L-(-)-α-苯乙胺类立方烷结构2-萘甲酸二聚体盐的晶体结构

doi:10.7517/j.issn.1674-0475.2007.06.409

影像科学与光化学 ›› 2007, Vol. 25 ›› Issue (6): 409-414.DOI: 10.7517/j.issn.1674-0475.2007.06.409

L-(-)-α-苯乙胺类立方烷结构2-萘甲酸二聚体盐的晶体结构

武小玲^1,2, 吴骊珠¹, 雷蕾¹, 佟振合¹, 张丽萍¹

1. 中国科学院, 理化技术研究所, 有机光电功能材料与分子工程学重点实验室, 北京, 100080;
2. 中国科学院, 研究生院, 北京, 100039

收稿日期:2007-06-13 修回日期:2006-06-15 出版日期:2007-11-23 发布日期:2007-11-23
通讯作者: 吴骊珠,E-mail:lzwu@mail.ipc.ac.cn.
基金资助:
科技部国家重点基础研究发展规划项目(2006CB806105,G2007CB808004);国家自然科学基金资助项目(20333080,20332040,20472091);中科院基础局资助项目

The Crystal Structure of L-(-)-α-Phenyl Ethylammonium Cubane-Like Dimer of Carboxylic 2-Naphthoate

WU Xiao-ling^1,2, WU Li-zhu¹, LEI Lei¹, TONG Zhen-he(TUNG Chen-ho)¹, ZHANG Li-ping ¹

1. Laboratory of Organic Optoelectronic Functional Materials and Molecular Engineering, Technical Institute of Physics and Chemistry, the Chinese Academy of Sciences, Beijing 100080, P. R. China;
2. Graduate University of the Chinese Academy of Sciences, Beijing 100039, P. R. China

Received:2007-06-13 Revised:2006-06-15 Online:2007-11-23 Published:2007-11-23

摘要/Abstract

摘要： L-(-)-α-苯乙胺与消旋的类立方烷结构2-萘甲酸二聚体相互作用形成铵盐,其晶体结构表明,L-(-)-α-苯乙胺与类立方烷结构2-萘甲酸二聚体作用形成的铵离子通过氢键N_2A-HN_2B…O_5A和N_1A-HN_1A…O_3A与类立方烷结构2-萘甲酸二聚体结合在一起.同时类立方烷结构2-萘甲酸二聚体的两个对映异构体之间也存在分子间氢键O_1A-H_1AA…O_6A和O_1B-H_1AB…O_6B.这些氢键将类立方烷结构2-萘甲酸二聚体的两个对映异构体连在同一个晶胞中,呈现两条分子链状堆积.

关键词: L-(-)-α-苯乙胺, 类立方烷结构2-萘甲酸二聚体, C2对称性

Abstract: L-(-)-α-Phenyl ethylamine was reacted with cubane-like dimer of carboxylic 2-naphthoate to afford L-(-)-α-phenyl ethylammonium cubane-like dimer of carboxylic 2-naphthoate with high yield.Crystal structural analysis demonstrates that the hydrogen bonding of N_2A-HN_2B…O_5A and O_1A-HN_1A…O_3A are responsible for the crystal packing,in which N_2A-HN_2B…O_5A connects L-(-)-α-phenyl ethylammonium cation and cubane-like dimer of carboxylic 2-naphthoate.Intermolecular hydrogen bonding of O_1A-H_1AA…O_6A and O_1B-H_1AB…O_6B directs the assembly of two enatiomers of cubane-like dimer of carboxylic 2-naphthoate acid.

Key words: L-(-)-α-phenyl ethylamine, cubane-like dimer of carboxylic 2-naphthoate acid, C₂ symmetry

中图分类号:

武小玲, 吴骊珠, 雷蕾, 佟振合, 张丽萍. L-(-)-α-苯乙胺类立方烷结构2-萘甲酸二聚体盐的晶体结构[J]. 影像科学与光化学, 2007, 25(6): 409-414.

WU Xiao-ling, WU Li-zhu, LEI Lei, TONG Zhen-he(TUNG Chen-ho), ZHANG Li-ping . The Crystal Structure of L-(-)-α-Phenyl Ethylammonium Cubane-Like Dimer of Carboxylic 2-Naphthoate[J]. Imaging Science and Photochemistry, 2007, 25(6): 409-414.

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L-(-)-α-苯乙胺类立方烷结构2-萘甲酸二聚体盐的晶体结构

The Crystal Structure of L-(-)-α-Phenyl Ethylammonium Cubane-Like Dimer of Carboxylic 2-Naphthoate

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