Solvothermal Synthesis of Metal Chalcogenides and Studies of Its Photoelectric Properties

doi:10.7517/j.issn.1674-0475.2004.06.420

Abstract

Abstract: Nanosize semiconductor particles were synthesized using the solvothermal technique.The structures were characterized by means of XRD and TEM techniques.PANI and PPY films were prepared by electrochemistry method onto the indium-tin oxide glass (ITO).The nanoparticles were doped on PANI and PPY films by the dipping process, and the self-assembled nanoparticles-PANI composite film was acquired.The photoelectric properties of the self-assembled films were studied by PL method.The result concluded that the photoluminescence radiation can be unambiguously enhanced when decorated PANI film with CdS nanoparticles.

Key words: semiconductor, nano, photo-properties

CLC Number:

TQ57

ZHONG Huai-zhen, HE Xiao-yun, LI Guo-qiang, CHEN Zhen. Solvothermal Synthesis of Metal Chalcogenides and Studies of Its Photoelectric Properties[J]. Imaging Science and Photochemistry, 2004, 22(6): 420-426.

References

[1] 席燕燕,黄怀国等.ZnO-聚苯胺复合膜的制备和性能研究[J].电化学,2003,9(1):30-35.Xi Y Y,Huang H G,et al.The Preparation and characterization of ZnO-PANI composite film[J].Electrochemistry,2003,9(1):30-35.
[2] Li J,Chen Z,Wang R J,Proserpio D M.Low temperature route towards new materials:solvothermal synthesis of metal chalcogenides in ethylenediamine[J].Coordination Chemistry Reviews,1999,190-192,707-735.
[3] 陈震,郑曦,陈日耀.有机溶剂热生长晶体及其应用[J].材料研究学报,2001,15(2),151-158.Chen Z,Zheng X,Chen R Y,et al.Application of voltammentry method in electroluminescence cell[J].Chinese Journal of Luminescence,2001,22 (3):271-275.
[4] Kanatzidis M G,Huang S P.Coordination chemistry of heavy polychalcogenide ligands[J].Coordination Chemistry Reviews,1994,130:509-621.
[5] Li J,Chen Z,Wang R J,et al.Low temperature route towards new materials:Solvothermal synthesis of metal chalcogenides in ethylenediamine[J].Coordinatinon Chemistry Reviews,1999,190:707.
[6] 马永孝,胡学弘导电聚苯胺的制备与应用研究[J].齐齐哈尔师范学院学报,1997,17(1):42-44.Ma Y X,Hu X H.Preparation and application of polyaniline[J].Journal of Qiqihar Teachers’ College(Natural Science),1997,17(1):42-44.
[7] 陈震,黄子祥.金属碲化物[Ga(en)₃]In₃Te₇晶体结构和性质的研究[J].化学学报,2000,58(7):835-839Chen Z,Huang Z X.Crystal structure and properties of indium telluride [Ga(en)₃]In₃Te₇ [J].Acta Chimica Sinica,2000,58(7):835-839.
[8] Huang H G,Zheng Z X,et al.Internal photoemission in polyaniline resealed by photoelectrochemistry[J].Synt.Met.,2001,2(123),321.
[9] Burrows P E,Shen Z,Bulovic V,McCarty D M,Forrest S R.Relationship between electroluminescence and current transport in organic heterojunction light-emitting devices [J].Appl.Phys.,1996,79 (10):7991-8006.
[10] 窦恺,赵家龙等.CdS半导体纳米晶体高强度激发下光谱特性研究[J].发光学报,1995,16(3):278-280Dou K,Zhao J L,et al.High excitation photoluminescence of CdS nanocrystals doped sodium borosilicate glass[J].Chinese Journal of Luminescence,1995,16 (3):278-280.
[11] 黄怀国,席燕燕,郑志新.择优生长CdS纳米微粒膜的制备和性能研究[J].电化学,2002,2(5):195-200.Huang H G,Xi Y Y,Zheng Z X.The preparation and characterization of growing preferentially CdS nano particle film [J].Electrochemistry,2002,2 (5):195-200.

