杂多酸/聚乙烯醇复合膜的制备及光催化性能研究

doi:10.7517/j.issn.1674-0475.2009.03.215

影像科学与光化学 ›› 2009, Vol. 27 ›› Issue (3): 215-224.DOI: 10.7517/j.issn.1674-0475.2009.03.215

杂多酸/聚乙烯醇复合膜的制备及光催化性能研究

甘雨, 徐彦军, 刘霞

中国农业大学, 理学院, 北京100193

收稿日期:2008-10-06 修回日期:2009-04-02 出版日期:2009-05-23 发布日期:2009-05-23
通讯作者: 刘霞
基金资助:
中国工程物理研究院化工材料研究所资助课题.

Preparation and Photocatalytic Activity of Heteropoly Acids/Polyvinyl Alcohol Thin Films

GAN Yu, XU Yan-jun, LIU Xia

College of Science, China Agricultural University, Beijing 100193, P.R.China

Received:2008-10-06 Revised:2009-04-02 Online:2009-05-23 Published:2009-05-23

摘要/Abstract

摘要： 合成了过渡金属取代的硅钨酸盐K₆SiM(H₂O)W₁₁O₃₉(M=Co、Ni、Cu,简称为SiMW₁₁),利用硅钨酸(H₄SiW₁₂O₄₀·nH₂O,简称为SiW₁₂)与SiMW₁₁做母体,分别将它们负载于聚乙烯醇(polyvinyl alcohol,PVA)上,制成一系列杂多酸/聚乙烯醇复合膜光催化剂,利用IR、SEM进行了表征.以高压汞灯为光源,分别研究了SiW₁₂/PVA、SiCoW11/PVA、SiNiW₁₁/PVA、SiCuW₁₁/PVA复合膜对有机染料甲基橙的光催化脱色,它们都具有很高的催化活性,60 min内对甲基橙的脱色率均可达到90%以上,其中SiW₁₂/PVA复合膜效果最好,12 min内脱色率达100%.提高SiW₁₂负载量可有效提高膜的光催化活性,当SiW₁₂与PVA质量比为1:1时催化活性最高.

关键词: 杂多酸, 聚乙烯醇, 光催化降解, 甲基橙

Abstract: The polyoxometalates K₆SiM(H₂O)W₁₁O₃₉(M=Co、Ni、Cu)(SiMW₁₁) were synthesized and a series of tungstosilicate acid/polyvinyl alcohol(SiW₁₂/PVA) and SiMW₁₁/polyvinyl alcohol(SiMW₁₁/PVA) composite films were prepared.The results indicated that the original Keggin structure of the SiW₁₂ and SiMW₁₁ remained intact on the films.The photocatalytic activity of the POM/PVA composite films was tested via the degradation of methyl orange(MO) under irradiation of the high pressure mercury lamp.It was observed that the amount of polyoxometalates in the films had important effects on the photocatalytic activity and the ability of photodecolorization is according to the following order: SiW₁₂/PVA>SiCoW₁₁/PVA>SiNiW₁₁/PVA>SiCuW₁₁/PVA.Meanwhile,it is easy to separate and recover the POM/PVA film from the reaction system.

Key words: heteropoly acid, polyvinyl alcohol, photodegradation, methyl orange

中图分类号:

O644

甘雨, 徐彦军, 刘霞. 杂多酸/聚乙烯醇复合膜的制备及光催化性能研究[J]. 影像科学与光化学, 2009, 27(3): 215-224.

GAN Yu, XU Yan-jun, LIU Xia. Preparation and Photocatalytic Activity of Heteropoly Acids/Polyvinyl Alcohol Thin Films[J]. Imaging Science and Photochemistry, 2009, 27(3): 215-224.

参考文献

[1] 唐立昊,岳斌,朱思三,等.钨磷酸(硅钨酸)/聚乙烯醇复合物的制备和光、电性质研究[J].高等学校化学学报,1999,20(9):1349-1351.Tang L H,Yue B,Zhu S S,et al.Preparation,photochromism and electronic properties of Keggin typetungstophosphate,tungstosilicate Acids/Polyvinyl alcohol complexes[J].Chemical Journal of Chinese Universities,1999,20(9):1349-1351.
[2] Feng W,Zhang T R,Liu Y,et al.Sonochemical preparation of photochromic mamocomposite thin fil m based onpolyoxomatalates well dispersedin polyacrylamide[J].J.Solid State Chem.,2002,169(1):1-4.
[3] 朱思三,唐立昊,岳斌.十聚钨酸/聚乙烯醇导电膜的制备[J].化学学报,1999,57(5):533-547.Zhu S S,Tang L H,Yue B.Preparation of decatungstic acid/polyvinyl alcohol conducting fil ms[J].Acta Chi micaSinica,1999,57(5):533-547.
[4] 鞠金梅,吴莹,稳荻江.有机-多金属氧酸盐杂化材料的研究进展[J].武汉化工学院学报,2004,26(1):59-63.Ju J M,Wu Y,Wen DJ.Progress in organic-polyoxometates hybrid materials[J].Journal of Wuhan Institute ofChemical Technology,2004,26(1):59-63.
[5] 王炜,程为.聚乙烯醇负载Keggin结构杂多酸光催化降解水中苯酚[J].大连铁道学院学报,2004,25(3):87-90.Wang W,Cheng W.Complex Film(heteropolyacid/polyvinylalcohol):synthesis and photocatalytic Degradation ofAqueous Phenol[J].Journal of Dalian RailwayInstitute,2004,25(3):87-90.
[6] 徐红,纪明慧,蒋黎,等.可见光下聚乙烯醇负载EuPW光催化降解甲基橙的研究[J].海南师范大学学报(自然科学版),2008,21(1):47-55.Xu H,Ji MH,Jiang L,et al.Degradation of methyl orange by photocatalyst EuPW/PVAunder visiblelight irradia-tion[J].Journal of Hainan Normal University(Natural Science),2008,21(1):47-55.
[7] Weakley TJ R,Malik S A.Heteropolyanions containingtowdifferent heteroatoms-I[J].J.Inorg.Nucl.Chem.,1967,29(12):2935-2944.
[8] Tourn啨C M,Tourn啨GF,Malik S A,Weakley TJ R.Triheterppolyanions containing Copper(II),Manganese(II),or Manganese(III)[J].J.Inorg.Nucl.Chem.,1970,32(12):3875-3890.
[9] Kozhevnikov I V,Kloetstra K R,Sinnema A,et al.Study of catalysts comprising heteropoly acid H3PW12O40sup-ported on MCM-41 molecular sieve and amorphous silica[J].J.Mol.Catal.A,1996,114(1-3):287-298.
[10] 艾丽梅,邓捷,李永仙,等.多酸含量对无机/高分子复合薄膜结构及光致变色性能的影响[J].化学学报,2007,65(17):1841-1844.Ai L M,Deng J,Li Y X,et al.Effect of polyoxometalates content on structure and photochromismof inorganic-polymer composite fil ms[J].Acta Chi mica Sinica,2007,65(17):1841-1844.
[11] 黄焱,潘庆谊,程知萱,等.镶嵌钨硅酸的新型有机-无机纳米复合薄膜的制备及光致变色性能研究[J].高等学校化学学报,2005,25(2):204-208.Huang Y,Pan Q Y,Cheng Z X,et al.Synthesis and photochroismof a novel organic-inorganic nanocomposite fil mentrapping tungstosilicate acid[J].Chemical Journal of Chinese Universities,2005,25(2):204-208.
[12] Duncan D C,Netzel T L,Hill C L.Early-ti medynamicand reactivity of polyoxometalate excited states[J].Inorg.Chem.,1995,34(18):4640-4649.
[13] 邓玲娟,杨春.SnII取代的Keggin型多金属氧酸盐的合成及光催化性能[J].应用化学,2007,24(2):139-143.Deng LJ,Yang C.Synthesis of SnII-substitude Keggin-type polyoxometalates and their photocatalytic performance[J].Chinese Journal of Applied Chemistry,2007,24(2):139-143.
[14] 邓国宏,余立新,郝继华,等.聚乙烯醇/二氧化硅共混膜的制备及耐温、耐溶剂性能研究[J].高分子材料科学与工程,2001,17(6):122-125.Deng G H,Yu L X,Hao J H,et al.Preparation and properties of poly(vinyl alcohol)/Silica hybrid fil ms[J].Polymer Materials Science and Engineering,2001,17(6):122-125.

[1]	聂坤, 杨汉培, 孙慧华, 崔素珍, 吴俊明. 新型Fe掺杂钙钛矿型KMgF₃光催化剂制备及性能[J]. 影像科学与光化学, 2017, 35(1): 61-69.
[2]	陈笛笛, 石建兵, 佟斌, 支俊格, 董宇平. 固载四苯基乙烯及其衍生物聚集体的聚乙烯醇薄膜对有机挥发气氛的检测[J]. 影像科学与光化学, 2014, 32(6): 523-531.
[3]	王攀, 曹婷婷, 方艳芬, 罗光富, 李瑞萍, 黄应平. Hg掺杂CdS的制备及可见光降解有毒有机污染物[J]. 影像科学与光化学, 2011, 29(1): 11-23.
[4]	曹静, 林海莉, 罗邦德, 李辰, 陈士夫. 异质结型AgI/AgBr/TiO₂催化剂的制备及其光催化性能[J]. 影像科学与光化学, 2010, 28(5): 334-342.
[5]	林海莉, 曹静, 罗邦德, 鞠廷勇, 陈士夫. 负载型AgBr/CaWO₄催化剂的制备及其可见光催化活性[J]. 影像科学与光化学, 2010, 28(5): 368-375.
[6]	曹静, 林海莉, 贾丽, 陈士夫. AgBr/TiO₂复合催化剂:双注法制备及其可见光催化性能[J]. 影像科学与光化学, 2009, 27(6): 462-468.
[7]	李慧泉, 范以宁, 董昆明, 金凤, 陈水生. 低量La³⁺掺杂S-TiO₂光催化剂的制备、表征及其光催化活性[J]. 影像科学与光化学, 2009, 27(1): 38-47.
[8]	李银辉, 殷德宏, 陈赞, 王金渠. 掺杂WO₃的SiO₂/TiO₂的溶胶热液合成及光催化性能[J]. 影像科学与光化学, 2008, 26(5): 349-357.
[9]	蔡河山, 刘国光, 黎晓霞. 模拟太阳光下稀土Gd掺杂TiO₂纳米晶的光催化性能研究[J]. 影像科学与光化学, 2008, 26(3): 238-243.
[10]	马新起, 冯彩霞, 贵莉莉, 姚莉, 牛玉奇, 郭新勇. 负载银纳米管钛酸催化剂的制备[J]. 影像科学与光化学, 2008, 26(2): 104-108.
[11]	刘松翠, 吕康乐, 邓克俭, 唐红梅, 黎小芳. 三种不同晶型二氧化钛的制备及光催化性能研究[J]. 影像科学与光化学, 2008, 26(2): 138-147.
[12]	朱启安, 王树峰, 陈万平, 孙旭峰, 张琪. Li⁺掺杂纳米TiO₂的制备及其光催化性能研究[J]. 影像科学与光化学, 2007, 25(5): 340-349.
[13]	黄徽, 杜玉扣, 戴兢陶, 杨平. TiO₂/ACF的制备及光催化降解四氯乙烯性能[J]. 影像科学与光化学, 2007, 25(2): 123-129.
[14]	吕晓萌, 林家敏, 谢吉民. 二铁取代硅钨酸盐光解引发甲基橙的脱色[J]. 影像科学与光化学, 2006, 24(6): 444-449.
[15]	李慧泉, 陈伟凡, 崔玉民. Nd₂O₃/TiO₂光催化剂的光生羟基自由基和光活性[J]. 影像科学与光化学, 2006, 24(3): 197-203.

杂多酸/聚乙烯醇复合膜的制备及光催化性能研究

Preparation and Photocatalytic Activity of Heteropoly Acids/Polyvinyl Alcohol Thin Films

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价