Synthesis and Structure Characterization of Coumarin Derivatives

doi:10.7517/j.issn.1674-0475.2008.05.393

Abstract

Abstract: Eleven new coumarin derivatives were prepared in 53% to 79% yields.The structures of the title compounds were characterized by elemental analysis,¹HNMR and MS.The crystal structure of donor-acceptor complex ABT-MCC derived from 2-amino-1,3-benzothiazole(ABT) and ethyl 8-mthoxycoumarin-3-carboxylate(MCC) was determined by X-ray diffraction analysis.The crystal of ABT-MCC belongs to the triclinic system,space group P1,cell parameters: a=9.5978(19)Å,b=10.686(2)Å,c=10.693(2)Å,α=71.30(3)°,β=70.43(3)°,γ=88.99(3) °,V=973.9(3)Å³,Z=2,D_x=1.359 mg/m³,μ=0.200 mm^-1,F(000)=416,R=0.0463, wR=0.0992.X-ray diffraction reveals that the complex shows the A…D…D’…A’ H-bonded tetramer.The molecules are connected via intermolecular hydrogen bonds into a one-dimensional chain structure,and are further assembled to form a layer structure via the π-π stacking.

Key words: coumarin derivatives, 2-aminobenzothiazole, donor-acceptor complex, synthesis, crystal structure

CLC Number:

SUN Yi-feng, MA Shi-ying, ZHANG Dong-di, CHENG Xue-li. Synthesis and Structure Characterization of Coumarin Derivatives[J]. Imaging Science and Photochemistry, 2008, 26(5): 393-402.

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