影像科学与光化学 ›› 2003, Vol. 21 ›› Issue (6): 432-445.DOI: 10.7517/j.issn.1674-0475.2003.06.432
曹立志, 王晗, 焦家俊, 庄思永
收稿日期:
2003-04-17
修回日期:
2003-05-21
出版日期:
2003-11-23
发布日期:
2003-11-23
通讯作者:
庄思永
基金资助:
CAO Li-zhi, WANG Han, JIAO Jia-jun, ZHUANG Si-yong
Received:
2003-04-17
Revised:
2003-05-21
Online:
2003-11-23
Published:
2003-11-23
摘要: 从感光乳剂硫增感敏化中心的形成和作用机理等方面对硫增感过程进行了综合叙述,并对硫敏化中心的分布、增感条件、增感中心的性质、增感团簇的研究、新型的硫增感手段等方面的理论进展也作了讨论.
中图分类号:
曹立志, 王晗, 焦家俊, 庄思永. 卤化银成像体系中的硫增感[J]. 影像科学与光化学, 2003, 21(6): 432-445.
CAO Li-zhi, WANG Han, JIAO Jia-jun, ZHUANG Si-yong. SULFUR SENSITIZATION IN THE SILVER HALIDE IMAGING SYSTEM[J]. Imaging Science and Photochemistry, 2003, 21(6): 432-445.
[1] Sheppard S E.Photographic gelatin[J].Photogr.J.,1925,65:380-387. [2] Steigmann A.Photographic reactions of chlorophyl,hemin and humic acid[J].Camera(Lucerne),1926,4:209-211. [3] Wood H W.Nature of the sensitizing substance of gelatin[J].Sci.et Inds.Phot.,1952,23(2):209-217. [4] Wood H W.The examination of gelatin extracts and polythionates by means of paper electrophoresis[J].J.Photo.Sci.,1954,2:154-159. [5] Russell G.Determination of photographic sensitizers in gelatin[J].J.Photo.Sci.,1956,4:94-100. [6] Chibissov K V,Titov A A,Mikhailova A A.New data on the nature of photographic sensitivity[J].J.Photo.Chem.,1947,21:643-652. [7] Sheppard S E.Effect of concentration of sensitizer on speed[J].Photogr.J.,1926,66:399-406. [8] Balls A,Harvey J F.The cluster mechanism in sulfur sensitization[J].J.Photogr.Sci.,1967,15(6):258-264. [9] Venet A,Chateau H, Pouradier J.Dismutation of thiosulfate into sulfide in the presence of silver bromide(Ⅳ)[J].Sci.et Inds.Phot.,1958,29:219-223. [10] Chateau H, Pouradier J.The dismutation of thiosulfate into sulfide in presence of silver bromide(Ⅴ)[J].Sci.et Inds.Phot.,1960,31:261-266. [11] Spracklen D M.Silver sulfide formation during thiosulfate sensitization[J].J.Photogr.Sci.,1966,14:220-227. [12] Spracklen D M.The adsorption of thiosulfate ions on emulsion grains,and the role of these adsorption ions in silver sulfide formation[J].J.Photogr.Sci.,1967,15:249-257. [13] Frieser H.,Ranz E.Investigation of the sulfur sensitization of photographic emulsion by the application of 35S[J].Ber.Bunsenges.Phys.Chem.,1964,68:389-399. [14] Peelaers W,Claes F H.Influence of interstial silver ions on the silver sulfide formation at the surface of silver bromide microcrystals[J].Photogr.Korresp.,1967,103(7):101-103. [15] Takiguchi H T.Silver sulfide formation during thiosulfate digestion in the presence of tetraazaindene[J].Nippon Shashin Gakkaiki,1985,48(6):424-431. [16] Oleshko V P,Alfimov M V,Cui X F,et al.Study of sulphur sensitization produces on the surface of tabular grains of silver halide emulsions by means of analytical electron microscopy and image analysis[J].J.Photogr.,Sci.,1994,42:110-116. [17] 胡勇军,王荣琴,彭必先.