Imaging Science and Photochemistry ›› 2008, Vol. 26 ›› Issue (2): 169-173.DOI: 10.7517/j.issn.1674-0475.2008.02.169

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Study on the Preparation of Bisdodecylphenyliodonium Hexafluoroantimonate

LIU An-chang, XIAO Qing, WEN Yu-ping, TAN Zhen-you, LIU Fang   

  1. Wuhan Institute of Technology, Hubei Key Lab of Novel Reactor & Green Chemical Technology, Wuhan 430074, Hubei, P.R.China
  • Received:2007-06-01 Revised:2007-09-14 Online:2008-03-23 Published:2008-03-23

Abstract: Bisdodecylphenyliodonium hexafluoroantimonate salt was prepared via reaction of dodecyl benzene with KIO3 and H2SO4 in the presence of Ac2O to give the corresponding iodonium hydrogen sulfate, which was converted to the compound, via anion exchange with KSbF6. The structure of bisdodecylphenyliodonium hexafluoroantimonate salt was identified by UV, IR and H-NMR.

Key words: iodonium salt, doceyl benzene, potassium hexafluoroantimonate

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