Highly Selective Fluorescent Sensing of Fe3+ by a New Anthraquinone Derivative 1,8-Bis(2-hydroxyethylimino) Anthraquinone

doi:10.7517/j.issn.1674-0475.2013.02.006

Abstract

Abstract: A new fluorionophore, which is composed of anthraquinone and a hydroxyl ethanol-amine receptor, has been synthesized. Effect of metal ions on the fluorescence of the ionophore was investigated. The results show that the ionophore displays a highly selective and sensitive response of fluorescence quenching toward Fe³⁺ in neutral buffer aqueous solution. There is a good linear relationship between the fluorescence intensity and Fe³⁺ concentration in the range of 4.0?10^-5-3.0?10^-4 mol/L. The detection limit is 3.8?10^-7 mol/L.

Key words: anthraquinone, fluorescence, probe, iron ions, sensing

CLC Number:

SHI Li-li, SUN Huan-he, SHANG Zhuo-bin, WANG Yu. Highly Selective Fluorescent Sensing of Fe³⁺ by a New Anthraquinone Derivative 1,8-Bis(2-hydroxyethylimino) Anthraquinone[J]. Imaging Science and Photochemistry, 2013, 31(2): 132-139.

References

[1] Aksuner N, Henden E, Yilmaz I, Cukurovali A. Recent developments in fluorescent sensors for trace-level determination of toxic-metal ions[J]. Trends Anal. Chem., 2012,32: 113-132.
[2] Wang J, Ha C S. Fluorescent logic operations based on azobenzene-containing compounds[J]. Sens. and Actuators B, 2010, 146(1): 373-380.
[3] 黄文君, 吴文辉. 荧光化学剂量计在汞离子检测中的应用[J].影像科学与光化学, 2011, 29(5): 321-335. Huang W J, Wu W H. Fluorescent chemodosimeters for mercury(Ⅱ) ions detection[J].Imaging Science and Photochemistry, 2011, 29(5): 321-335.
[4] Fan J L, Liu X J, Hu M M, Zhu H, Song F L, Peng X J. Development of an oxidative dehydrogenation-based fluorescent probe for Cu²⁺ and its biological imaging in living cells[J]. Anal. Chim. Acta., 2012, 735:107-113.
[5] Feng L H, Chen Z B, Wang D S.Selective sensing of Fe³⁺ based on fluorescence quenching by 2,6-bis(benzoxazolyl)pyridine with β-cyclodextrin in neutral aqueous solution[J]. Spectrochim. Acta A, 2007, 66(3): 599-603.
[6] Li Z X, Zhang L F, Li X Y, et al. A fluorescent color/intensity changed chemosensor for Fe³⁺by photo-induced electron transfer (PET) inhibition of fluoranthene derivative[J]. Dyes Pigment, 2012, 94(1): 60-65.
[7] Lee D Y, Singh N, Jang D O. Fine tuning of a solvatochromic fluorophore for selective determination of Fe³⁺: a new type of benzimidazole-based anthracene-coupled receptor[J]. Tetrahedron Lett., 2011, 52(12): 1368-1371.
[8] Zhang L Z, Wang J Y, Fan J L, et al. A highly selective, fluorescent chemosensor for bioimaging of Fe³⁺[J]. Biorg. Med. Chem. Lett., 2011, 21(18): 5413-5416.
[9] Dong L, Wu C, Zeng X, et al. The synthesis of a rhodamine B schiff-base chemosensor and recognition properties for Fe³⁺ in neutral ethanol aqueous solution[J]. Sens. Actuators B, 2010, 145(1): 433-437.
[10] Lohani C R, Kim J M, Lee K H. Facile synthesis of anthracene-appended amino acids as highly selective and sensitive fluorescent Fe³⁺ ion sensors[J]. Bioorg. Med.Chem.Lett., 2009, 19(21): 6069-6073.
[11] She M Y, Yang Z, Yin B, et al. A novel rhodamine-based fluorescent and colorimetric "off-on" chemosensor and investigation of the recognizing behavior towards Fe³⁺[J]. Dyes Pigments, 2012, 92(3):1337-1343.
[12] Salinas F, Muñoz de la Peña A, Murillo J A. Spectrofluorimetric determination of Ga(III) with 1-hydroxy-2-carboxyanthraquinone[J]. Microchimica Acta,1984, 84: 79-86.
[13] Tereza C R, dos Santos, Ricardo Q, Aucélio R C. Campos. Spectrofluorimetric method for the determination of aluminum with alizarin red PS[J]. Microchimica Acta, 2003, 142(1-2): 63-66.
[14] Yang H, Zhou Z G, Li F Y, Yi T, Huang C H. New Hg²⁺ and Ag⁺selective colorimetric sensor based on thiourea subunits[J]. Inorganic Chem. Commun., 2007, 10(10): 1136-1139.
[15] Han D Y, Kim J M, Kim J. ESIPT-based anthraquinonylcalix
[4] crown chemosensor for In³⁺[J].Tetrahedron Lett., 2010, 51(15): 1947-1951.
[16] Wang Y, Wang L, Shi L L, Shang Z B, Zhang Z, Jin W J. Colorimetric and fluorescent sensing of Cu²⁺ in aqueous β-cyclodextrin solution using 1,8-dihydroxyanthraquinone with the assistance of ammonia[J]. Talanta, 2012, 94(30): 172-177.
[17] Lopes J G S, Santos P S. The SERS spectrum of 1,2-diaminoanthraquinone studied on silver colloid[J]. J. Mol. Struct., 2005, 744-747:75-78.
[18] Barra M, Bohne C, Scaiano J C. Effect of cyclodextrin complexation on the photochemistry of xanthone absolute measurement of the kinetics for triplet-state exit[J]. J. Am. Chem. Soc.,1990,112(22):8075-8079.

