Rhodamine-Pathalic Diamide Derivative for Colorimetric and Fluorescent "Turn-On" Detection of Cr3+

doi:10.7517/j.issn.1674-0475.2015.02.144

Abstract

Abstract:

In this work, a Rhodamine-phthalic diamide derivative (RP1) was synthesized and characterized. It exhibited high selectivity to Cr³⁺over other metal cations inaqueous solution, and the "turn-on" response could be easily detected by means of absorption and fluorescence spectra, furthermore, an obvious color change from colorless to pink could be spontaneouly observed. Quantitive results showed that the binding model of RP1 and Cr³⁺was in 1:1 stoichiometry and the binding constant was 3.43×10⁴L/mol. Moreover, the mechanism study illustrated that the recognition of RP1 and Cr³⁺ went through a reversible coordination induced spiro-ring opening reaction, but not catalyzed hydrolysis of spiro-ring.

Key words: chemosensor, rhodamine B, phathalic diamide, Cr³⁺ detection

HAN Wen, YANG Yunxu, XU Tailin, SHENG Ruilong, LI Binlian, ZHU Haibo. Rhodamine-Pathalic Diamide Derivative for Colorimetric and Fluorescent "Turn-On" Detection of Cr³⁺[J]. Imaging Science and Photochemistry, 2015, 33(2): 144-153.

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Rhodamine-Pathalic Diamide Derivative for Colorimetric and Fluorescent "Turn-On" Detection of Cr³⁺

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