Imaging Science and Photochemistry ›› 2013, Vol. 31 ›› Issue (1): 10-17.DOI: 10.7517/j.issn.1674-0475.2013.01.002

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Surface Photosensitive Modification of Calcium Carbonate and Application in UV-Curable Coating

LAI Jun-wei1, YANG Jian-wen2, LIU Xiao-xuan1   

  1. 1. Department of Macromecule, Faculty of Materials and Energy, Guangdong University of Technology, Guangzhou 511400,Guangdong, P.R.China;
    2. Institute of Polymer Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, Guangdong, P.R.China
  • Received:2012-04-19 Revised:2012-06-20 Online:2013-01-15 Published:2013-01-15

Abstract: A photosensitive resin fills S-2-E, based on succinic acid anhydride(SAA)、2-hydroxy-4-(2-hydr-oxyethoxy) -2-methylpropiophenone (D2959) and epoxidized oleic acid (EOA),was synthesized and used for modification of CaCO3. Compared with the CaCO3 modified by OA, the characterization of CaCO3 modified by S-2-E、the optical activity of S-2-E-CaCO3 and its effects on the properties of UV curing coating were studied by oil absorption value test、DPC、DMA and SEM.The results show that there are not so much differences between S-2-E and OA in modification of CaCO3. And the CaCO3 which become photosensitive after being modified by S-2-E, can cure with UV coating and make the properties of UV curing film better in hardness and water resistance.

Key words: photosensitive, fatty acid, surface modification, CaCO3, UV curable coating

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