电镱法对硫敏化中心的直接观察[J].感光科学与光化学,1997,15(3):230-233.Hu Y J,Wang R Q,Peng B X.Direct observation on the sulfur sensitization centers with electron microscopy[J].Photographic Science and Photochemistry,1997,15(3):230-233. [18] Yoshida Y.A Quantitative Study of Sulfur Sensitization by Use of Several Labelled Sulfur Sensitizers[C].In:Proceeding of Autumn Meeting of Soc.Photogr.Sci.Technol.Jpn., Japan:Nara.1992. [19] Peelaers W,Claes F H.Influence of interstitial silver ions on the silver sulfide formation at surface of silver bromide microcrystals[J].Photogr.Korresp.,1967,103:101-103. [20] Peelaers W,Claes F H.Influence of environment on the habit of silver bromide microcrystals during the precipitation[J].Photogr.Korresp.,1958,104:12-15. [21] Moisar E.A study of sulfur sensitization at definite silver bromide crystal faces[J].J.Photogr.Sci.,1966,14:181-184. [22] Moisar E.A Kinetic and sensitometric investigation of sulphur ripening[J].J.Photogr.Sci.,1968,16:102-113. [23] Moisar E.Kinetics of silver sulfide for mation on silver bromide crystals of different surface structure[J].Ber.Bunsenges.Phys.Chem.,1968,72:467-474. [24] Cash D J.Adsorption and Desorption of thiosulphate at solid silver salts[J].J.Photogr.Sci.,1972,20:19-24. [25] Cash D J.Adsorption and photographic sulphur sensitizers to silver bromide and silver sulphide[J].J.Photogr.Sci.,1972,20:77-80. [26] Cash D J.The Rate of Sulfide formation during sulfur sensitization:measuerment of proton evolution[J].J.Photogr.Sci.,1972,20:107-120. [27] Cash D J.The kinetics of sulphur sensitization;sulphide migration during digestion[J].J.Photogr.Sci.,1972,20:223-227. [28] Ridgeway M,Hillson P J.Sulfur sensitization:Measurement of the activation energy[J].J.Photogr.Sci.,1975,23:153-156. [29] Corbin D,Gingello A,Macintyre G,et al.Effects of stabilizers on chemical sensitization of silver halide emulsions[J].Photogr.Sci.,Eng.,1980,24(1):45-49. [30] Roth P H,Simpson W H.Anomalies in the kinetics of chemical sensitization[J].Photogr.Sci.Eng.,1980,24:133-137. [31] Keevert J E,Gokhale V V.A study of reaction and aggregation steps in sulfur sensitization and role of tetraazaindene[J].J.Imaging Sci.,1987,31:243-249. [32] Tadakuma Y,Yoshida Y,Kanzaki H.A study of aggregation process of sulfur sensitization centers on AgBr emulsion grains[C].In:The Annual Conference of Soc.Photogr.Tech.Jpn.,Makuhari,Chiba,1990. [33] Takiguchi H.Effects of tetraazainden on reaction and aggregation process in sulfur sensitization with thiosulfate[J].J.Imaging Sci.,1988,32(1):20-27. [34] Van Doorselaer M K.Solid state properties and photographic activity of crystalline Ag2S- and (Ag,Au)2S specks at the surface of silver halide crystals[J].J.Photogr.,Sci.,1987,35:42-54. [35] Chibisov