影像科学与光化学 ›› 1985, Vol. 3 ›› Issue (2): 19-25.DOI: 10.7517/j.issn.1674-0475.1985.02.19

• 研究论文 • 上一篇    下一篇

改性明胶沉降剂的研制

刘宣亚, 陈丽娟, 彭必先   

  1. 中国科学院感光化学研究所
  • 收稿日期:1984-05-21 出版日期:1985-05-20 发布日期:1985-05-20

MODIFIED GELATIN AS COAGULATING AGENT IN EMULSION-MAKING

LIU XUAN-YA, CHEN LI-JUAN, PENG BI-XIAN   

  1. Institute of Photographic Chemistry, Academia Sinica
  • Received:1984-05-21 Online:1985-05-20 Published:1985-05-20

摘要: 沉降法在浓缩乳剂的制备中起着很重要的作用,改性明胶沉降剂的应用越来越被人们重视。本文研究了多种改性明胶的合成、取代度的测定、物理性能、沉降条件、沉降过程中明胶及卤化银的回收率和改性明胶卤化银乳剂的感光性能等。研究结果表明:改性明胶沉降剂具有以下的优点:取代度高、沉降诱发期短,沉降的pH范围较窄(一般0.6pH单位),卤化银的回收率高,而改性明胶沉降乳剂的性能比传统的水洗乳剂的性能优异:表现在灰雾小,最大密度高,分辨率好,感光度高和自然保存性能好。文章对造成上述现象的原因也进行了初步的分析和讨论。

Abstract: The coagulation method is of great importance in preparation of concentrated emulsion. The present study is devoted to the following items:1. Synthesis of different modified gelatins2. Evaluation of physical property3. Coagulating performance4. Recovery per cent of PA gelatin and silver halide5. Sensitometric characteristic of emulsion prepared with PA gelatin Modified gelatin is superior to other kinds of copolymer coagulating agent such as polystyrene sulfonate resin due to low cost, shorter induction period to start coagulation, narrower coagulating pH range, less loss of silver halide and better sensitometric property of the emulsion.