New Selective Fe3+ and Hg2+ Ions Chemosensors Based on Anthracenecarbonamide Derivatives

doi:10.7517/j.issn.1674-0475.2009.01.23

Abstract

Abstract: Two synthesized compounds,N-(6-aminopyridine2-yl)-9-anthracenecarbonamide(L¹) and N,N’-(pyridine-2,6-yl)-bis(9-anthracenecarbonamide)(L²) are found to show good sensitivity and selectivity to Fe³⁺ and Hg²⁺ ions,respectively.L¹ shows highly sensitive response to Fe³⁺ on fluorescence spectrum.The recognition of L² to Hg²⁺ could be achieved by using absorption and fluorescence spectra.The effect of the presence of other metal ions on sensing for the aim ions were studied too.In addition,the coordination models of these two compounds with metal ions were suggested.

Key words: anthracenecarbonamide, chemosensor, Fe³⁺, Hg²⁺, spectroscopy

CLC Number:

XU Quan-qing, WANG Jun, ZHANG Hui-miao, FU Wen-fu. New Selective Fe³⁺ and Hg²⁺ Ions Chemosensors Based on Anthracenecarbonamide Derivatives[J]. Imaging Science and Photochemistry, 2009, 27(1): 23-31.

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New Selective Fe³⁺ and Hg²⁺ Ions Chemosensors Based on Anthracenecarbonamide Derivatives

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