K V.The nature and function of local defects in the emulsion microcrystals[J].J.Photo.Sci.,1958,7:41-53. [36] Sheppard S E,Trivelli A P H,Wichtman E P.Production of sensitizing specks on silver halide grains[J].Phot.J.,1927,67:271-3. [37] Sheppard S E.Optical sensitizing of silver halide emuslsions.I.Adsorption of orthochrome T to silver bromide[J].J.Phys.Chem.,1928,32:751-62. [38] Gurney R W,Mott N F,Proc Roy.Theory of the photolysis of silver bromide and the photographic latent image[J].Soc.(London Ser.A),1938,164:151. [39] Hamilton J F,Harbison J M,Jeanmaire D J.Energy levels of sulfur sensitizer centers[J].J.Imaging Sci.,1988,32:17-19. [40] Kellogg L M,Hodes J.The measurement of electron trap depths for sulfur and sulfur-plus-gold centers in AgBr emulsions using thermally stimulated current techniques[C].In: Proceeding of The 40th Annual Conference of SPSE,Rochester,New York,1987. [41] Kellogg L M,Liebert N B,James T H.Investigation of photoconductivity in photographic films at 77℃K with microwave methods[J].Photogr.Sci.Eng.,1972,16:115-9. [42] 梁庚新.化学增感对潜影分布的影响[J].感光材料,1997,2:12-14.Liang G X.The effect of chemical sensitization on the latent distrubution[J].Photographic Materials,1997,2:12-14. [43] Hickman K C D.Chemical aspect of sulfide sensitizing[J].Phot.J.,1927,67:34-41. [44] Mitchell J W.The nature of photographic sensitivity[J].J.Photogr.Sci.,1957,5:49-70. [45] Mitchell J W.Photographic sensitivity[J].J.Photogr.Sci.,1958,63(3):57-80. [46] Mitchell J W.The concentration theory of latent image formation[J].Photogr.Sci,Eng.,1978,22(5):249-255. [47] Farnell G C,Flint R B,Brich D C.Direct observations on the distribution of silver sulphide of sensitized emulsion grains[J].J.Phys.Chem.,1977,25:203-207. [48] Tani T.Photographic effects of electron and positive hole traps.Chemical sensitization,reducing agents,and phenosafranine[J].Photogr.Sci.Eng.,1971,15:25-41. [49] Tani T.Characterization of sensitization centers and fog centers formed during digestion for sulfur sensitization[J].J.Imaging Sci.and Tech.,1995,39(5):386-392. [50] Mitchell J W.On the role of sulfide molecules in photographic sensitivity[J].J.Imaging Sci.and Tech.,1998,42:215-221. [51] Belous V M,Tolstobrov V I,Chibisov K V.Extrinsic light sensitivity and luminescence excitation spectra of homogeneous sulfur-sensitized silver bromide emulsions[J].Dokl.Akad.Nauk USSR,1979,244:628-320. [52] Tani T.Discussion on a model for sulfur sensitization and fog centers[J].J.Imaging Sci.and Tech.,1998,42:135-43. [53] 史瑶,赵文芳,杨新民,等.硫增感的敏化中心和潜影中心的氧化还原性能的研究[J].感光科学与光化学,2000,18(2):150-154.Shi Y,Zhao W F,Yang X M,et al.Study on the redox properties of sulfur sensitivity centers and latent image centers[J].Photographic Science and Photochemistry,2000,18(2):150-154. [54] 史瑶,夏培杰,杨新民,等.