[1]	ZHANG Kaili, CHEN Guangxue. Preparation of High Transparent Conductive Nanopaper and Its Application in Paper-based Capacitors [J]. Imaging Science and Photochemistry, 2020, 38(5): 790-794.
[2]	JIA Hongdan, XING Wenli, SONG Yujiao, ZHENG Shehong, GAO Yunyan, OU Zhize. Fluorescent Sensing of Hg²⁺ by Phenanthroimidazole Derivative Supported on Silica Nanoparticles [J]. Imaging Science and Photochemistry, 2020, 38(4): 601-608.
[3]	WU Baolin, HUANG Biwu, DU Zhipeng, YONG Tao, HAN Linlin. Study on UV-curing Properties of Phenyl Glycidyl Ether Acrylate Modified by Nano-SiO₂ [J]. Imaging Science and Photochemistry, 2019, 37(4): 304-314.
[4]	WANG Lingyun, TAN Kan, LUO Jing. Preparation of Photosensitive Carbon Nanotubes by Tannic Acid Modification and Preparation of UV-curable AESO Composite Films [J]. Imaging Science and Photochemistry, 2019, 37(3): 175-184.
[5]	MU Yalin, CHEN Xiaomei, LIU Xuan, LIU Gang. Recent Advances in Molecular Imaging of Atherosclerotic Plaque [J]. Imaging Science and Photochemistry, 2019, 37(1): 7-17.
[6]	LIU Tingting, ZHU Tianxiang, SHAO Lin, ZHAO Xinluo, ZHAO Jianwen, CUI Zheng. Fabrication and Electrical Properties of Printed Carbon Nanotube Thin Film Transistors (TFTs) Based on Self-made Carbon Nanotubes [J]. Imaging Science and Photochemistry, 2018, 36(3): 245-253.
[7]	LI Yue, SONG Yuze, TAO Yanzhong, GAO Fengxian, TANG Ning. Facial Fabrication of CdS Nanoparticles Sensitized TiO₂ Nanomesh with Enhanced Photocatalytic Activity [J]. Imaging Science and Photochemistry, 2018, 36(3): 275-282.
[8]	TAO Pingfang, FENG Yuqin, ZHOU Neng, QIN Liqin, ZHANG Pei. Hydrothermal Synthesis of α-NaYF₄: Ce³⁺/Tb³⁺ Nanospheres with High Fluorescence Properties [J]. Imaging Science and Photochemistry, 2018, 36(2): 161-170.
[9]	LIU Lanlan, ZHOU Haihua, LI Lihong, ZHANG Xingye, SONG Yanlin. Fabrication of Transparent Conductive Films Based on Silver Nanowires and Their Applications in Printed Electronics [J]. Imaging Science and Photochemistry, 2018, 36(1): 33-50.
[10]	LI Dandan, CHEN Xin, WANG Hong, FU Yang, YU Yuan, ZHI Jinfang. Nanodiamonds Raman Probes for Visualizing the Interaction between Antimicrobial Peptide and Bacteria [J]. Imaging Science and Photochemistry, 2018, 36(1): 89-99.
[11]	GAO Wenhui, WANG Zhaoqun, PAN Junqing, YIN Hongzong. Determination of Indole Acetic Acid by SPR Biosensor Based on the Metal Nanoparticles Sensitization [J]. Imaging Science and Photochemistry, 2017, 35(6): 843-852.
[12]	Samuel Lascio, Hai-Feng Ji. Optical,Optoelectronic,and Photocatalytic Applications of Phosphorus Nanomaterials [J]. Imaging Science and Photochemistry, 2017, 35(5): 587-602.
[13]	CAO Yitao, WU Lizhu, TONG Zhenhe(TUNG Chenho), ZHANG Tierui. Photochemical Synthesis of Inorganic Nanomaterials [J]. Imaging Science and Photochemistry, 2017, 35(5): 642-648.
[14]	XU Hongxia, WANG Zaiwei, ZHANG Chuanjian, CUI Guanglei. Coaxial CoSe/TiN Nanotube Arrays as Counter Electrodes of Dye-sensitized Solar Cells [J]. Imaging Science and Photochemistry, 2017, 35(5): 758-764.
[15]	XIAO Kai, WEN Liping, JIANG Lei. Construction and Application of Biomimetic Photoresponsive Smart Nanochannels [J]. Imaging Science and Photochemistry, 2017, 35(4): 337-348.