荧光探针法研究连接基团对双子型阳离子表面活性剂聚集行为的影响

doi:10.7517/j.issn.1674-0475.2013.01.008

影像科学与光化学 ›› 2013, Vol. 31 ›› Issue (1): 63-68.DOI: 10.7517/j.issn.1674-0475.2013.01.008

荧光探针法研究连接基团对双子型阳离子表面活性剂聚集行为的影响

姜小明^1,2, 张文倩¹, 宋磊¹, 赵濉²

1. 贵州大学化学与化工学院,贵州贵阳 550025;
2. 中国科学院理化技术研究所,北京 100190

收稿日期:2012-05-14 修回日期:2012-06-19 出版日期:2013-01-15 发布日期:2013-01-15
通讯作者: 姜小明,博士,副教授,通讯联系人,E-mail:ming1840@yahoo.com.cn.
基金资助:
国家自然科学基金(21061003 );贵州省工业攻关项目黔科合GY字([2010]3014);贵州省教育厅自然科学研究项目(黔教科2011)022号;贵阳市工业振兴科技计划项目(2011101)4-11号.

Effect of the Nature of the Spacer on the Aggregation Properties of Gemini Cationic Surfactants in the Aqueous Solution Investigated by Fluorescence

JIANG Xiao-ming^1,2, ZHANG Wen-qian¹, SONG Lei¹, ZHAO Sui²

1. School of Chemistry and Chemical Engineering, Guizhou University, Guiyang 550025, Guizhou, P.R.China;
2. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P.R.China

Received:2012-05-14 Revised:2012-06-19 Online:2013-01-15 Published:2013-01-15

摘要/Abstract

摘要： 利用荧光探针法和表面张力法测定了新型双子型阳离子表面活性剂的临界胶团浓度(cmc)、最低表面张力(γ_cmc)、胶团微极性和胶团聚集数(N_agg),探讨了连接基团对此类表面活性剂在水溶液中聚集行为的影响.结果表明,当连接基团增长时,cmc和胶团微极性增加,γ_cmc增大,N_agg减少,表面活性降低,在溶液中自发形成胶团的能力减弱.

关键词: 表面活性剂, 双子型, 聚集, 连接基团

Abstract: The values of cmc, N_aggand micelle micropolarity of the Gemini surfactants have been measured by fluorescence. The nature effect of the spacer on the aggregation properties of Gemini surfactants in the aqueous solution has been investigated. With the increae of spacer length, N_aggdecreased, while the values of cmc, γ_cmc and the micelle micropolarity increased.

Key words: surfactant, Gemini, aggregation, spacer

中图分类号:

O647

姜小明, 张文倩, 宋磊, 赵濉. 荧光探针法研究连接基团对双子型阳离子表面活性剂聚集行为的影响[J]. 影像科学与光化学, 2013, 31(1): 63-68.

JIANG Xiao-ming, ZHANG Wen-qian, SONG Lei, ZHAO Sui. Effect of the Nature of the Spacer on the Aggregation Properties of Gemini Cationic Surfactants in the Aqueous Solution Investigated by Fluorescence[J]. Imaging Science and Photochemistry, 2013, 31(1): 63-68.

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荧光探针法研究连接基团对双子型阳离子表面活性剂聚集行为的影响

Effect of the Nature of the Spacer on the Aggregation Properties of Gemini Cationic Surfactants in the Aqueous Solution Investigated by Fluorescence

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