Synthesis and Photosensitive of a Novel Cationic Photoinitiator [4-(2-Hydroxy-3-Butoxy-1-Propoxy) Phenyl] Phenyliodonium Hexafluoroantimonate

doi:10.7517/j.issn.1674-0475.2006.01.61

Abstract

Abstract: [4-(2-hydroxy-3-butoxy-1-propoxy)phenyl]phenyliodonium hexafluoroantimonate (BPI·SbF₆) was prepared by the reaction of 2-propanol,1-butoxy-3-phenoxy with [hydroxy(tosyloxy)io-do]benzene in approximately 79% yield. The later product BPI·SbF₆ was identified by infrared spectrum, UV spectrum, ¹HNMR spectrum and element analysis. The characteristic curves of pho-topolymerization system CY179/BPI·SbF₆ with different concentration of initiator BPI·SbF₆ and the characteristic post-curves of photopolymerization system CY179/BPI·SbF₆ with different UV curing time were studied.

Key words: cationic photoinitiator, iodonium salt, photosensitive, post-curing

CLC Number:

HUANG Qiang, XIONG Wan-bing, JIANG Hou-you, LIU Xiao-ya, CHEN Ming-qing, YANG Cheng. Synthesis and Photosensitive of a Novel Cationic Photoinitiator [4-(2-Hydroxy-3-Butoxy-1-Propoxy) Phenyl] Phenyliodonium Hexafluoroantimonate[J]. Imaging Science and Photochemistry, 2006, 24(1): 61-66.

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Synthesis and Photosensitive of a Novel Cationic Photoinitiator [4-(2-Hydroxy-3-Butoxy-1-Propoxy) Phenyl] Phenyliodonium Hexafluoroantimonate

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