A STUDY ON THE ELECTROCHEMICAL BEHAVIOR OF FERROCEN YL-N-OCTADECANOALE L-B FILM

doi:10.7517/j.issn.1674-0475.1990.03.192

Abstract

Abstract: The cyclic voltammetic behavior of ferrocene derivative——ferrocenyl-n-octadecanoate (Fc-OCOC₁₇H₃₅) which was attached on SnO,electrode surface by L-B technique was studied.Surface activity theory of molecules absorbed (modified) on electrode surface was employed to compare with the experimental cyclic voltammograms using a computer-fitting approach.Quantitative agreement between experiment and theory was obtained and some parameters such as standard electrode potential,cone,of attached reactants were estimated The results indicated that L-B film of FcOCOC₁₇H₃₅ can act as stable,reversible and fast charge transfer agent for modified electrodes.

Key words: modified electrode, L-B filn technique, cyclic voltammetry, computer fitting

LIN YUAN, XIAO XU-RUI. A STUDY ON THE ELECTROCHEMICAL BEHAVIOR OF FERROCEN YL-N-OCTADECANOALE L-B FILM[J]. Imaging Science and Photochemistry, 1990, 8(3): 192-198.

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