4-(4-甲基-苯基)-6-苯基-2,2'-联吡啶铂(Ⅱ)光致产氢研究

doi:10.7517/j.issn.1674-0475.2013.01.003

影像科学与光化学 ›› 2013, Vol. 31 ›› Issue (1): 18-23.DOI: 10.7517/j.issn.1674-0475.2013.01.003

4-(4-甲基-苯基)-6-苯基-2,2'-联吡啶铂(Ⅱ)光致产氢研究

王格侠, 冯科, 邢令宝, 史晓燕, 张丽萍, 佟振合, 吴骊珠

中国科学院理化技术研究所光化学转换与功能材料重点实验室, 北京 100190

收稿日期:2012-05-17 修回日期:2012-06-14 出版日期:2013-01-15 发布日期:2013-01-15
通讯作者: 吴骊珠
基金资助:
科技部国家重点基础研究发展规划项目(2009CB220008);国家自然科学基金(21090343,21002108,91027041);裘槎基金;中科院知识创新工程.

Photocatalytic Hydrogen Production Using a Cyclometalated 4-(4-Tolyl)-6-Phenyl-2,2'-Bipyridyl Platinum(Ⅱ) Chloride Complex

WANG Ge-xia, FENG Ke, XING Ling-bao, SHI Xiao-yan, ZHANG Li-ping, TONG Zhen-ho(TUNG Chen-ho), WU Li-zhu

Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

Received:2012-05-17 Revised:2012-06-14 Online:2013-01-15 Published:2013-01-15

摘要/Abstract

摘要： 本文以氯离子配位的4-(4-甲基-苯基)-6-苯基-2,2'-联吡啶铂(Ⅱ)配合物为光敏剂,Co(dmgH)₂pyCl为催化剂,三乙醇胺(TEOA)为电子牺牲体,在pH为8.5的乙腈/水混合溶剂中构建了光致产氢体系.体系光照(λ > 400 nm)19 h后产氢量达到1.8 mL,反应的转换数(TON)达到804(vs.光敏剂).

关键词: 4-(4-甲基-苯基)-6-苯基-2,2'-联吡啶铂(Ⅱ)配合物, Co(Ⅲ)配合物, 光敏剂, 光致产氢, 反应转换数

Abstract: A homogeneous system containing 4-(4-tolyl)-6-phenyl-2, 2'-bipyridyl platinum(Ⅱ) chloride 1 as a photosensitizer, a bis(dimethylglyoximate) Co(Ⅲ) complex as a catalyst, and TEOA as a sacrificial electron donor is designed for H₂ generation from water. With visible light irradiation(λ > 400 nm) for 19 h, more than 804 equivalents of H₂ per photosensiter were achieved, which is competitive with that obtained by platinum(Ⅱ) terpyridyl acetylide complex.

Key words: 4-(4-tolyl)-6-phenyl-2, 2'-bipyridyl platinum(Ⅱ) chloride, Co(Ⅲ) complex, photosensitizer, photocatalytic hydrogen production, turnover number

中图分类号:

王格侠, 冯科, 邢令宝, 史晓燕, 张丽萍, 佟振合, 吴骊珠. 4-(4-甲基-苯基)-6-苯基-2,2'-联吡啶铂(Ⅱ)光致产氢研究[J]. 影像科学与光化学, 2013, 31(1): 18-23.

WANG Ge-xia, FENG Ke, XING Ling-bao, SHI Xiao-yan, ZHANG Li-ping, TONG Zhen-ho(TUNG Chen-ho), WU Li-zhu. Photocatalytic Hydrogen Production Using a Cyclometalated 4-(4-Tolyl)-6-Phenyl-2,2'-Bipyridyl Platinum(Ⅱ) Chloride Complex[J]. Imaging Science and Photochemistry, 2013, 31(1): 18-23.

