THE EFFECT OF SUBSTITUENTS ON PHOTOLUMINESCENCE AND ELECTROLUMINESCENCE OF PYRAZOLINE DERIVATIVES

doi:10.7517/j.issn.1674-0475.2000.02.160

Imaging Science and Photochemistry ›› 2000, Vol. 18 ›› Issue (2): 160-164.DOI: 10.7517/j.issn.1674-0475.2000.02.160

Previous Articles Next Articles

THE EFFECT OF SUBSTITUENTS ON PHOTOLUMINESCENCE AND ELECTROLUMINESCENCE OF PYRAZOLINE DERIVATIVES

ZHANG Xiao-hong¹, JIANG Yong-cai¹, WU Shi-kang¹, GAO Zhi-qiang², LI Zhen-sheng(LEE C S)², LI Shu-tang(LEE S T)²

1. Institute of Photographic Chemistry, The Chinese Academy of Sciences, Beijing 100101, P. R. China;
2. Department of Physics and Materials Science, City University of Hong Kong, Kowloon, Hong Kong, P. R. China

Received:1999-06-02 Revised:1999-07-14 Online:2000-05-20 Published:2000-05-20

Abstract

Abstract: Two compounds of pyrazoline derivatives (PD1, PD2) with different substituents were synthesized. The effects of substituents on their photoluminescence and eletroluminescence were also studied. The results indicate that the fluorescence quantum yield of compound PD2 with methoxy group is higher than that of compound PD1 with the substituents of N,N-dimethlyamino group. But as dopants in organic electroluminescent devices, in which the structure ITO/TPD/TPBI:2%PD/TPBI/Mg:Ag was employed, the device with PD1 as dopant is more effective than that of PD2. In the device with PD1 as dopant, blue emission peak around 487 nm and a luminance of 1224 cd/m² is achieved at a current density of about 420 mA/cm². These results are discussed preliminarily.

Key words: pyrazoline derivatives, photoluminescence, electroluminescence

CLC Number:

O644

ZHANG Xiao-hong, JIANG Yong-cai, WU Shi-kang, GAO Zhi-qiang, LI Zhen-sheng(LEE C S), LI Shu-tang(LEE S T). THE EFFECT OF SUBSTITUENTS ON PHOTOLUMINESCENCE AND ELECTROLUMINESCENCE OF PYRAZOLINE DERIVATIVES[J]. Imaging Science and Photochemistry, 2000, 18(2): 160-164.

[1]	ZHU Wenqing, FAN Pan, LI Yang, ZHU Yumeng, ZHANG Jin. The Construction of Double Ligands Zn(Ⅱ)MOFs and Its Photoluminescence Properties [J]. Imaging Science and Photochemistry, 2020, 38(2): 159-166.
[2]	GAO Yu, LIU Guogang, SHI Jianbing, DONG Yuping. Synthesis of Aryl-substituted Pyrrole Derivatives with Tunable Emissive Behaviors [J]. Imaging Science and Photochemistry, 2019, 37(2): 93-106.
[3]	ZHU Dandan, XIA Jing, WANG Lei, LI Xuanze, MENG Xiangmin. Van der Waals Epitaxy and Photoluminescence of Two-Dimensional CdS Nanoplates [J]. Imaging Science and Photochemistry, 2016, 34(3): 273-280.
[4]	CUI Linsong, LIU Yuan, JIANG Zuoquan, LIAO Liangsheng. Synthesis of Bicarbazole-based Ambipolar Hosts and Application in Organic Light-emitting Devices [J]. Imaging Science and Photochemistry, 2014, 32(2): 141-149.
[5]	PAN Yue-li, LIU Hui-jun, WEI Wen-mei, ZHAO Zu-zhi. Synthesis and Electroluminescent Properties of 4-[4-((4-pyridyl)vinyl)styryl]-N,N- Dibutylbenzenamine [J]. Imaging Science and Photochemistry, 2013, 31(1): 33-41.
[6]	ZHANG Yuan, WU Liang-zhuan, YU Yuan, LI Yu-zhen, ZHI Jin-fang. Low-Temperature Synthesis of MoO₃ Nanobelts Aqueous Sols with High Photoluminescence Properties [J]. Imaging Science and Photochemistry, 2012, (5): 384-389.
[7]	JIN Yu-juan, LUO Yun-jun, LI Guo-ping, ZHANG Wan-lu. Application of PAMAM Dendrimers for Detecting Latent Fingerprints on Adhesive Tapes [J]. Imaging Science and Photochemistry, 2012, 30(3): 228-236.
[8]	JIN Yu-juan, LUO Yun-jun, LI Guo-ping, LI Jie. Application of Photoluminescent PAMAM Dendrimer in Fingerprint Detection [J]. Imaging Science and Photochemistry, 2011, 29(3): 194-202.
[9]	CHENG Chao, LIU Chun-yan. Microwave-Assisted Method for the Preparation of ZnO with Various Morphologies [J]. Imaging Science and Photochemistry, 2010, 28(4): 265-271.
[10]	JIN Yu-juan, LUO Yun-jun, LI Guo-ping, LI Jie, LU Wen-ting. Inherent Photoluminescence Properties of PAMAM Dendrimers and Application in Fingerprint Detection [J]. Imaging Science and Photochemistry, 2010, 28(2): 111-120.
[11]	LI Guo-ping, LUO Yun-jun. Preparation of Silver Nanoclusters within PAMAM Template under Ultraviolet Radiation and Their Photoluminescence Efficiency [J]. Imaging Science and Photochemistry, 2007, 25(4): 249-256.
[12]	LI Jie, HAN Li, XUE Min-zhao, ZHANG Qing, LIU Yan-gang. THE ENHANCEMENT EFFECT OF ULTRAVIOLET ON THE PHOTOSTIMULATED LUMINESCENCE IN BaFCl:Eu PHOSPHOR [J]. Imaging Science and Photochemistry, 2003, 21(1): 39-45.
[13]	JIANG Hua, LIU Yun-qi, WU Xia, ZHANG Yong-an, JIN Lin-pei . RESEARCH PROGRESS OF LOW MOLECULAR WEIGHT COMPLEX ELECTROLUMINESCENT MATERIALS [J]. Imaging Science and Photochemistry, 2002, 20(2): 149-158.
[14]	WANG Wei, XUE Min-zhao, LIU Yan-gang . SYNTHESES AND ELECTROLUMINESCENT PROPERTIES OF CYANO SUBSTITUTED N,N'-DIPHENLYSTYRYLANILINE [J]. Imaging Science and Photochemistry, 2001, 19(1): 9-12.
[15]	YIN Dong-dong, SHAN Lu, SHEN Yu quan. RECENT ADVANCEMENTS OF THE ELECTROLUMINESCENCE OF ORGANIC SMALL MOLECULES [J]. Imaging Science and Photochemistry, 2000, 18(3): 235-242.

THE EFFECT OF SUBSTITUENTS ON PHOTOLUMINESCENCE AND ELECTROLUMINESCENCE OF PYRAZOLINE DERIVATIVES

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments