基于羧酸银的光敏热成像技术进展

doi:10.7517/j.issn.1674-0475.2003.01.1

摘要/Abstract

摘要： 最近10年,光敏热显影成像材料在技术上取得了重要进展,特别是以羧酸银作为银源的这类材料.这些进展集中体现在1995年为满足商品需要而研制成功的世界上第一个具有高分辨力、可作诊断使用的医用X射线胶片的Kodak DryView激光成像片上.此后,采用同样技术的一类特殊片种,即高反差的印刷胶片也随之问世.这些产品的实践应用都相当成功,已被多家公司所采用.这些新产品得益于三个方面的技术进展:改进成像层的照相性质、高影像质量和低成本的激光成像硬件,这也是此研究工作的焦点.在这类材料上所取得的重要成就反映在它们的高分辨力、高最大密度、低最小密度以及整张胶片性质的均一性上.所有这些优点,再加上超过100年的影像稳定性,使原来“老”的光敏热显影技术发生了一次脱胎换骨的变化,成为了当今最新的一种硬拷贝成像介质.

关键词: 光敏热显影成像, 羧酸银, 调色剂, 光敏热成像

Abstract: Significant advances have been made within just the last ten years in the technology of photothermographic imaging materials, particularly those that utilize silver carboxylates as the source of silver for the metallic image. These advances have come about as the result of new commercial product needs that were precipitated by the introduction of the world’s first high-resolution, diagnostic quality, medical x-ray film, Kodak DryView laser imaging film, in 1995. Since then, high contrast graphic arts films, a special offshoot of the same technology, have been introduced. Both applications are sufficiently successful that they are now available from multiple companies. These new products have resulted from a three pronged approach to their development: improved photographic film properties in the imaging layer, higher quality, lower cost laser imaging hardware, and focus of research designed to support this work. Significant achievements can clearly be seen in the form of high-resolution, high D-max, low D-min, and uniform cross film properties, all of which, when combined with image stability exceeding 100 years, re establishes the "old" photothermographic technology as an up to date hardcopy imaging medium.

Key words: photothermography, silver carboxylates, silver behenate, toner, phthalazine

中图分类号:

TQ57

David R. Whitcomb. 基于羧酸银的光敏热成像技术进展[J]. 影像科学与光化学, 2003, 21(1): 1-19.

David R. Whitcomb. ADVANCES IN PHOTOTHERMOGRAPHIC IMAGING TECHNOLOGY BASED ON SILVER CARBOXYLATES[J]. Imaging Science and Photochemistry, 2003, 21(1): 1-19.

