Preparation Nano-TiO2 by Hydrothermal Method and Its Application in Dye Sensitized Solar Cell

doi:10.7517/j.issn.1674-0475.2006.03.173

Abstract

Abstract: A precursor was obtained by hydrolyzing tetrabutyl titanate in hydrochloric acid or acetic acid solution,anatase nano-TiO₂ powder was prepared from the precursor by hydrothermal method.Using the nano-TiO₂ as the electron transmission medium,a dye-sensitized solar cell(DSC) was assembled.The influence of nano-TiO₂ on the photoelectronic properties of the DSC was investigated by measuring XRD,ICP,SEM,TEM,DRS and I-V curve of the solar cell.The result show that the temperature of the hydrothermal play an important role in the photoelectric performance of the DSC,the anatase TiO₂ prepared in acetic acid solution shows higher photoelectric performance than others.

Key words: solar cells, dye sensitized, hydrothermal method, anatase TiO₂

CLC Number:

WANG Dong-bo, WU Ji-huai, HAO San-chun, LAN Zhang, YANG Hong-xun. Preparation Nano-TiO₂ by Hydrothermal Method and Its Application in Dye Sensitized Solar Cell[J]. Imaging Science and Photochemistry, 2006, 24(3): 173-179.

References

[1] Brain O' Regan,Michael Grätzel.A low-cost high-efficiency solar cell based on dye-sensitized colloidal TiO₂ film[J].Nature,1991,353:737-740.
[2] Gratzel M.Review dye-sensitized solar cells[J].Journal of Photochemistry and Photobiology C:Photochemistry Reviews 4,2003,145-153.
[3] Torsten Oekermann,Dongshe Zhang,Tsukasa Yoshida.Electron transport and back reaction in nanocrystalline TiO₂ films prepared by hydrothermal crystallization[J].J.Phys.Chem.B,2004,108:2227-2235.
[4] 黄晖,罗宏杰,姚熹.水热法制备TiO₂薄膜的研究[J].物理学报,2002,51(08):1881-1806.Huang H,Luo H J,Yao X.A study on TiO₂ thin films deposited by hydrothermal technique[J].ACTA PHYSICA SINICA,2002,51(08):1881-1806.
[5] Yu V Kolen' ko,B R Churagulov,M Kunst.Photocatalytic properties of titania powders prepared by hydrothermal method[J].Applied Catalysis B:Environmental,2004,54:51-58.
[6] Juan Y,Sen M,José M F Ferreir.Hydrothermal processing of nanocrystalline anatase films from tetraethylammonium hydroxide peptized titania sols[J].Journal of the European Ceramic Society,2004,24:335-339.
[7] 陈代荣,孟祥建,李博等.偏钛酸作前驱体水热合成TiO₂微粉[J].无机材料学报,1997,12(1):110-114.Chen D R,Meng X J,Li B,et al.TiO₂ particles derived from H₃TiO₃ with hydrothermal method[J].Journal of Inorganic Materials,1997,12(1):110-114.
[8] 吴孟强,张其翼,陈艾,等.凝胶-水热法制备纺锤型TiO₂粉体[J].硅酸盐学报,2002,30(1):108-111.Wu M Q,Zhang Q Y,Chen A,et al.Synthesis of spindle type titanta particles by the gel-hydrothermal process[J].Journal of the Chinese Ceramic Society,2002,30(1):108-111.
[9] 郝三存,吴季怀,林建明,等.铂修饰光阴极及其在纳晶太阳能电池中的应用[J] 感光科学与光化学,2004,22:175-181..HAO S C,WU J H,LIN J M,et al.Modification of photocathode with platinum and its application in dye-sensitized solar cell[J].Photographic Science and Photochemistry,2004,22:175-181.
[10] 施而畏,陈之战,元如林,等.水热结晶学[M].北京:科学出版社,2004.209-229.Shi E W,Chen Z Z,Yuan R L,et al.Hydrothermal Crystallography[M].Beijing:Science Press,2004.209-229.
[11] Claudia Longo,A F Nogueira,Marco-A De Paoli,Solid-state and flexible dye-sensitized TiO₂ solar cells:a study by electrochemical impedance spectroscop[J].J.Phys.Chem.B,2002,106:5925-5930.

