Celluloses Grafted with Fluorene-Benzene and Carbazole-Benzene Copolymer and Its Application to the Detection of Nitro-Aromatic

doi:10.7517/j.issn.1674-0475.2012.04.251

Abstract

Abstract: Sensing celluloses were prepared from fluorene-benzene and carbazole-benzene copolymer grafted to chemical modification of cellulose paper by Suzuki coupling reaction for the detection of nitro-aromatic explosives. Fluorescence quenching studies have shown that, the two kinds of sensor have higher fluorescence quenching efficiency than the thin film state, due to the modified cellulose have a high specific surface area and porosity structure, which are beneficial for the rapid diffusion of DNT vapor molecules. In addition, the two sensing cellulose have shown good fluorescence quenching efficiency after four quenching-recovery circles, which indicates that the sensing cellulose has a good fluorescence quenching reversibility and stability.

Key words: nitro-aromatics, chains aggregation, grafting, fluorescence quenching

CLC Number:

LENG Hong-fei, WU Wen-hui. Celluloses Grafted with Fluorene-Benzene and Carbazole-Benzene Copolymer and Its Application to the Detection of Nitro-Aromatic[J]. Imaging Science and Photochemistry, 2012, 30(4): 251-259.

References

[1] Thomas S W, Joly G D, Swager T M. Chemical sensors based on amplifying fluorescent conjugated polymers [J]. Chemical Reviews, 2007, 107(4): 1339-1386.
[2] Thomas Iii S W, Amara J P, Bjork R E. Amplifying fluorescent polymer sensors for the explosives taggant 2,3-dimethyl-2,3-dinitrobutane (DMNB) [J]. Chemical Communications, 2005, 36: 4572-4574.
[3] Leng H F, Wu W H. Synthesis of a novel fluorene-based conjugated polymer with pendent bulky caged adamantane moieties and its application in the detection of trace DNT explosives[J]. Reactive and Functional Polymers, 2012, 72(3): 206-211.
[4] 任韦华,刘峰,胡军,刘洪来. 含三苯胺单元的超支化共轭聚合物的合成、表征及应用[J]. 影像科学与光化学, 2008, 26(4): 318-326. Ren W H, Liu F, Hu J, et al. Synthesis, characterization and application of hyperbranched conjugated polymer containing triphenylamine unit[J]. Imaging Science and Photochemistry, 2008, 26(4): 318-326.
[5] Li H, Wang J, Pan Z. Amplifying fluorescence sensing based on inverse opal photonic crystal toward trace TNT detection [J]. Journal of Materials Chemistry, 2011, 21(6): 1730-1735.
[6] Long Y, Chen H, Yang Y. Electrospun nanofibrous film doped with a conjugated polymer for DNT fluorescence sensor [J]. Macromolecules, 2009, 42(17): 6501-6509.
[7] 赵前进,吴文辉. 聚芴类蓝光材料抑制链簇集及绿光发射的新进展 [J]. 影像科学与光化学, 2008, 26(4): 305-317. Zhao Q J, Wu W H. Recent progress in fluorene-based luminescent materials: towards suppression of aggregates and green emission[J]. Imaging Science and Photochemistry, 2008, 26(4): 305-317.
[8] Peterson J J, Willgert M, Hansson S. Surface-grafted conjugated polymers for hybrid cellulose materials [J]. Journal of Polymer Science Part A: Polymer Chemistry, 2011, 49(14): 3004-3013.
[9] van den Berg O, Schroeter M, Capadona J R. Nanocomposites based on cellulose whiskers and (semi)conducting conjugated polymers [J]. Journal of Materials Chemistry, 2007, 17(26): 2746-2753.
[10] Capadona J R, Van Den Berg O, Capadona L A. A versatile approach for the processing of polymer nanocomposites with self-assembled nanofibre templates [J]. Nature Nanotechnology, 2007, 2(12): 765-769.
[11] Peng C Q, Thio Y S, Gerhardt R A. Conductive paper fabricated by layer-by-layer assembly of polyelectrolytes and ito nanoparticles [J]. Nanotechnology, 2008, 19(50): 505603.
[12] Mahadeva S K, Yun S, Kim J. Flexible humidity and temperature sensor based on cellulose-polypyrrole nanocomposite [J]. Sensors and Actuators A: Physical, 2011, 165(2): 194-199.

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