影像科学与光化学 ›› 2000, Vol. 18 ›› Issue (4): 316-322.DOI: 10.7517/j.issn.1674-0475.2000.04.316

• 研究论文 • 上一篇    下一篇

硫敏化中心中的银原子簇的增感作用

史瑶, 夏培杰, 杨新民, 姚林辉, 郑彤, 赵文芳   

  1. 中国科学院感光化学研究所, 北京100101
  • 收稿日期:2000-05-21 修回日期:2000-07-19 出版日期:2000-11-20 发布日期:2000-11-20
  • 通讯作者: 赵文芳(1941- ),女,研究员,博士生导师,主要从事卤化银体系的成像过程研究,通讯联系人.
  • 基金资助:
    国家自然科学基金资助项目(29873054);美国柯达公司资助项目

SENSITIZATION OF SILVER CLUSTERS IN SULFUR SENSITIZATION CENTERS

SHI Yao, XIA Pei-jie, YANG Xin-min, YAO Lin-hui, ZHENG Tong, ZHAO Wen-fang   

  1. Institute of Photographic Chemistry, Chinese Academy of Sciences, Bejing 100101, P. R. China
  • Received:2000-05-21 Revised:2000-07-19 Online:2000-11-20 Published:2000-11-20

摘要: 采用一定电位范围内的氧化还原缓冲液处理单分散立方溴化银乳剂颗粒表面上的硫敏化中心和由曝光生成的潜影中心,考察银原子簇的漂白和再生后的曝光响应曲线.实验结果再一次确认硫敏化中心中存在的银原子簇对硫敏化起重要作用,而且敏化效果也与银原子簇的含量有关.为此,提出硫敏化中心是由硫化银簇与银簇组成,它们在潜影形成的过程中各起不同的作用,但都有利于提高潜影的生成效率,因而共同产生敏化效应.

关键词: 硫敏化, 潜影形成, 氧化还原缓冲液

Abstract: Redox buffers in the range of certain potentials were adopted to treat both sulfur sensitization centers on the surface of mono dispersed cubic silver bromide and latent image centers formed during exposures in order to examine their respective response curves after bleaching and regeneration of silver clusters. Experimental results confirmed that there were silver clusters in the sulfur sensitization centers, which played an important role in the sulfur sensitization as well as the sensitization efficiency seemed to be related to content of silver. For this reason, it has been proposed that the sulfur sensitization centers consist of silver sulfide clusters and silver clusters, in which these two kinds of clusters may have different functions in the process of latent image formation, but both are advantageous to increase in the efficiency of LI formation.

Key words: sulfur sensitization, latent image formation, redox buffers

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