1-丁基-3-甲基咪唑碘对染料敏化太阳电池的影响

doi:10.7517/j.issn.1674-0475.2007.06.422

影像科学与光化学 ›› 2007, Vol. 25 ›› Issue (6): 422-430.DOI: 10.7517/j.issn.1674-0475.2007.06.422

1-丁基-3-甲基咪唑碘对染料敏化太阳电池的影响

康世杰, 李清华, 吴季怀, 林琳, 郝三存, 兰章, 李品将

华侨大学, 材料物理化学研究所, 福建, 泉州, 362021

收稿日期:2007-04-27 修回日期:2007-06-19 出版日期:2007-11-23 发布日期:2007-11-23
通讯作者: 吴季怀E-mail:jhwu@hqu.edu.cn.
基金资助:
国家自然科学基金资助项目(50082003,50372022);福建省重大科技项目(2005HZ01-4)

Influence of 1-Butyl-3-Methylimidazolium Iodide on Dye-Sensitized Solar Cells

KANG Shi-jie, LI Qing-hua, WU Ji-huai, LIN Lin, HAO San-cun, LAN Zhang, LI Pin-jiang

Institute of Materials Physical Chemistry, Huaqiao University, Quanzhou 362021, Fujian, P. R. China

Received:2007-04-27 Revised:2007-06-19 Online:2007-11-23 Published:2007-11-23

摘要/Abstract

摘要： 采用季铵化反应合成了1-丁基-3-甲基咪唑碘([Bmim]I).以此制备了DSCs用液体电解质.通过对比不同浓度的1-丁基-3-甲基咪唑碘、碘化钾、碘,研究其对电池性能的影响.经过优化后,当c_IL=0.9 mol·L^-1、c_KI=0.5 mol·L^-1、c_I₂=0.12 mol·L^-1时,所组装的离子液体DSCs在AM1.5,100 mW·cm^-2下,DSCs的短路电流密度为15.97 mA·cm^-2、开路电压为0.71 V、填充因子为0.55、光电转换效率可达6.34%.

关键词: 离子液体, 1-丁基-3-甲基咪唑碘, 染料敏化, 太阳电池

Abstract: 1-Butyl-3-methylimidazolium iodide was synthesized by quaternization.The photovoltaic performance of dye-sensitized solar cells (DSCs) was compared for electrolytes containing different concentrations of I,KI and iodine.After optizimed,the DSCs with the electrolyte (0.90 mol·L^-1 I,0.50 mol·L^-1 KI and 0.12 mol·L^-1 I₂ in GBL) gave short circuit photocurrent density (J_sc) of 15.97 mA·cm^-2,open circuit voltage (V_oc) of 0.71 V,and fill factor (FF) of 0.55,corresponding with the photoelectric conversion efficiency (η) of 6.34% under one Sun (Xenon lamp,AM1.5,100 mW·cm^-2).

Key words: ionic liquid, 1-butyl-3-methylimidazolium iodide, dye-sensitized, solar cell

中图分类号:

康世杰, 李清华, 吴季怀, 林琳, 郝三存, 兰章, 李品将. 1-丁基-3-甲基咪唑碘对染料敏化太阳电池的影响[J]. 影像科学与光化学, 2007, 25(6): 422-430.

KANG Shi-jie, LI Qing-hua, WU Ji-huai, LIN Lin, HAO San-cun, LAN Zhang, LI Pin-jiang. Influence of 1-Butyl-3-Methylimidazolium Iodide on Dye-Sensitized Solar Cells[J]. Imaging Science and Photochemistry, 2007, 25(6): 422-430.

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1-丁基-3-甲基咪唑碘对染料敏化太阳电池的影响

Influence of 1-Butyl-3-Methylimidazolium Iodide on Dye-Sensitized Solar Cells

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