通过微观形貌对Ba(Ti,Sn)O3压电陶瓷的结构及压电性能分析

doi:10.7517/j.issn.1674-0475.2017.02.174

影像科学与光化学 ›› 2017, Vol. 35 ›› Issue (2): 174-178.DOI: 10.7517/j.issn.1674-0475.2017.02.174

通过微观形貌对Ba(Ti,Sn)O₃压电陶瓷的结构及压电性能分析

刘洁晶

衡水学院, 河北衡水 053000

收稿日期:2017-01-25 修回日期:2017-02-21 出版日期:2017-03-15 发布日期:2017-03-15
通讯作者: 刘洁晶
基金资助:
河北省科学计划项目（12210333）和衡水市科学技术研究与发展计划项目（14045）

Effect of CaCO₃ Dopant on Structure and Electrical Properties of Ba(Ti, Sn)O₃ Lead-free Piezoelectric Ceramics

LIU Jiejing

Hengshui University of China, Hengshui 053000, Hebei, P. R. China

Received:2017-01-25 Revised:2017-02-21 Online:2017-03-15 Published:2017-03-15

摘要/Abstract

摘要：

本文采用传统固相合成法制备了（Ba_1-xCa_x）（T_i0.98Sn_0.02）O₃（BCTS，x=0.00、0.01、0.02、0.03）无铅压电陶瓷，研究了不同烧结温度下Ba（Ti，Sn）O₃压电陶瓷材料的微观形貌对相结构及压电性能的影响。X-射线衍射（XRD）分析表明，所有陶瓷样品均为单一、纯钙钛矿结构，无第二相生成。通过扫描电子显微镜（SEM）图片可知，陶瓷样品在烧结温度为1450℃时，晶粒更加均匀、陶瓷结构更加致密，气孔较少并且晶粒成螺旋状结构生长。当陶瓷烧结温度为1450℃，并且x=0.01时，陶瓷的综合性能达到最佳，其压电常数（d₃₃）达到346 pC/N。

关键词: 扫描电子显微镜, 无铅压电陶瓷, 相结构, 微观结构, 压电性能

Abstract:

(Ba_1-xCa_x)(Ti_0.98Sn_0.02)O₃(BCTS,x=0.00,0.01,0.02,0.03) lead-free ceramics were prepared by traditional solid-state reaction method. Effect of microstructure on phase structure and piezoelectric properties with different sintering temperatures were studied. According to the results by X-ray diffraction, all samples possess pure perovskite phases without second phases. By scanning electron microscopy (SEM) images show that the grain was uniform, phases structure was more dense and with less porosity, the grain growth of spiral structure, when the sintering temperatures is 1450℃. The optimum electrical properties can be obtained at x=0.01 and sintering temperatures is 1450℃:d₃₃=346 pC/N.

Key words: scanning electron microscopy, lead-free piezoceramics, phase structure, microstructure, piezoelectric properties

刘洁晶. 通过微观形貌对Ba(Ti,Sn)O₃压电陶瓷的结构及压电性能分析[J]. 影像科学与光化学, 2017, 35(2): 174-178.

LIU Jiejing. Effect of CaCO₃ Dopant on Structure and Electrical Properties of Ba(Ti, Sn)O₃ Lead-free Piezoelectric Ceramics[J]. Imaging Science and Photochemistry, 2017, 35(2): 174-178.

参考文献

[1] Peng G G, Chen C, Zhang J, Zheng D Y, Hu S M, Zhang H. Effects of PNN/PZT ratios on phase structure, electric properties and relaxation behavior of PZN-PNN-PZT ceramics[J]. Journal of Materials Science:Materials in Electronics, 2016, 27(4):3145-3151.
[2] Zhang H, Zheng D Y, Hu S M, Cheng C, Peng G G, Zhang J, Li L L. Structural and electrical properties of Bi_1/2Na_1/2TiO₃-BaTiO₃-Sr₃CuNb₂O₉, lead-free piezoelectric ceramics[J]. Journal of Materials Science Materials in Electronics, 2017,28(1):67-74.
[3] R del J, Jo W, Seifert K T P, Anton E, Granzow T, Damjanovic D. Perspective on the development of lead-free piezoceramics[J]. Journal of the American Ceramic Society, 2009, 92(6):1153-1177.
[4] Li W, Xu Z J, Chu R Q, Fu P, Zang G Z. Enhanced ferroelectric properties in (Ba_1-xCa_x)(Ti_0.94Sn_0.06)O₃ lead-free ceramics[J]. Journal of the European Ceramic Society, 2012, 32(3):517-520.
[5] 于坤, 江向平, 陈超, 李璐,李小红. Co₂O₃掺杂对BCTZ无铅压电陶瓷的性能影响[J]. 压电与声光, 2014,(3):441-444. Yu K, Jiang X P, Chen C, Li L, Li X H. Effects of Co₂O₃ doping on properties of BCZT lead-free piezoelectric ceramics[J]. Piezoelectrics and Acoustooptics, 2014,(3):441-444.
[6] Li W, Qi J Q, Wang Y L, Li L T, Gui Z L. Doping behaviors of Nb₂O₅, and Co₂O₃, in temperature stable BaTiO₃-based ceramics[J]. Materials Letters, 2002, 57(1):1-5.
[7] Singh K C, Nath A K, Laishram R, Thakur O P. Structural, electrical and piezoelectric properties of nanocrystalline tin-substituted barium titanate ceramics[J]. Journal of Alloys & Compounds, 2011, 509(5):2597-2601.
[8] Badapanda T, Sarangi S, Behera B, Sahooc P K, Anward S, Sinhae T P, Luz G E, Longog E, Cavalcantef L S. Structural refinement, optical and ferroelectric properties of microcrystalline Ba(Zr_0.05Ti_0.95)O₃, perovskite[J]. Current Applied Physics, 2014, 14(5):708-715.
[9] Huang X Q, Liu Q B, Zhang C. Effect of sintering temperature on microstructure and electrical properties of (1-x)BCZT-xBY lead-free ceramics[J]. Advanced Materials Research, 2014, 900:119-122.

通过微观形貌对Ba(Ti,Sn)O₃压电陶瓷的结构及压电性能分析

Effect of CaCO₃ Dopant on Structure and Electrical Properties of Ba(Ti, Sn)O₃ Lead-free Piezoelectric Ceramics

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 2

编辑推荐

Metrics

本文评价

[1]	王东贤, 王琳, 宫清涛, 廖琳, 张路, 靳志强, 黄玉萍, 严峰, 赵濉, 俞稼镛. 改性聚丙烯酰胺水溶液的疏水缔合性质[J]. 影像科学与光化学, 2005, 23(3): 197-202.
[2]	刘素文, 岳军, 阎天堂. SEM法测量T颗粒厚度[J]. 影像科学与光化学, 1993, 11(1): 1-4.