影像科学与光化学 ›› 2010, Vol. 28 ›› Issue (6): 401-407.DOI: 10.7517/j.issn.1674-0475.2010.06.401

• 研究论文 •    下一篇

甲酸根掺杂立方体溴碘化银微晶乳剂的增感效应研究

马望京, 赵艳艳, 段培成, 史瑶, 李智, 杨新民   

  1. 中国科学院理化技术研究所, 北京, 100190
  • 修回日期:2010-06-11 出版日期:2010-11-23 发布日期:2010-11-23
  • 通讯作者: 杨新民

Sensitization on Cubic AgBrI Emulsion Doped with Formate

MA Wang-jing, ZHAO Yan-yan, DUAN Pei-cheng, LI Zhi, SHI Yao, YANG Xin-min   

  1. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P.R.China
  • Revised:2010-06-11 Online:2010-11-23 Published:2010-11-23

摘要: 使用反馈式微机控制双注仪,在晶体生长不同时期,依次加入不同量碘盐和一定量甲酸盐,制得了两个系列的溴碘化银乳剂:一系列为碘含量分别为乳剂颗粒总银量的0、2×10-2、3×10-2、4×10-2和5×10-2I-mol/Ag mol的溴碘化银颗粒乳剂;另一系列为碘含量与上述系列乳剂相同,并掺杂有1×10-4mol/Ag mol甲酸根的溴碘化银颗粒乳剂.对其感光性能的测试结果表明,经过化学敏化和光谱增感后,甲酸根掺杂的溴碘化银乳剂较未掺杂甲酸根的乳剂,感光度显著提高,在一定量的I-掺杂范围内(0-4×10-2I-mol/Ag mol),灰雾没有明显增加.

关键词: 甲酸根, 掺杂, 溴碘化银, 增感效应

Abstract: By using of the double-jet apparatus controlled by a microcomputer,different amounts of iodide salt and a certain amount of formate were doped in AgBr crystal in different periods of the crystal growth to prepare two series of cubic AgBrI emulsion: a series of formate-undoped AgBrI grain emulsions which contained 0,2×10-2,3×10-2,4×10-2,5×10-2 I- mol/Ag mol iodide ions respectively,another series of formate-doped AgBrI grain emulsions doped with 1×10-4 mol/Ag mol formate,which contained the same quantities of iodide ions as former,respectively.The sensitometric results from these emuls ions showed that the sensitivities of formate-doped AgBr/I emulsions,relative to those of the corresponding formate-undoped on esas the controlled,regardless of whether they were sensitized chemically and spectrally,were remarkably increased,while in a certain amount of iodid-edopin grange (0-4×10-2 I- mol/Ag mol),fog level of those were not remarkably improved.

Key words: formate, doped, AgBr/I, sensitization

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