影像科学与光化学 ›› 1996, Vol. 14 ›› Issue (4): 347-350.DOI: 10.7517/j.issn.1674-0475.1996.04.347

• 研究简报 • 上一篇    下一篇

10,10’-二烃基-9,9’-联二吖啶烯的电荷转移光谱和氧化反应研究

宋化灿, 潘文龙, 英柏宁, 苏镜娱   

  1. 中山大学化学系, 广州510275
  • 收稿日期:1996-03-06 修回日期:1996-06-24 出版日期:1996-11-20 发布日期:1996-11-20
  • 通讯作者: 宋化灿
  • 基金资助:
    国家自然科学基金

STUDY ON CHARGE TRANSFER SPECTRA AND OXIDIZATION OF 10,10’-DIALKYL-9,9’-BIACRIDENS

SONG Huacan, PAN Wenlong, Ying Baining, SU Jingyu   

  1. Department of Chemistry, Zhongshan University, Guangzhou 510275, P. R. China
  • Received:1996-03-06 Revised:1996-06-24 Online:1996-11-20 Published:1996-11-20

摘要: 研究了10,10'-二烃基-9,9'-联二吖啶烯的DDQ的电荷转移光谱,用两种方法计算出了它们的电离热(Ip)值,并研究了该系列化合物与DDQ、TCNE和CA的氧化反应,其氧化结果和用HNO3氧化所得到的10,10'-烃基-9,9'-联二吖啶硝酸盐结果一致。在DDQ、TCNE和CA中,只有DDQ可以和该系列化合物形成CTC,其原因是DDQ有弱的氧化能力而有强的络合能力。

关键词: 10,10-二烃基-9,9’-联二吖啶烯, 电荷转移络合物, 紫外光谱, 电离势

Abstract: Acridine derivatives,e. g. amsacrine[1] and antimicrobial[2,3] drugs,are known as anticancer drugs from the point of view of biology and 10,10’-dialkyl-9,9’-biacridinium nitrates are called lucigenin which were used as reagent in chemical analysis[4,5] The solutions of 10. 10’-dialkyl-9,9’-bialkylacridens have strong fluorescence and it is found that the bialkylacridens can be oxidized easily by the air,so they may be used der to investigate the charge donation ability of the biacridens,ten 10,10'-dialkyl-9,9'-biacridens were synthesized by the reduction of corresponding N-alkylacridones with Zn powder and hydrogen chloride and ethyl alcohol.

Key words: 10,10’-dialkyl-9,9’-biacriden, charge transfer complexes, UV, ionization potential