硫敏化中心中的银原子簇的增感作用[J].感光科学与光科学,2000,18(4):316-322.Shi Y,Xia P J,Yang X M,et al.Sensitization of silver clusters in sulfur sensitization centers[J].Photographic Science and Photochemistry,2000,18(4):316-322. [55] 李金培,王素娥.碘和硫增感剂在卤化银颗粒表面的分布[J].感光科学与光化学,1997,15(2):101-103.Li J P,Wang S E.Distribution of iodide and sulphur at silver halide microcrystal surface[J].Photographic Science and Photochemistry,1997,15(2):101-103. [56] 王荣琴,杨赣.照相稳定剂583对扁平卤化银乳剂微晶的增感作用[J].感光材料,1997,3:21-24.Wang R Q,Yang G.Sensitization function of photographic stabilizer 583 in tabular silver halide microcrystals[J].Photographic Materials,1997,3:21-24. [57] 王巍,彭彦彬,余青,等.影响硫增感因素的初步研究[J].感光材料,1996,1:25-28.Wang W,Peng Y B,Yu Q,et al.Study of influnences of some factors on sulfur sensitization[J].Photographic Materials,1996,1:25-28. [58] Kanzaki H, Tadakuma Y.Electronic processes in chemically-sensitized emulsion grains of silver bromide[J].J.Phys.Solids,1994,55(7):631-645. [59] Kanzaki H,Tadakuma Y.Luminescence and luminescence-modulation studies on chemical sensitizer centers in emulsion grains of silver bromide[J].J.Phys.Chem.Solids,1997,58(2):221-233. [60] Mifune H.A study of location of latent image centers formed on sulfur-sensitized silver bromide grains.Ⅱ. The location control of latent image centers by use of cyanine dyes and TAI[J].Nippon Shashin Gakkaishi,1999,62(3):196-208. [61] Mifune H.Enhancement of silver nuclei formation by sulfur-sensitization centers on silver bromide grains[J].J.Imaging Sci.and Tech.,2002,46(2):117-122. [62] Hailstone R K,Zhao T,Difrancesco A G,et al.Sulfide centers on(111) AgBr surfaces:Characterization[J].J.Imaging Sci.Tech.,2001,45(1):76-82. [63] 彭必先,崔卫东,于忠德,等.银硫二元团簇形成与光过程的硫敏化[J].中国科学(B辑),1997,27(3):221-227.Peng B X,Cui W D,Yu Z D,et al.The formation of silver sulfur binary cluster and the sulfur sensitization in the photographic process[J].Science in China(Series B),1997,27(3):221-227. [64] 崔卫东,彭必先,高振.增感团簇的形成、功能与催化活性研究[J].感光科学与光化学,1998,16(4):371Cui W D,Peng B X,Gao Z.The study of the formation,functions and catalytic activity of sensitizing cluster[J].Photographic Science and Photochemistry,1998,16(4):371 [65] 赵翔,彭必先,高振.Ag(Ag2S)n/AgBr支持团簇的形成及分子催化活性研究[J].感光科学与光科学,1999,17(4):376Zhao X,Peng B X,Gao Z.The study of the formation and molecular catalytic activity of the cluster[J].Photographic Science and Photochemistry,1999,17(4):376 [66] 崔勐,封继康,葛茂发,等.硫银二元团簇[Ag*(Ag2S)n]+(n=1,2)的从头计算研究[J].高等学校化学学报[J],1999,20(3):436-439.Cui M,Feng J K,Ge M F,et al.Ab initio study of silver-sulfur binary [Ag*(Ag2S)n]+(n=1,2) cluster[J].Chem.J.Chinese Universities,1999,20(3):436-439. [67] 崔勐,封继康,葛茂发,等.硫银二元团簇[Ag*(Ag2S)n]+(n=3,4)]的从头计算研究[J].