影像科学与光化学 ›› 1984, Vol. 2 ›› Issue (2): 9-13.DOI: 10.7517/j.issn.1674-0475.1984.02.9

• 研究论文 • 上一篇    下一篇

乳剂颗粒表面上碘离子的减敏作用

战师荣1, 吴桂兰1, 吕光荣1, 刘敦1, 程虎民2   

  1. 1. 中国科学院感光化学研究所;
    2. 北京大学化学系
  • 收稿日期:1983-05-09 出版日期:1984-05-20 发布日期:1984-05-20

ON THE DESENSITIZING EFFECT OF SURFACE IODIDE IN EMULSION GRAINS

ZHAN SHI-RONG1, WU GUI-LAN1, LU GUANG-RONG1, LIU DUN1, CHENG HU-MIN2   

  1. 1. Insititute of Photographic Chemistry, Academia inica;
    2. Department of Chemistry, Peking University
  • Received:1983-05-09 Online:1984-05-20 Published:1984-05-20

摘要: 本文表明双注法乳剂颗粒表面上的碘离子与处在颗粒内部的碘离子相比,前者有三种作用:(1)使颗粒的离子电导率增高;(2)使颗粒表面上的硫加金敏化反应受到抑制,而这又进一步同样使颗粒的离子电导率增高;(3)使乳剂的光敏度降低,由此推测,乳剂颗粒表面上的碘离子对颗粒的减敏作用是与某种使颗粒的离子电导率增高的过程有连系的。

Abstract: A series of double-jet silver halide emulsions are prepared with iodide ions incorporated at different instants of precipitation and thus presumed to locate at different distances from emulsion grain surface. "With iodide ions reaching the grain surface, the emulsion speed falls, the ionic conductivity of the grains rises and, in the case of sulphur-plus-gold sensitization, the drop in ionic conductivity otherwise caused by the sensitization is more than compensated. The desensitizing action of surface iodide, obviously partly due to development retardation, is thought to be connected in some way with the rise in ionic conductivity.