Effect of POP-290 on the Acrylate UV Coating

doi:10.7517/j.issn.1674-0475.2010.03.209

Abstract

Abstract: EA/POP-290/active monomer flame-retardant UV coating was prepared,and the effects of different contents POP-290 on the flame retardance and UV curing properties of acrylate UV coating were studied.It was shown that POP-290 can increase the gel content,T_g and curing rate.When the content of POP-290 was up to 7%,the burning grading up to FH-1 and the LOI increased from 21 to 26.

Key words: epoxy acrylate, polyether polyol, flame retardance, UV curing

CLC Number:

JIANG Hui, WANG De-hai, HU Xiang-tai, CHEN Min. Effect of POP-290 on the Acrylate UV Coating[J]. Imaging Science and Photochemistry, 2010, 28(3): 209-216.

References

[1] Chen X,Hu Y,Song L,et al.Thermal properties and combustion behaviors of UV-cured phosphate triacrylate/star poly(urethane acrylate) oligomer blends[J].Polymers for Advanced Technologies,2008,19(5):393-398.
[2] Apohan N K,Karatas S,Bilen B,et al.In situ formed silica nanofiber reinforced UV-curable phenylphosphine oxide containing coatings[J].Journal of Sol-Gel Science and Technology,2008,46(1):87-97.
[3] Huang Z G,Shi W F.UV curing behavior of hyperbranched polyphosphate acrylate/di(hydroxylpropyl methacrylate) piperazine and properties of the cured film[J].Progress in Organic Coatings,2007,59(4):312-317.
[4] Huang Z G,Shi W F.Thermal degradation behavior of hyperbranched polyphosphate acrylate/tri(acryloyloxyethyl) phosphate as an intumescent flame retardant system[J].Polymer Degradation and Stability,2007,92(7):1193-1198.
[5] 袁才登,许涌深.含氮酚醛树脂及其对环氧树脂的阻燃改性[J].热固性树脂,2000,15(002):12-14.Yuan C D,Xu Y S.Nitrogen-containing phenolic resins and their uses in flame-retardant modification of epoxy Resins[J].Thermosetting resin,2000,15(002):12-14.
[6] 许苗军,李斌,李晓丽,等.三嗪阻燃剂的合成及阻燃ABS研究[J].中国塑料,2004,18(11):81-84.Xu M J,Li B,Li X L,et al.Synthesis of a triazine flame retardant and its flame retardancy in ABS[J].China Plastics,2004,18(11):81-84.
[7] Liang H B,Asif A,Shi WF.Thermal degradation and flame retardancy of a novel methacrylated phenolic melamine used for UV curable flame retardant coatings[J].Polymer Degradation and Stability,2005,87(3):495-501.
[8] 黄福林.软质聚氨酯泡沫塑料用无卤阻燃剂的研究[J].化学研究与应用,2008,20(7):840-843.Huang F L.A novel halogen-free flame retardant for flexible polyurethane foams[J].Chemical Research and Application,2008,20(7):840-843.
[9] 欧育湘.实用阻燃技术[M].北京:化学工业出版社,2002.1-18.Ou Y X.Practical Flame Retardant Technology[M].Beijing:Chemical Industry Press,2002.1-18.
[10] 欧育湘.阻燃高分子材料[M].北京:国防工业出版社,2001.4-56.Ou Y X.Flame-retarded Polymeric Materials[M].Beijing:National Defense Industry Press.2001.4-56.
[11] 陈红,侯运城,邹林,等.2006-2007年国内外不饱和聚酯树脂工业进展[J].热固性树脂,2008,23(3):44-51.Chen H,Hou Y C,Zou L,et al.Industry development of unsaturated polyester resin at home and abroad from 2006 to 2007[J].Thermosetting Resin,2008,23(3):44-51.
[12] Zhu S W,Shi W F.Flame retardance of UV cured epoxy acrylate blended with different states of phosphated methacrylate[J].Polymer Degradation and Stability,2003,82(3):435-439.
[13] Kahraman M V,Kayaman-Apohan N,Arsu N,et al.Flame retardance of epoxy acrylate resin modified with phosphorus containing compounds[J].Progress in Organic Coatings,2004,51(3):213-219.
[14] Liang H B,Ding J,Shi W F.Kinetics and mechanism of thermal oxidative degradation of UV cured epoxy acrylate/phosphate triacrylate blends[J].Polymer Degradation and Stability,2004,86(2):217-223.
[15] 王锋.UV固化环氧丙烯酸酯涂料研究进展[J].热固性树脂,2007,22(4):36-40.Wang F.Research progress of UV-curable epoxy acrylate coatings[J].Thermosetting Resin,2007,22(4):36-40.
[16] 王素琴,曹瑞军,段玉岗.激光快速成型光固化树脂的研究应用[J].感光材料,1999,S1:84-87.Wang S Q,Chao R J,Duan Y G.Study and application of photocurable resin in laser rapid prototyping[J].Image Materials,1999,S1:84-87.
[17] 项光其.氰基胍分子结构的研究[J].温州师范学院学报,2003,24(2):20-22.Xiang G Q.Study on molecular structure of[NHC(NH₂)₂] CN[J].Journal of Wenzhou Teachers College,2003,24(2):20-22.