.Digital imaging with tabular grain emulsions[P].US patent,5 451 490.1995-09-19.
[2] 姚林辉,李振兴,唐大刚,等.碘含量对立方体卤化银乳剂感光性能和离子性能的影响[J].感光科学与光化学,1999,17(2):104-109.Yao L H,Li Z X,Tang D G,et al.The effects of iodide content on photographic and ionic properties of silver halide cubic microcrystals[J].Photographic Science and Photochemistry,1999,17(2):104-109.
[3] Carroll B H.Iridium sensitization:A literature review[J].Photogr.Sci.Eng.,1980,24(6):265-267.
[4] Bryant R A,Olm M T,Fenton D E,et al.Photographic emulsions of enhanced sensitivity[P].US patent,5 728 517.1998-05-17.
[5] Mydlarz J Z,Budz J A,Bell E L.Digital imaging with high chloride emulsions[P].US patent,5 783 373.1998-07-21.
[6] 王瑞.数码相纸发展动态[J].感光材料信息月报,2001,(8):6-9.Wang R.Development of digital imaging paper[J].Information of Photosensitive Materials Monthly Report,2001,(8):6-9.
[7] 邹竞.{100}高氯化银T颗粒乳剂[J].感光材料,1999,(2):10-13.Zou J.{100}High chloride tabular emulsion[J].Photosensitive Material,1999,(2):10-13.
[8] Saito M C.Process for the preparation of silver halide emulsion[P].EP patent,0 670 515A2.1995-09-06.
[9] Oyamada T,Shiozawa T,Yamashita S.Anisotropic growth and screw dislocation of {100} tabular grains[C].International Symposium on Silver Halide Imaging:Recent Advances and Future Opportunities in Silver Halide Imaging.Canada:British Columbia,1997.2-7.
[10] Chang Y C,Metha R V,Buitano L A.High chloride (100) tabular grain emulsions containing large,thin tabular grains and a process for their preparation[P].US patent,5 663 041.1997-09-02.
[11] Seiji Y.Silver halide emulsion and photographic material using the same[P].US patent,5 565 315.1996-10-15.
[12] Slagt M.Effect of iridium doping in cubic and octahedral AgBr grains on the latent formation process[C].International Symposium on Silver Halide Imaging:Silver Halide in a New Millennium.Canada:Quebec,2000.221-226.
[13] House G L,Brust T B,Hartsell D L.High chloride tabular grain emulsions and processes for their preparation[P].US patent,5 320 938.1994-04-14.
[14] 梁冰.照相乳剂中浅电子陷阱掺杂剂的掺杂(硕士论文)[D].上海:华东理工大学,2001.Liang B.Doping of shallow electron trapping dopants in photosensitive emulsions (Master Thesis)[D].Shanghai:East China University of Science and Technology,2001.

[1]	马逸骅, 陈琳, 杨永珍, 于世平, 苏秀琴. 钆掺杂碳量子点的制备及其双模态成像研究进展[J]. 影像科学与光化学, 2020, 38(5): 763-770.
[2]	邱申保, 王素敏, 王奇观, 尚嘉茵, 张文治, 杨磊, 樊亚茹. 水溶性氮掺杂石墨烯量子点的合成及其对Pb²⁺的选择性识别研究[J]. 影像科学与光化学, 2018, 36(1): 108-116.
[3]	陈文铖, 李振声, 佟庆笑. 不对称刚性扭曲菲并咪唑分子的设计合成及其深蓝电致发光性能研究[J]. 影像科学与光化学, 2017, 35(5): 720-728.
[4]	聂坤, 杨汉培, 孙慧华, 崔素珍, 吴俊明. 新型Fe掺杂钙钛矿型KMgF₃光催化剂制备及性能[J]. 影像科学与光化学, 2017, 35(1): 61-69.
[5]	王勐, 夏静, 朱丹丹, 王磊, 孟祥敏. Fe掺杂ZnO空心微球的制备与光催化性能[J]. 影像科学与光化学, 2016, 34(3): 245-251.
[6]	洪星星, 康向东, 刘岗, 成会明. 原位聚合碳掺杂改性石墨态氮化碳光催化活性研究[J]. 影像科学与光化学, 2015, 33(5): 434-440.
[7]	李海燕, 钱俊杰, 刘金凤, 李秋叶, 张敏, 杨建军. 氮铋共掺杂TiO₂的合成及其可见光催化性能研究[J]. 影像科学与光化学, 2013, 31(6): 411-420.
[8]	张鹏, 于彦龙, 匡元江, 姚江宏, 曹亚安. Si掺杂TiO₂催化剂的结构与可见光催化活性研究[J]. 影像科学与光化学, 2013, 31(4): 295-304.
[9]	郑云, 顾彦, 汪淑廉, 杨静, 兰天龙, 黄应平, 张爱清. 铕掺杂TiO₂的制备及其可见光光催化性能研究[J]. 影像科学与光化学, 2012, 30(1): 60-70.
[10]	景明俊, 王岩, 张敏, 杨建军. 负载金的掺氮二氧化钛的制备及其可见光催化性能[J]. 影像科学与光化学, 2011, 29(5): 353-363.
[11]	王攀, 曹婷婷, 方艳芬, 罗光富, 李瑞萍, 黄应平. Hg掺杂CdS的制备及可见光降解有毒有机污染物[J]. 影像科学与光化学, 2011, 29(1): 11-23.
[12]	阮修莉, 邵冬海. TiO₂纳米管电极金属离子掺杂的表征[J]. 影像科学与光化学, 2011, 29(1): 54-62.
[13]	马望京, 赵艳艳, 段培成, 史瑶, 李智, 杨新民. 甲酸根掺杂立方体溴碘化银微晶乳剂的增感效应研究[J]. 影像科学与光化学, 2010, 28(6): 401-407.
[14]	汪应灵, 谢友海, 袁建梅, 周庆祥, 刘国光. 掺硼纳米TiO₂的制备及光催化性能研究[J]. 影像科学与光化学, 2010, 28(4): 287-295.
[15]	马望京, 史瑶, 赵艳艳, 段培成, 李智, 杨新民. Zn(Ⅱ)-EDTA和Cd(Ⅱ)-EDTA在草酸根掺杂溴化银颗粒乳剂中的增感效应[J]. 影像科学与光化学, 2009, 27(6): 409-417.

改善高氯卤化银乳剂的高照度性能

IMPROVEMENT OF PHOTOGRAPHIC PROPERTIES UNDER HIGH INTENSITY EXPOSURE IN HIGH CHLORIDE EMULSIONS

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价