化学学报1999,57:673-679.Cui M,Feng J K,Ge M F,et al.Ab initio study of silver-sulfur binary [Ag*(Ag2S)n]+(n=3,4) cluster[J].Acta Chimica Sinica, 1999,57:637-679. [68] Philip S,Arthur H.Silver halide photosensitive material[P].US patent,4 713 322.1987-12-15. [69] George J,Arthur H.Silver halide photosensitive materials containing thiourea and analogue compounds[P].US Patent,4 810 626.1989-03-07. [70] John J,Terry L.Identification of viral associated immunoreactants in biological[P].US Patent,4 810 629.1989-03-07. [71] 李晓玲,周本茂,张成刚.冠醚化合物对乳剂的增感作用[J].感光科学与光化学,1994,12(3):201-206.Li X L,Zhou B M,Zhang C G.The sensitizing effects of crown compounds on AgBr emulsion[J].Photographic Science and Photochemistry,1994,12(3):201-206. [72] 崔海萍,闫军,李健芳.Zn(Ⅱ)-EDTA对细微粒卤化银乳剂起增感作用的研究[J].信息记录材料,2002,3:17-19.Cui H P,Yan J,Li J F.The research on the additional sensitizing effects of Zn(Ⅱ)-EDTA[J].Information Recording Materials,2002,3:17-19. [73] 史瑶,姚林辉,赵文芳,等.苯并三氮唑对硫增感溴化银乳剂的过增感效应[J].感光科学与光化学,2002,20(5):326-334.Shi Y,Yao L H,Zhao W F,et al.Hypersensitization of sulfur-sensitized emulsion by benzotriazole[J].Photographic Science and Photochemistry,2002,20(5):326-334. [74] 李金培,唐(日文)骜,王素娥.纳米尺寸ZnS化学增感剂[J].感光科学与光化学2001,19(4):241-243.Li J P,Tang M A,Wang S E.Nanosized ZnS chemical sensitizer[J].Photographic Science and Photochemistry,2001,19(4):241-243. [75] 许春华,李金培,唐旻骜,等.纳米尺寸硫化镍化学增感剂[J].感光科学与光化学,2002,20(5):321-325.Xu C H,Li J P,Tang M A,et al.Nanosized NiS chemical sensitizer[J].Photographic Science and Photochemistry,2002,20(5):321-325. |
[1] | 李智, 段培成, 杨新民, 郑彤. 反相微乳液法制备纳米Ag2S增感剂的化学增感研究[J]. 影像科学与光化学, 2008, 26(5): 385-392. |
[2] | 王英茹, 柳青. K4[Ru(CN)6]对T-颗粒溴碘化银乳剂感光性能及光电子寿命影响的研究[J]. 影像科学与光化学, 2008, 26(3): 244-253. |
[3] | 马望京, 夏培杰. 甲酸盐掺杂立方八面体溴化银乳剂颗粒的增感效应研究[J]. 影像科学与光化学, 2006, 24(6): 408-414. |
[4] | 李智, 郑彤, 史京京, 王颖, 彭必先, 陈丽娟. 氯化银立方体微晶乳剂和{100}面扁平微晶乳剂的甲酸盐掺杂增感[J]. 影像科学与光化学, 2006, 24(5): 343-350. |
[5] | 马望京, 国红, 夏培杰. 溴化银乳剂中甲酸盐掺杂的位置效应研究[J]. 影像科学与光化学, 2005, 23(1): 29-36. |
[6] | 史瑶, 智欣, 夏培杰, 赵文芳. AgBr核壳乳剂的颗粒内部还原增感与表面化学增感的协同增感效应[J]. 影像科学与光化学, 2004, 22(5): 333-342. |
[7] | 智欣, 史瑶, 曹静, 夏培杰. AgBrⅠ核壳乳剂的还原敏化与硫加金敏化的协同增感效应[J]. 影像科学与光化学, 2004, 22(5): 350-356. |
[8] | 刘霁, 宋磊, 岳军. 纳米尺度AgBr/I乳剂颗粒的光电子衰减行为[J]. 影像科学与光化学, 2004, 22(2): 81-87. |
[9] | 史京京, 滕淑华, 吴珊, 彭必先, 陈丽娟, 倪景华. 氯化银T-颗粒乳剂制备专用的氧化明胶的研究[J]. 影像科学与光化学, 2004, 22(1): 13-19. |
[10] | 曹立志, 王晗, 焦家俊, 庄思永. 原子力显微镜观察T-颗粒乳剂晶体形貌[J]. 影像科学与光化学, 2003, 21(5): 334-337. |
[11] | 杨少鹏, 董国义, 陆晓东, 李晓苇, 傅广生. 硫增感AgBr I T颗粒乳剂光电子行为研究[J]. 影像科学与光化学, 2003, 21(3): 176-183. |
[12] | 孙承华, 段培成, 周树云, 陈萍. 短波长菁染料对氯化银乳剂的光谱增感作用[J]. 影像科学与光化学, 2003, 21(3): 184-189. |
[13] | 杨晓玲, 庄思永. 改善高氯卤化银乳剂的高照度性能[J]. 影像科学与光化学, 2003, 21(2): 107-113. |
[14] | 闫军, 崔海萍, 黄鹏波, 张胜. 磁场作用对明胶中卤化银乳剂制备的影响及机理探讨[J]. 影像科学与光化学, 2002, 20(5): 358-362. |
[15] | 戴晖, 梁冰, 庄思永, 孙健, 张大德. [Fe(CN)6]4-在溴碘化银T-颗粒乳剂中的掺杂[J]. 影像科学与光化学, 2001, 19(4): 262-267. |
阅读次数 | ||||||
全文 |
|
|||||
摘要 |
|
|||||