THE PROPERTIES OF THE EXCITEDSTATE OF ASYMMETRIC PENTAAZADENTATE MACROCYCLIC CADMIUM AND INDIUM COMPLEXES

doi:10.7517/j.issn.1674-0475.1999.03.232

Abstract

Abstract: The properties of the excitedstate asymmetric pentaazadentate macrocyclic Cadmium and Indium complexes and the stability under the visible light are studied. The results show that the energies of the lowest excited triplet state of them are about 120 kJ/mol, the quantum yields of them for generating singlet oxygen are in the range of 0.6-0.9, the first-order molecular hypersusceptibility are about 10^-28 esu. Under the visible light, complex is stable, while complex has a less stability.

Key words: pentaazadentate metal complex, excited triplet state, the first-order hypersusceptibility, photobleaching

GUO Fengqi, , WANG Duoyuan. THE PROPERTIES OF THE EXCITEDSTATE OF ASYMMETRIC PENTAAZADENTATE MACROCYCLIC CADMIUM AND INDIUM COMPLEXES[J]. Imaging Science and Photochemistry, 1999, 17(3): 232-238.

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