影像科学与光化学 ›› 2012, Vol. 30 ›› Issue (3): 161-174.DOI: 10.7517/j.issn.1674-0475.2012.03.161

• 综述 •    下一篇

基于有机光电材料的痕量爆炸物识别

张成义1, 臧泠2   

  1. 1. 加州大学 圣地亚哥分校 化学与生物化学系,美国 加利福尼亚州 拉荷亚 92093;
    2. 犹他大学 材料科学与工程系, 美国 犹他州 盐湖城 84112
  • 收稿日期:2012-02-20 修回日期:2012-03-14 出版日期:2012-05-15 发布日期:2012-05-15
  • 通讯作者: ZHANG Cheng-yi, E-mail: cyzhang2008@gmail.com, Phone: +1-858-534-5176, Fax: +1-858-534-5383;
    ZANG Ling, E-mail: lzang@eng.utah.edu, Phone: +1-801-587-1551, Fax: +1-801-585-0625.
  • 基金资助:
    This work was supported by NSF (CAREER CHE 0641353, CBET 730667), DHS (2009-ST-108-LR0005), and the USTAR Program.

Organic Optoelectronic Materials for Trace Explosive Sensing

ZHANG Cheng-yi1, ZANG Ling2   

  1. 1. Department of Chemistry and Biochemistry, University of California San Diego, La Jolla, CA 92093 USA;
    2. Department of Material Science and Engineering, University of Utah, Salt Lake City, UT 84112 USA
  • Received:2012-02-20 Revised:2012-03-14 Online:2012-05-15 Published:2012-05-15

摘要: 随着国际恐怖袭击事件的增多,痕量爆炸物的识别技术研究越来越为重要.本文以作者在该领域的研究为例,综述了基于一维有机纳米材料、荧光金属配位聚合物(金属-有机框架化合物)和聚噻咯的荧光猝灭技术,在痕量爆炸物识别上的应用.同时介绍了酞菁薄膜和苝亚酰胺纳米线制备的电子传感器分别对过氧化物和硝基类爆炸物有灵敏的响应.

关键词: 爆炸物识别, 传感器, 荧光化合物, 痕量检测

Abstract: Detection of trace explosives is of great concern for homeland security, battlefield protection, and industrial and environmental safety control. Fluorescence quenching based sensing has proven to be one of the most promising approaches for trace explosives detection. This review is focused on examples reported by Porf. Ling Zang's group and Prof. William Trogler's group related to fluorescence quenching sensors based on one-dimensional small molecular nanomaterials, fluorescent coordination polymers (or metal-organic frameworks) and polysiloles. It is also introduced the use of organic semiconductors, such as phthalocyanine thin films and perylene diimide nanowires, to construct electronic sensors for trace explosive sensing.

Key words: explosive sensing, sensor, fluorescent compounds, trace detection

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