氮化铌电催化还原CO2

doi:10.7517/issn.1674-0475.181208

影像科学与光化学 ›› 2019, Vol. 37 ›› Issue (2): 107-117.DOI: 10.7517/issn.1674-0475.181208

氮化铌电催化还原CO₂

李文廷^1,3, 侯朋飞^1,3, 康鹏^1,2,3

1. 中国科学院理化技术研究所光化学转换与功能材料重点实验室, 北京 100190;
2. 天津大学化学院, 天津 300350;
3. 中国科学院大学, 北京 100049

收稿日期:2018-12-26 修回日期:2019-01-08 出版日期:2019-03-15 发布日期:2019-03-15
通讯作者: 康鹏
基金资助:
国家基础研究开发重点项目（2016YFB0600901）

Niobium Nitride Catalyst for Electrocatalytic Reduction of CO₂

LI Wenting^1,3, HOU Pengfei^1,3, KANG Peng^1,2,3

1. Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China;
2. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, P. R. China;
3. University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Received:2018-12-26 Revised:2019-01-08 Online:2019-03-15 Published:2019-03-15
Supported by:
National Key R&D Projects of China (2016YFB0600901)

摘要/Abstract

摘要： 通过电化学的方法将CO₂转化为CO是解决资源和环境问题的经济友好的策略。在本次工作中，利用湿化学方法制备了铌/碳的前驱体，在NH₃和Ar氛围下煅烧后分别转化为Nb₄N₅/C和Nb₂O₅/C。当氮化温度达到700℃时，制备的Nb₄N₅/C表现出优异的催化活性，在CO₂饱和的0.5 mol·L^-1的NaCl溶液中，电解电位为-0.83V（RHE）时，CO的法拉第效率最高，达到57%。实验结果表明，Nb₄N₅/C的催化活性与Nb₄N₅中的N掺杂有关。

关键词: 氮化铌, 电催化, CO₂还原, CO

Abstract: Converting CO₂ to CO by electrochemical method is considered as an economic and friendly strategy to solve problems of resource and environment. In this work, precursor of niobium/carbon was prepared by wet chemical method and converted into Nb₄N₅/C and Nb₂O₅/C after calcination under NH₃ and Ar respectively. When the nitriding temperature reaches to 700℃, prepared Nb₄N₅/C exhibits excellent catalytic activity with CO Faradaic efficiency of 57% at -0.83 V vs RHE in CO₂ saturated 0.5 mol·L^-1 NaCl solution. The results show that the catalytic activity of Nb₄N₅/C is related to the N doping in Nb₄N₅.

Key words: niobium nitride, electrocatalysis, CO₂ reduction, CO

李文廷, 侯朋飞, 康鹏. 氮化铌电催化还原CO₂[J]. 影像科学与光化学, 2019, 37(2): 107-117.

LI Wenting, HOU Pengfei, KANG Peng. Niobium Nitride Catalyst for Electrocatalytic Reduction of CO₂[J]. Imaging Science and Photochemistry, 2019, 37(2): 107-117.

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氮化铌电催化还原CO₂

Niobium Nitride Catalyst for Electrocatalytic Reduction of CO₂

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