CoⅡ/ZnⅡ Tetrahedron for Selectively Luminescent Recognition of ATP

doi:10.7517/j.issn.1674-0475.2014.01.098

Abstract

Abstract:

Because the unique spatial confinement, easy assembly and multi-functional features of cage-like metal-organic complexes, there is an important advantage for the selective recognition of small biological molecules. Here we reported a organic ligand L₂ which has a high degree of symmetry, and got two zinc/cobalt-based cage-like complexes Zn-L₂/Co-L₂ through complexation with transition metal ions Zn^Ⅱ / Co^Ⅱ. These two cage-like complexes Zn-L₂ and Co-L₂ are tetrahedron on geometry which have with optical activity. The tetrahedral complexes Zn-L₂/Co-L₂ are cationic cage-like complexes to studied the recognition for biological small molecules nucleotide. By means of fluorescence to study the interaction between nucleotide and tetrahedral complexes Zn-L₂/Co-L₂, we found that there were three aniline significantly enhanced fluorescence signal when only adenosine triphosphate molecule ATP was added. The tetrahedral complexes Zn-L₂/Co-L₂ are the selective recognition of ATP.

Key words: nucleotides, identification, fluorescence, cage-like complexes

JIAO Yang, YAN Yuyu, HE Cheng, DUAN Chunying. Co^Ⅱ/Zn^Ⅱ Tetrahedron for Selectively Luminescent Recognition of ATP[J]. Imaging Science and Photochemistry, 2014, 32(1): 98-105.

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Co^Ⅱ/Zn^Ⅱ Tetrahedron for Selectively Luminescent Recognition of ATP

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