β-二酮类化合物光色互变行为的研究

doi:10.7517/j.issn.1674-0475.1991.01.13

影像科学与光化学 ›› 1991, Vol. 9 ›› Issue (1): 13-21.DOI: 10.7517/j.issn.1674-0475.1991.01.13

β-二酮类化合物光色互变行为的研究

张亦帆, 吴世康

中国科学院感光化学研究所, 北京 100101

收稿日期:1989-03-22 修回日期:1990-03-17 出版日期:1991-02-20 发布日期:1991-02-20
通讯作者: 吴世康

A STUDY ON THE PHOTOCHROMIC BEHAVIOR OF β-DIKETONE COMPOUNDS

ZHANG YI-FAN, Wu SHI-KANG

Institute of Photographic Chemistry, Academia Sintca. Beijing 100101, P.R. China

Received:1989-03-22 Revised:1990-03-17 Online:1991-02-20 Published:1991-02-20

摘要/Abstract

摘要： 对几种不同结构的β-二酮化合物光色互变行为进行了研究,发现其中一些化合物具有光色互变行为,而另一些则不能观察到该现象。对该类化合物的光色互变行为的机理进行了讨论和分析。

关键词: β-二酮化合物, 互变异构化, 光色互变, 分子内氢键

Abstract: The photochromic behavior of several kind of β-diketone compound with different structure has been studied. It was found that some compounds studied possess photochromic behavior, but for others listed in this paper, this phenomenon can not be observed. The mechanism of this phenomenon which was observed for some compounds was discussed in detail.

Key words: β-diketone compound, tautomerization, photochromism, intramolecular hydrogen bond

张亦帆, 吴世康. β-二酮类化合物光色互变行为的研究[J]. 影像科学与光化学, 1991, 9(1): 13-21.

ZHANG YI-FAN, Wu SHI-KANG. A STUDY ON THE PHOTOCHROMIC BEHAVIOR OF β-DIKETONE COMPOUNDS[J]. Imaging Science and Photochemistry, 1991, 9(1): 13-21.

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[2]	王凤奇, 郭燕, 樊美公. 光异构化反应的研究——水杨醛缩芳胺席夫碱的吸收光谱与分子结构的关系[J]. 影像科学与光化学, 1989, 7(4): 63-68.

β-二酮类化合物光色互变行为的研究

A STUDY ON THE PHOTOCHROMIC BEHAVIOR OF β-DIKETONE COMPOUNDS

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