Highly Selective Fluorescent Sensing of Fe³⁺ by a New Anthraquinone Derivative 1,8-Bis(2-hydroxyethylimino) Anthraquinone

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	HUANG Haiqing, XIAO Saijin, YANG Guangzhaoyao, ZHAO Jiahui. Label-free and Rapid Detection of ATP Based on Molybdenum Oxide Quantum Dots [J]. Imaging Science and Photochemistry, 2020, 38(6): 950-955.
[2]	MA Yihua, CHEN Lin, YANG Yongzhen, YU Shiping, SU Xiuqin. Progress in Research on the Preparation of Gadolinium-doped Carbon Dots and Their Bimodal Imaging [J]. Imaging Science and Photochemistry, 2020, 38(5): 763-770.
[3]	LI Xiaoning, LI Meng. New Modified Attapulgite for Arsenic Ions Adsorption by Atomic Fluorescence Spectrometry [J]. Imaging Science and Photochemistry, 2019, 37(2): 127-135.
[4]	LIU Xiaoqin, HUANG Yuanyuan, GAO Jianfeng, CHEN Yuzhe, TONG Zhenhe(TUNG Chen-ho), WU Lizhu. Construction of Two-photon Excited Supramolecular Polymer Nanoparticles and Their Bioimaging Application [J]. Imaging Science and Photochemistry, 2019, 37(2): 136-145.
[5]	JIANG Wei, FANG Huiying, HE Xiaojing. Current Status and Prospects of Magnetic Resonance/Optical Bimodal Molecular Probes [J]. Imaging Science and Photochemistry, 2019, 37(2): 156-162.
[6]	MU Yalin, CHEN Xiaomei, LIU Xuan, LIU Gang. Recent Advances in Molecular Imaging of Atherosclerotic Plaque [J]. Imaging Science and Photochemistry, 2019, 37(1): 7-17.
[7]	LI Yali, GUO Jing, SONG Juan, PIAO Xiangmin, XU Xiaolong, WANG Yingping. Synthesis, Properties and Application of Fluorescence Carbon Quantum Dots in Bioimaging [J]. Imaging Science and Photochemistry, 2019, 37(1): 46-56.
[8]	WANG Kaixia, XU Wei, HE Qingguo, CHENG Jiangong. Design, Synthesis and Properties of Highly Selective Fluorescent Probe for Methylamphetamine Vapor Detection [J]. Imaging Science and Photochemistry, 2018, 36(6): 478-488.
[9]	ZHANG Yucai, CHEN Hongman, DENG Renpan, YAN Yin, MIAO Zhiwei. Synthesis and Spectrometric Detection of Lindqvist Acid and Aniline Hybrid Solid [J]. Imaging Science and Photochemistry, 2018, 36(6): 514-521.
[10]	CHANG Shunzhou, XIANG Kaiqiang, MING Wei, ZHANG Zhizhong, TIAN Baozhu, ZHANG Jinlong. Synthesis and Properties of a pH Fluorescent Probe Based on PET Mechanism [J]. Imaging Science and Photochemistry, 2018, 36(5): 425-433.
[11]	WANG Juanjuan, WEI Xuehong. The Effect of Temperature on Imaging of Confocal Laser Scanning Microscope [J]. Imaging Science and Photochemistry, 2018, 36(5): 443-452.
[12]	LI Junfen, LI Pengxia, ZHANG Lin, DONG Chuan. Study on Fluorescence Spectral Behavior of 1,5-Diphenyl-3-biphenylyl-2-pyrazoline [J]. Imaging Science and Photochemistry, 2018, 36(4): 299-305.
[13]	XIE Xiange, XIA Fangyuan, HUANG Suqin, PENG Xiaowei, FU Yan, WANG Xiaomei, TAO Xutang. Rapid Fluorescence Detection of Glutamic Acid and Aspartic Acid by Spirocyclic Rhodamine 6G Hydrazide [J]. Imaging Science and Photochemistry, 2018, 36(4): 315-323.
[14]	GAO Wenyu, ZHOU Yihua, TENG Xiao, WU Lihui, CAO Sheng. Research Progress of Paper-based Fluorescent Sensor on Carbon Quantum Dots for Visual Detection [J]. Imaging Science and Photochemistry, 2018, 36(4): 367-379.
[15]	MA Yaguang, ZHANG Yutao, MA Yiyu, GUO Zhiqian, ZHU Weihong. Near-infrared Cyanine-based Fluorescent Probe for Cysteine with High Selectivity [J]. Imaging Science and Photochemistry, 2018, 36(3): 236-244.