Imaging Science and Photochemistry ›› 1994, Vol. 12 ›› Issue (2): 126-132.DOI: 10.7517/j.issn.1674-0475.1994.02.126
Previous Articles Next Articles
WANG WEI-BO, AN JING-YI, LI XUE-PING, XIAO XU-RUI
Received:
Revised:
Online:
Published:
Abstract: The electrochemical redox behavior of compound 13-SO3Na-DDHA in buffer solution of different pH values repertively has been studied. There is a linear relationship between the reduction potential of carbonyl group and pH value.The slope of this line is about 60mV/pH. This result corresponds to one step 2-electron,2-proton reduction process:Q+2H++2e=QH2. As a polar but non-proton solvent,DMF is favorable for radicalstabilization. If DMF is added to a buffer solution,this compound may be reduced by twostep one-electron processes.
Key words: hypocrellin a sulfonate, quinone electrochemistry, photoinduced reduction
WANG WEI-BO, AN JING-YI, LI XUE-PING, XIAO XU-RUI. INVESTIGATION ON THE ELECTROCHEMICAL AND PHOTOINDUCED REDUCTION OF 13-SO3Na-DDHA[J]. Imaging Science and Photochemistry, 1994, 12(2): 126-132.
0 / / Recommend
Add to citation manager EndNote|Ris|BibTeX
URL: http://www.yxkxyghx.org/EN/10.7517/j.issn.1674-0475.1994.02.126
http://www.yxkxyghx.org/EN/Y1994/V12/I2/126
