Imaging Science and Photochemistry ›› 2013, Vol. 31 ›› Issue (2): 150-156.DOI: 10.7517/j.issn.1674-0475.2013.02.008

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Research on the Optoelectronic Properties of SnS Thin Films Prepared by Two-Stage Process

JI Qiang, SHEN Hong-lie, JIANG Feng, WANG Wei, ZENG You-hong   

  1. College of Materials Science & Technology, Nanjing University of Aeronautics & Astronautics, Nanjing 210016, Jiangsu, P.R. China
  • Received:2012-11-19 Revised:2012-12-27 Online:2013-03-15 Published:2013-03-15

Abstract: SnS thin films were prepared by two-stage process. Sn precursor layers were deposited on glass substrates by sputtering and followed by sulfurization of the metallic tin precursor layers at 220℃ in a furnace for 60 min. The characterization results of microstructures, composition and optical and electrical properties show that the SnS film presents p-type conductivity and has a (040) preferred grain orientation; SnS film has an orthorhombic structure, and the surface is uniform and density with the ratio of Sn to S close to 1. It is found that the film shows a high optical absorption coefficient of 5×104 cm-1 and persistent photoconductivity effect. It has a direct energy band gap of 1.23 eV. The prepared SnS film is useful as an absorption layer of solar cells and for fabrication of photo-sensitive device.

Key words: SnS films, two-stage process, solar cell, photoelectric properties

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