全印刷碳纳米管薄膜晶体管构建及电性能研究

doi:10.7517/j.issn.1674-0475.2016.02.136

影像科学与光化学 ›› 2016, Vol. 34 ›› Issue (2): 136-143.DOI: 10.7517/j.issn.1674-0475.2016.02.136

全印刷碳纳米管薄膜晶体管构建及电性能研究

张祥^1,2, 费斐², 郭文瑞², 聂书红², 吴良专³, 谢建军¹, 赵建文², 崔铮²

1. 上海大学材料科学与工程学院, 上海 200444;
2. 中国科学院苏州纳米技术与纳米仿生研究所印刷电子研究中心, 江苏苏州 215123;
3. 中国科学院理化技术研究所, 北京 100190

收稿日期:2015-12-07 修回日期:2016-01-15 出版日期:2016-03-15 发布日期:2016-03-15
通讯作者: 赵建文,崔铮
基金资助:
国家自然基金青年基金项目(91123034, 61102046)和江苏省自然基金项目(BK2011364)资助

Fabrication and Electrical Properties of Fully Printed Thin-film Transistors Based on PFO-DPP Sorted Semiconducting Single-walled Carbon Nanotubes

ZHANG Xiang^1,2, FEI Fei², GUO Wenrui², NIE Shuhong², WU Liangzhuan³, XIE Jianjun¹, ZHAO Jianwen², CUI Zheng²

1. School of Materials Science and Engineering, Shanghai University, Shanghai 200444, P. R. China;
2. Printable Electronics Research Centre, Suzhou Institute of Nanotech and Nano-bionics, Chinese Academy of Sciences, Suzhou 215123, Jiangsu, P. R. China;
3. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

Received:2015-12-07 Revised:2016-01-15 Online:2016-03-15 Published:2016-03-15

摘要/Abstract

摘要：

利用纳米压印和电刷镀技术在PET基体上制作出大面积金源、漏电极阵列。分别采用钛酸钡复合材料为介电层,印刷银电极为顶电极,聚芴-二噻吩基吡咯并吡咯二酮(PF8DPP)分离的半导体碳纳米管为有源层,在柔性基体上构建出全印刷碳纳米管薄膜晶体管器件和反相器。全印刷碳纳米管薄膜晶体管的开关比和迁移率分别达到4×10⁴和6 cm²·V^-1·s^-1,且器件表现出零回滞特性。构建的反相器在V_dd=8 V时,其增益可以达到12。

关键词: 纳米压印, 电刷镀, 半导体碳纳米管, 聚合物, 印刷电子, 薄膜晶体管

Abstract:

Printed top-gate carbon nanotube thin-film transistors (TFTs) and inverters were achieved on flexible substrates. Large-scale gold electrode arrays were constructed on PET substrates using nano-imprinting in combination with the brush electroplating technique. PF8DPP-soretd sc-SWCNTs, BaTiO₃ and printed silver electrodes were acted as the channel materials, the dielectric layer and the top gates, respectively. Printed top-gate TFTs exhibited good performance with mobility up to 6 cm²·V^-1·s^-1, on/off ratio of 10⁴ and free hysteresis. Furthermore, the voltage gain of the inverter can reach 12 at V_dd of 8V.

Key words: nano-imprinting, brush plating, semiconducting carbon nanotube, polymer, printed electronics, thin film transistor

张祥, 费斐, 郭文瑞, 聂书红, 吴良专, 谢建军, 赵建文, 崔铮. 全印刷碳纳米管薄膜晶体管构建及电性能研究[J]. 影像科学与光化学, 2016, 34(2): 136-143.

ZHANG Xiang, FEI Fei, GUO Wenrui, NIE Shuhong, WU Liangzhuan, XIE Jianjun, ZHAO Jianwen, CUI Zheng. Fabrication and Electrical Properties of Fully Printed Thin-film Transistors Based on PFO-DPP Sorted Semiconducting Single-walled Carbon Nanotubes[J]. Imaging Science and Photochemistry, 2016, 34(2): 136-143.

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全印刷碳纳米管薄膜晶体管构建及电性能研究

Fabrication and Electrical Properties of Fully Printed Thin-film Transistors Based on PFO-DPP Sorted Semiconducting Single-walled Carbon Nanotubes

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