THE PHOTOCATALYTIC OXIDATION REACTION OF 1,4-BIPHENYLBUTADIENE ON CdS POWDER

doi:10.7517/j.issn.1674-0475.1988.04.36

Imaging Science and Photochemistry ›› 1988, Vol. 6 ›› Issue (4): 36-42.DOI: 10.7517/j.issn.1674-0475.1988.04.36

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THE PHOTOCATALYTIC OXIDATION REACTION OF 1,4-BIPHENYLBUTADIENE ON CdS POWDER

Gu KE-JUN, CAO YI, ZHANG BAO-WEN

Institute of Photographic Chemistry, Academic Sinica, Beijing

Received:1987-07-13 Revised:1988-02-04 Online:1988-11-20 Published:1988-11-20

Abstract

Abstract: The photocatalytic oxidation reaction of 1,4-biphenylbutadiene on CdS powder in acetoni-trile was studied and it was found that water, TiO₂, and sodium sulfite could promote the reaction. The possible mechanisms were discussed. Based on these investigations it is suggested that the methods to decrease the recombination of electron/hole pairs may increase the semiconductor photocatalytic yield.

Key words: semiconductor, photooxidation, electron transfer, 1,4-biphenylbutadiene, cadmium sulfide

Gu KE-JUN, CAO YI, ZHANG BAO-WEN. THE PHOTOCATALYTIC OXIDATION REACTION OF 1,4-BIPHENYLBUTADIENE ON CdS POWDER[J]. Imaging Science and Photochemistry, 1988, 6(4): 36-42.

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THE PHOTOCATALYTIC OXIDATION REACTION OF 1,4-BIPHENYLBUTADIENE ON CdS POWDER

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