参考文献

[1] Grötzel M. Artificial photosynthesis-water cleavage into hydrogen and oxygen by visible-light[J]. Acc. Chem. Res., 1981, 14(12): 376-384.
[2] Kalyanasundaram K, Kiwi J, Gr tzel M. Hydrogen evolution from water by visible-light, a homogeneous 3 component test system for redox catalysis[J]. Helv . Chim. Acta., 1978, 61(7): 2720-2730.
[3] Kirch M, Leh J M, Sauvage J P. Hydrogen generation by visible-light irradiation of aqueous-solutions of metal-complexes-approach to the photo-chemical conversion and storage of solar-energy[J]. Helv. Chim. Acta., 1979, 62(4): 1345-1384.
[4] Lehn J M, Sauvage J P. Chemical storage of light energy-catalytic generation of hydrogen by visible-light or sunlight - irradiation of neutral aqueous-solutions[J]. Nouv. J. Chim., 1977, 1(6): 449-451.
[5] Zhang D, Wu L Z, Zhou L, et al. Photocatalytic hydrogen production from hantzsch 1,4-dihydropyridines by platinum(Ⅱ) terpyridyl complexes in homogeneous solution[J]. J. Am. Chem. Soc., 2004, 126(11): 3440-3441.
[6] Du P W, Schneider J, Eisenberg R, et al. Photocatalytic generation of hydrogen from water using a platinum(II) terpyridyl acetylide chromophore[J]. J. Am. Chem. Soc., 2006, 128(24): 7726-7727.
[7] Du P, Schneider J, Luo G, et al. Visible light-driven hydrogen production from aqueous protons catalyzed by molecular cobaloxime catalysts[J]. Inorg. Chem., 2009, 48(11): 4952-4962.
[8] Du P, Schneider J, Li F, et al. Bi- and terpyridyl platinum(Ⅱ) chloro complexes: molecular catalysts for the photogeneration of hydrogen from water or simply precursors for colloidal platinum[J]. J. Am. Chem. Soc., 2008, 130(15): 5056-5058.
[9] Du P, Knowles K, Eisenberg R. A homogeneous system for the photogeneration of hydrogen from water based on a platinum(Ⅱ) terpyridyl acetylide chromophore and a molecular cobalt catalyst[J]. J. Am. Chem. Soc., 2008, 130(15): 12576-12577.
[10] Du P W, Schneider J, Eisenberg R, et al. Photoinduced electron transfer in platinum(II) terpyridyl acetylide chromophores: Reductive and oxidative quenching and hydrogen production[J]. J. Phys. Chem. B., 2007, 111(24): 6887-6894.
[11] Wang W, Goeb S, Ji Z, et al. Homogeneous photocatalytic hydrogen production using pi-conjugated platinum(ii) arylacetylide sensitizers[J]. Inorg. Chem., 2011, 50(3): 705-707.
[12] Lai S W, Chan M C W, Cheung T C, et al. Probing d(8)-d(8) interactions in luminescent mono- and binuclear cyclometalated platinum(Ⅱ) complexes of 6-phenyl-2,2 '-bipyridines[J]. Inorg. Chem., 1999, 38(18): 4046-4055.
[13] 韩雪,吴骊珠,吴梓新,张丽萍,佟振合. 4-( 4-甲基苯基)-6-苯基-2, 2' -二联吡啶芳炔铂(Ⅱ)络合物的合成及光物理性质[J].感光科学与光化学,2006,24(3):161-166. Han X, W u L Z, Wu Z X, Zhang L P, Tung C H. The synthesis and photophysical properties of 4-(4-tolyl -6-phenyl-2,-2-bipyridyl) platinum(Ⅱ) aryl-substituted acetylide complexes[J]. Photographic Seience and Photochemistry, 2006,24(3):161-166.
[14] Ding J, Feng K, Tung C H, et al. Long-lived charge separation in a dyad system containing cyclometalated platinum(Ⅱ) complex and ferrocene donor[J]. J. Phys. Chem. C, 2011, 115(3): 833-839.

[1]	王震, 张荻琴, 赵宇, 张云龙, 赵榆霞. 用于全息存储的新型感绿光敏剂的制备及其性能研究[J]. 影像科学与光化学, 2018, 36(3): 211-218.
[2]	赵洁, 李峻柏. 基于长波长光激发的光敏剂和载体在肿瘤光动力治疗中的应用[J]. 影像科学与光化学, 2017, 35(4): 364-378.
[3]	黄星, 刘源, 王潇朴, 赵榆霞. 双光子聚合技术在组织工程学方面的研究进展[J]. 影像科学与光化学, 2017, 35(4): 396-412.
[4]	骆司航, 赵春常. 两性聚合物光敏剂的合成及性能[J]. 影像科学与光化学, 2016, 34(5): 426-434.
[5]	李旭兵, 王旭喆, 宋子琪, 张丽萍, 佟振合, 吴骊珠. 基于新型NiFe氢化酶催化中心模拟物的光诱导产氢研究[J]. 影像科学与光化学, 2015, 33(5): 411-416.
[6]	李秋艳, 权莹, 梁海燕, 张乐. 化学增感对苯并三氮唑银的PTG材料感光性能的影响[J]. 影像科学与光化学, 2015, 33(3): 218-223.
[7]	黄灵, 赵建章. 具有强可见光吸收的富勒烯-Bodipy衍生物作为光催化剂在硫醚光催化氧化中的应用[J]. 影像科学与光化学, 2014, 32(5): 471-483.
[8]	李秋艳, 李剑, 马望京, 李金培. 不同光敏剂对光敏热成像材料感光性能的影响[J]. 影像科学与光化学, 2014, 32(2): 209-215.
[9]	雷万华, 王雪松. 光动力抗菌光敏剂的研究进展[J]. 影像科学与光化学, 2013, 31(5): 321-334.
[10]	张洪, 李建雄, 刘安华. 阳离子光引发剂敏化的研究进展[J]. 影像科学与光化学, 2013, 31(1): 69-78.
[11]	何礼青, 骆超, 周前雄, 侯原军, 张宝文, 王雪松. 利用静电吸引作用提高光催化放氢效率[J]. 影像科学与光化学, 2011, 29(4): 270-277.
[12]	肖竦, 刘怀志. 四苯基卟啉类光敏剂在醇-酸体系中的光谱性质研究[J]. 影像科学与光化学, 2005, 23(4): 274-280.
[13]	高云燕, 游长江, 陈金平, 李嫕. 硅胶固载光敏剂的合成及其在反式维生素D₃光敏异构化为顺式维生素D₃中的应用[J]. 影像科学与光化学, 2003, 21(1): 20-24.
[14]	马金石. 卟啉类第二代光敏剂的发展[J]. 影像科学与光化学, 2002, 20(2): 131-148.
[15]	高林东, 钱旭红, 张元兴, 张立. 可溶性多氟烷氧基取代金属酞菁:新型肿瘤光动力治疗光敏剂[J]. 影像科学与光化学, 2001, 19(4): 244-249.

4-(4-甲基-苯基)-6-苯基-2,2'-联吡啶铂(Ⅱ)光致产氢研究

Photocatalytic Hydrogen Production Using a Cyclometalated 4-(4-Tolyl)-6-Phenyl-2,2'-Bipyridyl Platinum(Ⅱ) Chloride Complex

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价