影像科学与光化学 ›› 1997, Vol. 15 ›› Issue (3): 193-199.DOI: 10.7517/j.issn.1674-0475.1997.03.193

• 研究快讯 •    下一篇

A STUDY OF THE STABILIZING CAPACITY OF GLYCINE TOWARD SILVER CLUSTER Ag42+ IN AQUEOUS SOLUTION

崔卫东, 彭必先   

  1. 中国科学院感光化学研究所, 北京 100101
  • 收稿日期:1997-04-15 修回日期:1997-05-06 出版日期:1997-08-20 发布日期:1997-08-20
  • 通讯作者: 彭必先
  • 基金资助:
    国家自然科学基金(批准号: 29473138)

A STUDY OF THE STABILIZING CAPACITY OF GLYCINE TOWARD SILVER CLUSTER Ag42+ IN AQUEOUS SOLUTION

CUI Weidong, PENG Bixian   

  1. Institute of Photographic Chemistry, Chinese Acadmyg of Sciences, Beijing 100101, P. R. china
  • Received:1997-04-15 Revised:1997-05-06 Online:1997-08-20 Published:1997-08-20

摘要: 本文用溴钨灯照射含异丙醇、甘氨酸(稳定剂)和硝酸银的水溶液制得非金属银团簇Ag42+(λmax=275nm),其产率随甘氨酸量的增加而增加,并且在空气中甘氨酸可以稳定其数天。对所得结果以及Ag42+在照相潜影形成过程中的可能作用进行了讨论。本文用溴钨灯照射含异丙醇、甘氨酸(稳定剂)和硝酸银的水溶液制得非金属银团簇Ag42+max=275nm),其产率随甘氨酸量的增加而增加,并且在空气中甘氨酸可以稳定其数天。对所得结果以及Ag42+在照相潜影形成过程中的可能作用进行了讨论。

关键词: 甘氨酸, 银团簇, 稳定能力, 潜影形成

Abstract: Atom clusters, aggregate consisting of a few to thousands of atoms, have many strange properties, such as unusual chemical reactivity/catalytic activity, quantum size effect, dras-tic surface-to-bulk ratio, even-odd property, magic number, etc. These particular features have focused the at tention of many scientists in different fields, such as, catalysis chemistry, meteorological physics, environmental chemistry and photographic science. Great progress has been made in a effort to correlate the cluster structure with performance. The studies on silver clusters have been confined to clusters in silver vapor or in supersonic beams in vacuo[1], in matrix at low temperature[2], in zeolite[3] and in photographic plates[4]. In aqueous solution, silver clusters were made using the method of 60Co γ-radiolysis or pulse radiolysis by high energy electrons.

Key words: glycine, silve cluster, stabilizing capacity, latent image formation