共轭聚合物/C60复合体系及其在光伏打电池中的应用

doi:10.7517/j.issn.1674-0475.2002.01.69

影像科学与光化学 ›› 2002, Vol. 20 ›› Issue (1): 69-77.DOI: 10.7517/j.issn.1674-0475.2002.01.69

• 综述 • 上一篇

共轭聚合物/C₆₀复合体系及其在光伏打电池中的应用

黄红敏, 贺庆国, 蔺洪振, 杨俊林, 白凤莲

中国科学院, 化学研究所, 分子科学中心, 有机固体开放实验室, 北京, 100080

收稿日期:2001-04-20 修回日期:2001-04-27 出版日期:2002-01-23 发布日期:2002-01-23
通讯作者: 白凤莲,Tel:010-62577367,E-mail:baifl@infoc3.icas.ac.cn
基金资助:
国家自然科学基金(29992530和50083002)及国家重点基础研究发展规划资助(G2000028200)

CONJUGATED POLYMER/C₆₀ COMPOSITES AND THEIR APPLICATION IN PHOTOVOLTAIC CELLS

HUANG Hong-min, HE Qing-guo, LIN Hong-zhen, YANG Jun-lin, BAI Feng-lian

Laboratory of Organic Solids, Center for Molecular Science, Institute of Chemistry, The Chinese Academy of Sciences, Beijing 100080, P. R. China

Received:2001-04-20 Revised:2001-04-27 Online:2002-01-23 Published:2002-01-23

摘要/Abstract

摘要： 共轭聚合物/C₆₀复合体系在有机太阳能电池中的应用引起了化学工作者的广泛兴趣.本文介绍了共轭聚合物/C₆₀复合体系的光诱导电子转移,以及近年来该体系在光伏打电池中的研究进展.

关键词: 光伏打电池, 共轭聚合物, 光诱导电子转移

Abstract: The composites of conjugated polymer/C₆₀ system have attracted much interest in the field of organic solar cells.Studies on photoinduced electron transfer and recent advancements of conjugated polymer/C₆₀ composites in photovoltaic cells are reviewed.

Key words: photovoltaic cell, conjugated polymer, photoinduced electron transfer

中图分类号:

O644

黄红敏, 贺庆国, 蔺洪振, 杨俊林, 白凤莲. 共轭聚合物/C₆₀复合体系及其在光伏打电池中的应用[J]. 影像科学与光化学, 2002, 20(1): 69-77.

HUANG Hong-min, HE Qing-guo, LIN Hong-zhen, YANG Jun-lin, BAI Feng-lian. CONJUGATED POLYMER/C₆₀ COMPOSITES AND THEIR APPLICATION IN PHOTOVOLTAIC CELLS[J]. Imaging Science and Photochemistry, 2002, 20(1): 69-77.

参考文献

[1] Karg S,Riess W,Dyakonov V,et al.Electrical and optical characterization of poly(phenylene-vinylene)light emitting diodes[J].Synth.Met.,1993,54:427.
[2] Yu G,Zhang C,Heeger A J.Dual-function semiconducting polymer devices:light emitting and photodetecting diodes[J].Appl.Phys.Lett.,1994,64:1540.
[3] Yu G,Pakbaz K,Heeger A J.Semiconducting polymer diodes:large size,low cost photodetectors with excellent visible-ultraviolet sensitivity[J].Appl.Phys.Lett.,1994,64:3422.
[4] Sariciftci N S,Smilowitz L,Heeger A J,et al.Photoinduced electron transfer from a conducting polymer to Buckminsterfullerene[J].Science,1992,258:1474.
[5] Sension R J,Szarka A Z,Smith G R,et al.Ultrafast photoinduced electron transfer to C₆₀[J].Chem.Phys.Lett.,1991,185:179.
[6] Wang Y.Photoconductivity of fullerene-doped polymers[J].Nature,1992,356:585.
[7] Wang Y.Photophysical properties of fullerene and fullerene/N,N-diethylaniline charge-transfer complexes[J].J.Phys.Chem.,1992,96:764.
[8] Sariciftci N S,Smilowitz L,Heeger A J,et al.Semiconducting polymers(as donors)and Buckminsterfullerene(as acceptor):photoinduced electron transfer and heterojunction devices[J].Synth.Met.,1993,59:333.
[9] Morita S,Zarkhidov A A,Yoshino K.Doping effect of Buckminsterfullerene in conducting polymer:change of absorption spectrum and quenching of luminescence[J].Solid State Commun.,1992,82:249.
[10] Smilowitz L,Sariciftci N S,Wu R,et al.Photoexcition spectroscopy of conducting polymer-C₆₀ fullerene composites:photoinduced electron transfer[J].Phys.Rev.,B:Condens.Matter.,1993,47:13835.
[11] Lee C H,Yu G,Sariciftci N S,et al.Sensitization of the photoconductivity of conducting polymers by C₆₀:photoinduced electron transfer[J].Phys.Rev.,B:Condens.Matter.,1993,48:15425.
[12] Wei X,Vardeny Z V,Sariciftci N S,et al.Absorption-detected magnetic resonance studies of photoexciton in conjugated-polymer/C₆₀composites[J].Phys.Rev.,B:Condens.Matter.,1996,53:2187.
[13] Kraabel B,Mcbranch D,Sariciftci N S,et al.Ultrafast spectroscopic studies of photoinduced electron transfer from semiconducting polymers to C₆₀[J].Phys.Rev.,B:Condens.Matter.,1994,50:18.
[14] Lee K H,Janssen R A J,Sariciftci N S,et al.Direct evidence of photoinduced electron transfer in conducting polymer-C₆₀ composites by infrared photoexcitation spectroscopy[J].Phys.Rev.,B:Condens.Matter.,1994,49:5781.
[15] Sariciftci N S,Heeger A J.Conjugated polymer-acceptor heterojunctions;diodes,photodiodes and photovoltaic cells[J].Int.J.Mod.Phys.B,1994,8:237.
[16] Yamashita Y,Takashima W,Kaneto K.Characteristics of heterojunction diode of fullerene (C₆₀)/tetrathiafulvalene(TTF)[J].Jpn.J.Appl.Phys.,1993,32:L1017.
[17] Morita S,Zakhidov A A,Yoshino K.Wavelength dependence of junction characteristics of poly(3-alkylthiophene)/C₆₀ fullerene layer[J].Jpn.J.Appl.Phys.,1993,32:L873.
[18] Zakhidov A A,Taka K,Yoshino K.Organic multilayered photocell with enhanced separation of charges at polarization double barriers[J].Synth.Met.,1995,71:2113.
[19] Kallinger C,Handeer M,Haugeneder A,et al.Control of electron transfer in conjugated polymer/fullerene heterostructures[J].Synth.Met.,1999,101:285.
[20] Sariciftci N S,Broun D,Zhang C,et al.Semiconducting polymer-Buckminsterfullerene heterojunctions:Diodes,photodiodes and photovoltaic cells[J].Appl.Phys.Lett.,1993,62:585.
[21] Yu G,Gao J,Hummelon J C,et al.Polymer photovoltaic cells:Enhanced efficiencies via a network of internal Donor-Acceptor heterojunctions[J].Science,1995,270:1789.
[22] Johansson H,Brabec C J,Neugebauer H,et al.Photoinduced FT-IR spectroscopy of conjugated polymer/fullerene composites embedded into conventional host polymer matrices[J].Synth.Met.,1999,101:192.
[23] Brabec C J,Padinger F,Hummelen J C,et al.Realization of large area flexible fullerene-conjugated polymer photocells:a route to plastic solar cells[J].Synth.Met.,1999,102:861.
[24] Brabec C J,Johansson H,Padinger F,et al.Photoinduced FT-/IR spectroscopy and CW-photocurrent of conjugated polymers and fullerenes blended into conventional polymer matrices[J].Solar Energy Materials and Solar Cells,2000,61:19.
[25] Halls J J M,Pichler K,Friend R H,et al.Exciton dissociation at a poly(p-phenylenevinylene)/C₆₀ heterojunction[J].Synth.Met.,1996,77:277.
[26] Feldrapp K,Brutting W,Schwoerer M,et al.Photovoltaic effect in blend systems and heterostructures of poly(p-phenylenevinylene)[J].Synth.Met.,1999,101:156.
[27] Tang C W.Two-layer organic photovoltaic cell[J].Appl.Phys.Lett.,1986,48:183.
[28] Gao J,Hide F,Wang H.Efficient photodetectors and photovoltaic cells from composites of fullerenes and conjugated polymers:photoinduced electron transfer[J].Synth.Met.,1997,84:979.
[29] Fromherz T,Padinger F,Gebeyehu D,et al.Comparison of photovoltaic devices containing various blends of polymers and fullerene derivates[J].Solar Energy Materials and Solar Cells,2000,63:61.
[30] Ago H,Petritsch K,Shaffer M S P,et al.Composites of carbon nanotubes and conjugated polymers for photovoltaic devices[J].Adv.Mater.,1999,11:1281.
[31] Sariciftci N S.Polymeric photovoltaic materials.Current Opinion in Solid State and Materials Science[J],1999,4:373.