参考文献

[1] D Morgan.Personal communication.
[2] B C Willett. Kodak DryView Laser Imaging Systems, ACS Symposium on Green Chemistry, Rochester, NY, Oct 2000.
[3] D Morgan. BE Patent 663112 (1965).
[4] S E Sheppard, W Vaneslow. US Patent 1 976 302 (1934).
[5] D H Klosterboer. Neblette's Eighth Edition: Imaging Processes and Materials, J M Sturge, V Walworth, A Shepp, Eds., Van Nostrand-Reinhold, Ch.9, 279 (1989).
[6] W H F Talbot. US Patent 5 171 (1847).
[7] C S Miller, B L Clark. US Patent 2 663 654 (1953).
[8] R Owen. US Patent 2 910 377 (1959).
[9] R Owen. US Patent 3 074 809 (1963).
[10] E A Grant. US Patent 3 080 254 (1963).
[11] L E Wingert. US Patent 3 031 329 (1962).
[12] J L Reitter. US Patent 3 218 166 (1962).
[13] A W Leclair. US Patent 3 816 139 (1974).
[14] H Hagemann, A von Konig. US Patent 3 951 660 (1976).
[15] S Birkeland. US Patent 3 589 903 (1971).
[16] G van D Tiers, J A Wiese, Jr. US Patent 3 707 377 (1972).
[17] J M Winslow. US Patent 3 994 732 (1976).
[18] AD-A011 704 (1975) 3M and Air Force Avionics Laboratory.
[19] D Morgan. J.Imaging Technol. 13, 4 (1987).
[20] B A Lea. US Patent 4 835 096 (1989).
[21] C Renfrew. US Patent 3 531 286 (1970).
[22] P J Cowdery-Corvan, D R Whitcomb. Handbook of Imaging Materials, A S Diamond, D S Weiss, Eds., 2002, Marcel Dekker.
[23] V M Andreev, E P Fokin, Yu I Mikhailov, V V Boldyrev. Zhur.Nauch.i Prik.Fotogr.i Kine., 24(1979) 311.
[24] Y Hayashi, T Ueda. J Soc.Photogr.Sci.Tech., Jpn., 46(1983) 39.
[25] R Hradaynath, M K Sharma. Def.Sci., J., 35(1985) 89.
[26] D A Morgan.Handbook of Imaging Materials,A S Diamond,Ed.,Marcel Dekker,New York,Chap.2, 43 (1991).
[27] P M Zavlin, A N Dyakonov, S S Natzakanov, S S Tibilov, P Z Velinzon, S I Gaft. Tekhn.Kino i Tele., 3(1991) 12.
[28] M R V Sahyun. J.Imaging Sci.Technol., 42(1998) 23.
[29] D R Whitcomb. Kirk-Othmer Encyclopedia of Chemical Technology, online edition, in press.
[30] D Morgan. SPSE International Tokyo Symposium, p.52, 1973.
[31] Kodak DryView 8100 laser imaging system, Eastman Kodak Company product literature.
[32] D Morgan. Proc.SPIE-Int.Soc.Opt.Eng. (1993), 1912 (Color Hard Copy and Graphic Arts II), 271.
[33] S Emmers, B Horsten, I Geuens, Y Gilliams, A Bellens, D Bollen, I Hoogmarten. US Patent 6 159 667 (2000).
[34] M de Clerck. Proc.Int.Conf.Imaging.Sci. ICPS '98, Antwerp, Belgium (1998) 106.
[35] B P Tolochko, S V Chernov, S G Nikitenko, D R Whitcomb, Nucl.Instr.Meth.Phys.Res.(A) 405, 428 (1998).
[36] D R Whitcomb, W C Frank, R D Rogers, B P Tolochko, S V Chernov, S G Nikitenko. IS&T 49th Ann.Conf., Minneapolis, MN., p.426 (1996).
[37] S E Hill, M B Mizenk, M R V Sahyun, Y E Usanov. J.Imaging Sci.Technol., 40 (1996) 568.
[38] I Geuens, I Hoogmartens, G Defieuw. EP Patent 1,158,355 (2001).
[39] D R Whitcomb, R D Rogers. J.Chem.Cryst., 25, 1995, 137.
[40] D R Whitcomb, R D Rogers. Inorg.Chim.Acta, 256, 1997, 263.
[41] T Maekawa, M Yoshikane, H Fujimura, I Toya. J.Imaging Sci.Technol., 45 (2001) 365.
[42] D R Whitcomb. Int.Conf.Imaging Sci., Tokyo, 2002.Society of Photographic Science and Technology of Japan, Imaging Society of Japan, The Society for Imaging Science and Technology.
[43] H Strijckers. Proc.Int.Conf.Imaging Sci., p.23, Tokyo, Japan, 2002.
[44] J R Miller, B C Willett, D C Lynch, B J Kummeth. US Patent 5 541 054 (1996).
[45] M Fujita, T Ishizaka, A Hatakeyama, H Okada, N Asanuma. US Patent 6 132 949 (2000).
[46] C Zou, J B Philip, S M Shor, M C Skinner, P Zhou. US Patent 5 434 043 (1995).
[47] S Takahashi. JP 11 102 057 (1999).
[48] R H Helland, C W Gomez, W D Ramsden. US Patent 6 329 128 (2001).
[49] T Tani. Photographic Sensitivity, Theory and Mechanisms, Oxford University Press, New York, 1995.
[50] J W Reeves. US Patent 4 435 499 (1984).
[51] G L Featherstone, D C Lynch, J R Miller, M C Skinner, J M Winslow, S M Simpson. US Patent 5,891,615 (1999).
[52] H Tsuzuki, A Hatakeyama, K Nakajima. Proc.Int.Conf.Imaging Sci., p.27, Tokyo, Japan, 2002.
[53] K Yamane, S Yamashita. Proc.Inter.Conf.Imaging Sci., p.29, Tokyo, Japan, 2002.
[54] M E Irving, D H Levy, J H Reynolds, D T Southby, P D Zimmerman. WO 200 196 950 (2001).
[55] B B Bokhonov, L Burleva, W C Frank, J R Miller, M B Mizen, M R V Sahyun, D R Whitcomb, J M Winslow, C Zou. J.Imaging Sci.Technol., 40 (1996) 85.
[56] B B Bokhonov, L P Burleva, A A Politov, N F Uvarov, D R Whitcomb, M B Mizen, M R V Sahyun, IS&T's 50th Ann.Conf.38-41 (1997).
[57] C Zou, M R V Sahyun, B Levy, N Serpone. J.Imaging Sci.Technol., 40, 94 (1996).
[58] Yu E Usanov, T B Kolesova, B B Bokhonov, M R V Sahyun. J.Imaging.Sci.Technol., 45, 267 (2001).
[59] H Strijckers, C van Roost. 2000 Int.Symp.Silver Halide Tech., IS &T, Springfield, VA, 2000, 248.
[60] S H Kong. J.Imaging Sci.Technol., 43(1999) 509.
[61] A Hirano. Proc.Int.Conf.Imaging Sci., ICPS'98, Antwerp, Belgium (1998) 65.
[62] T Ito, S Nishiwaki, T Mitsuhasi. J.Imaging Sci.Technol. 45 (2001) 357.
[63] K Katoh, A Hatekeyama. EP Patent 803 764 (1997).
[64] H Vandenabeele, H Uytterhoeven. EP Patent 851 285 (1998).
[65] M Fujita, T Ishizaka, A Hatakeyama, H Okada, N Asanuma. US Patent 6 132 949 (2000).
[66] A J Alton, J P Beese, P J Cowdery-Corvan, L J Magee, M W Martin, EP Patent 809 141 (1997).
[67] G Defieuw, J Loccufier, Y Hoogmartens, I Geuens. EP Patent 964 300 (1999).
[68] S Emmers, B Horsten, I Geuens, Y Gilliams, A Bellens, D Bollen, I Hoogmartens. EP Patent 848 286 (1997).
[69] J Blair, G LaBelle, F Manganiello, K Sakizadeh, D Whitcomb. IS&T 50th Annual Conference, 581 (1996).
[70] K Sakizadeh. J.Imaging Sci.Technol., in press.
[71] K Goan. JP 2 001 056 521 (2001).
[72] Y Hayashi, T Akagi, S Kinoshita, R Hirohashi. Nippon Shashin Gakkaishi, 52 (1989) 21.
[73] L A Nesterova, Z P Bistrova, I N Orlova, V G Sevastyanov, G R Allakhverdov, B I Zhelnin, E I Volovich, L N Cinyaver, S S Tibilov, P Z Velinzon. SU Patent 1 740 369 (1992).
[74] N Kawanishi, T Ando. EP Patent 1 069 468 (2001).
[75] J Besse, A J Alton, L J Magee, P Cowdery-Corvan, M W Martin. EP Patent 809 141 (1997).