光敏型季铵盐类阳离子表面活性剂的合成及表面活性和泡沫性质

doi:10.7517/issn.1674-0475.190301

影像科学与光化学 ›› 2019, Vol. 37 ›› Issue (3): 234-240.DOI: 10.7517/issn.1674-0475.190301

光敏型季铵盐类阳离子表面活性剂的合成及表面活性和泡沫性质

郭茜君, 姜小明

贵州大学化学与化工学院, 贵州贵阳 550025

收稿日期:2019-03-19 出版日期:2019-05-15 发布日期:2019-05-15
通讯作者: 姜小明
基金资助:
贵州省科学技术基金项目（20132097）资助

Preparation of a Photosensitive Cationic Surfactant and Its Surface and Foam Properties

GUO Qianjun, JIANG Xiaoming

Department of Chemistry and Chemical Engineering, Guizhou University, Guiyang 550025, Guizhou, P. R. China

Received:2019-03-19 Online:2019-05-15 Published:2019-05-15

摘要/Abstract

摘要： 本文报道了一种光敏型的阳离子表面活性剂（AZO），其分子结构中含有偶氮苯基团，并研究了光照对表面活性和泡沫性能的影响。经紫外光照射后，表面活性剂的饱和吸附量（Г_max）减小，临界胶束浓度（cmc）、最低表面张力（γ_cmc）和分子极限占有面积（A_min）增大；气泡数目增多，直径变小，发泡能力和泡沫稳定性降低。实验结果证实，该表面活性剂的表面活性和泡沫稳定性可以用光照进行调控。

关键词: 偶氮苯, 表面活性剂, 表面张力, 泡沫稳定性

Abstract: A cationic surfactant with an azobenzene group was prepared, which is AZO. Its molecule structure was identified by ¹HNMR. The surface properties and foam stability were measured before and after UV light irritation. The photoisomerization of the azo-benzene group happened under the UV irradiation. After the UV irradiation, the Г_max values decreased, the values of cmc and γ_cmc increased and the foam stability decreased. The results showed that the surface properties and the foam stability of the surfactant can be controlled using the different light irradiation.

Key words: azobenzene, surfactant, surface tension, foam stability

郭茜君, 姜小明. 光敏型季铵盐类阳离子表面活性剂的合成及表面活性和泡沫性质[J]. 影像科学与光化学, 2019, 37(3): 234-240.

GUO Qianjun, JIANG Xiaoming. Preparation of a Photosensitive Cationic Surfactant and Its Surface and Foam Properties[J]. Imaging Science and Photochemistry, 2019, 37(3): 234-240.

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光敏型季铵盐类阳离子表面活性剂的合成及表面活性和泡沫性质

Preparation of a Photosensitive Cationic Surfactant and Its Surface and Foam Properties

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