Synthesis,Structure and Spectroscopic Properties of a Novel Copper (I) Complex with N-(6-Aminopyridine-2-yl)-9-Anthracenecarbonamide

doi:10.7517/j.issn.1674-0475.2008.01.60

Abstract

Abstract: Two new ligands,N-(6-aminopyridine-2-yl)-9-anthracenecarbonamide (L¹) and N,N’-(pyridine-2,6-yl)-bis (9-anthracenecarbonamide) (L²),and the novel copper (I) complex of L¹,[CuL¹ (PPh₃)₂] (BF₄) (1),have been synthesized and characterized.The crystal structures of L² and 1 were determined by single crystal Xray analysis,which show that the carbonyl (C=O) group in 1 is coordinated to the copper (I) ion through the oxygen atom.In addition,the spectroscopic properties of L¹ and 1 were studied at room temperature.

Key words: copper (I) complex, oxygen-bonding, crystal structure, spectroscopic properties

CLC Number:

ZHAO Xi-juan, CHEN Yong, CHI Shao-ming, FU Wen-fu. Synthesis,Structure and Spectroscopic Properties of a Novel Copper (I) Complex with N-(6-Aminopyridine-2-yl)-9-Anthracenecarbonamide[J]. Imaging Science and Photochemistry, 2008, 26(1): 60-67.

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