[1]	ZHAO Xue, PEI Juan, LI Yingpin. Effect of Co-sensitization of Dyes with Different Acceptor Moieties for Dye-sensitized Solar Cells [J]. Imaging Science and Photochemistry, 2019, 37(6): 525-535.
[2]	LIU Lanlan, ZHOU Haihua, LI Lihong, ZHANG Xingye, SONG Yanlin. Fabrication of Transparent Conductive Films Based on Silver Nanowires and Their Applications in Printed Electronics [J]. Imaging Science and Photochemistry, 2018, 36(1): 33-50.
[3]	ZHANG Jiabin, MA Yuchao, YI Jinduo, DOU Junyan, WANG Hongyu, MA Changqi. Synthesis and Properties of 4,4'-Spiro-bi[cyclopenta[2,1-b;3,4-b']dithiophene]Cored 1,8-Naphthalimide Derivatives for Organic Solar Cells [J]. Imaging Science and Photochemistry, 2017, 35(5): 736-748.
[4]	KONG Xiangbin, CHEN Yongzhen, LI Zhiyi, LIU Yanwei, WEI Xiaofang, LIU Jianjun, WANG Ruifang, WANG Ying. Effect of Pressure on Morphology and Crystallinity of the Perovskite Thin Film [J]. Imaging Science and Photochemistry, 2017, 35(5): 749-757.
[5]	ZHANG Meilin, JIN Feng, ZHENG Meiling, LIU Jie, DUAN Xuanming. Effect of Hydrothermal Growing Method on the Structure and Crystalline Quality of ZnO Nanorod Array [J]. Imaging Science and Photochemistry, 2015, 33(2): 136-143.
[6]	LI Hai-yan, QIAN Jun-jie, LIU Jin-feng, LI Qiu-ye, ZHANG Min, YANG Jian-jun. Study on the Synthesis of N, Bi-codoped TiO₂ Nanoparticles and Their Visible Light Photocatalytic Performance [J]. Imaging Science and Photochemistry, 2013, 31(6): 411-420.
[7]	FANG Yan-yan, LIN Yuan. Effect of Ionic Liquid Polymers with Different Pendant Group for Polymer Electrolyte on the Photovaltic Performance of Dye-Sensitized Solar Cells [J]. Imaging Science and Photochemistry, 2013, 31(6): 430-439.
[8]	WU Shi-kang, WANG Peng-fei. The Application of Functional Dyes in Solar Cell [J]. Imaging Science and Photochemistry, 2010, 28(3): 217-229.
[9]	HE Li, LIU Bo, CHEN Yu, ZHU Wei-hong. Synthesis and Photovoltaic Performances of Dye-sensitized Solar Cells Based on Novel NIR Dyes Containing Multi-cyano Acceptor [J]. Imaging Science and Photochemistry, 2010, 28(2): 137-146.
[10]	ZHANG Yang, ZENG Qing-hui, ZHI Jin-fang. Application of the Peroxotitanium Complex (PTC) for Flexible Dye Sensitized Solar Cells (DSSC) [J]. Imaging Science and Photochemistry, 2009, 27(6): 418-426.
[11]	LIU Guang-lu, CAI Ning, ZHAO Ying, ZHANG Yuan, YANG Rui-xia, XIONG Shao-zhen . Preparation of an Environmental Friendly Quasi-solid-state Electrolyte and Its Application in Dye-sensitized Solar Cells [J]. Imaging Science and Photochemistry, 2008, 26(6): 445-451.
[12]	ZHANG Xiu-kun, WU Ji-huai, LI Shu-quan, XU Bo, LI Biao, LI Pin-jiang, LAN Zhang, HUANG Miao-liang, LIN Jian-ming, FAN Le-qing. Preparation of Nano-crystalline TiO₂ Porous Film Electrode Using a Mixing P25 Hydrothermal Method [J]. Imaging Science and Photochemistry, 2008, 26(6): 499-506.
[13]	ZHANG Feng, TAO Jie, TAO Hai-jun, DONG Xiang. Preparation and Photoelectric Performance of Flexible Titania Nanotubes Thin Film [J]. Imaging Science and Photochemistry, 2008, 26(3): 224-232.
[14]	JIANG Chun-hua, HU Yu-ning, WAN Fa-rong, LONG Yi. Structure of Counter Electrode in Dye-Sensitized Nano Crystal TiO₂ Solar Cells [J]. Imaging Science and Photochemistry, 2006, 24(5): 325-334.
[15]	LI Jian-zhuang, ZHAO Xiu-jian, XIA Dong-Iin. The Influence of Heat-Treatment on CuInGaSe₂ Thin Films by Electrodeposition [J]. Imaging Science and Photochemistry, 2005, 23(4): 241-246.

Preparation Nano-TiO₂ by Hydrothermal Method and Its Application in Dye Sensitized Solar Cell

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments