Imaging Science and Photochemistry ›› 2012, Vol. 30 ›› Issue (6): 447-455.DOI: 10.7517/j.issn.1674-0475.2012.06.447

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Synthesis and Properties of Hollow Glass Spheres/ TiO2 Composite

YUAN Jing1,2, AN Zhen-guo1, ZHANG Jing-jie1, LI Bing1   

  1. 1. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P.R. China;
    2. Graduate University of Chinese Academy of Sciences, Beijing 100049,P.R.China
  • Received:2012-04-27 Revised:2012-05-29 Online:2012-11-15 Published:2012-11-15

Abstract: Anatase TiO2 shells deposited on hollow glass microspheres with tunable morphologies were successfully prepared through a controllable chemical precipitation method with urea as the precipitator, and thus glass/TiO2 core/shell composite hollow microspheres were fabricated. The phase structure, morphology, particle size, shell thickness, and the chemical compositions, of the composite microspheres were characterized by X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectrum and Raman spectra. The probable growth mechanism of the TiO2 shells and the formation process of the core/shell composite microspheres were proposed.

Key words: hollow glass microspheres, TiO2, core/shell, urea

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