共轭聚合物/C₆₀复合体系及其在光伏打电池中的应用

CONJUGATED POLYMER/C₆₀ COMPOSITES AND THEIR APPLICATION IN PHOTOVOLTAIC CELLS

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	崔倩玲, 叶荣琴, 李立东. 基于能量转移机理的水溶性荧光共轭聚合物体系的设计制备及应用[J]. 影像科学与光化学, 2017, 35(4): 429-444.
[2]	肖林红, 李慧, 成春贵, 耿建新. 石墨烯/有机共轭体系的光热效应与应用[J]. 影像科学与光化学, 2017, 35(4): 464-476.
[3]	杨科, 张艳, 徐建华. 电子转移光氧化反应在有机合成中的应用[J]. 影像科学与光化学, 2014, 32(5): 433-446.
[4]	王建武, 朱春雷, 冯丽恒, 袁焕祥, 吕凤婷, 刘礼兵, 王树. pH值响应的共轭聚合物纳米粒子的制备、表征与细胞成像研究[J]. 影像科学与光化学, 2014, 32(1): 121-130.
[5]	王中丽, 高云燕, 欧植泽, 郭创龙, 李海霞, 金和林. 异咯嗪修饰富勒烯-聚丙烯酸的合成及其与DNA的相互作用[J]. 影像科学与光化学, 2011, 29(3): 181-193.
[6]	李旭兵, 王晓军, 王格侠, 邢令宝, 张丽萍, 佟振合, 吴骊珠. 环双(百草枯对苯撑)-双2-萘甲酸三缩四乙二醇酯二元超分子给受体体系光诱导电子转移研究[J]. 影像科学与光化学, 2010, 28(4): 241-246.
[7]	金咪咪, 欧植泽, 高云燕, 郝萍, 殷卫峰, 刘丽华. 竹红菌素金属配合物与人血清白蛋白相互作用的光谱研究[J]. 影像科学与光化学, 2010, 28(1): 1-9.
[8]	彭兆快, 陶斯禄, 张晓宏, 吴世康. 有机电致发光器件中几种常用组分的荧光光谱研究[J]. 影像科学与光化学, 2004, 22(5): 357-362.
[9]	周丽丽, 张晓宏, 吴世康. 双(萘-类硫脲盐)化合物的光化学反应[J]. 影像科学与光化学, 2004, 22(4): 259-265.
[10]	翁宇峰, 过梅丽, 蔺洪振, 白凤莲. 共轭聚合物在传感器上的应用[J]. 影像科学与光化学, 2003, 21(5): 338-345.
[11]	周学东, 姜永才, 张晓宏, 吴世康. 一种新型红光敏感光交联体系[J]. 影像科学与光化学, 2002, 20(3): 169-176.
[12]	王辉, 梅明华, 房喻, 张晓宏, 吴世康. 阳离子荧光敏感器的器件化问题研究[J]. 影像科学与光化学, 2002, 20(2): 118-125.
[13]	解宏智, 孙照勇, 艾希成, 张兴康, 吴世康. 多足化合物的分子内激基缔合物形成及pH对其荧光的影响[J]. 影像科学与光化学, 2001, 19(3): 177-184.
[14]	解宏智, 伊珊, 吴世康. 多足开链化合物的分子内光诱导电子转移及pH对其荧光的影响[J]. 影像科学与光化学, 2000, 18(1): 51-57.
[15]	黄德音, 段学辉, 刘燕刚, 蓝闽波. 苝四羧酸多联体化合物的合成及其光谱特性研究[J]. 影像科学与光化学, 1999, 17(1): 17-24.