Imaging Science and Photochemistry ›› 2007, Vol. 25 ›› Issue (6): 452-458.DOI: 10.7517/j.issn.1674-0475.2007.06.452

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Synthesis and Properties of a Novel Cross-Linked Poled Polymer

ZHAO Wen-ke1,2, WANG Zhi-peng1,2, CHEN Zhuo1,2, XU Guang-ming1, HAN Xu1, QIU Ling1, ZHEN Zhen1, LIU Xin-hou1   

  1. 1. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100080, P. R. China;
    2. Graduate University of the Chinese Academy of Sciences, Beijing 100049, P. R. China
  • Received:2007-03-22 Revised:2007-05-14 Online:2007-11-23 Published:2007-11-23

Abstract: A novel NLO side-chain polymer was synthesized by attaching the NLO chromophore to a hydroxy-containing polymer BPAN which possesses excellent processability.The new polymer inherited the good performance of BPAN such as good film formation property and cross-linkability,etc.Cross-linked poled polymer with even higher content of NLO chromophore was obtained by taking the same kind of NCO-containing chromophore as cross-linking agent.The electro-optic coefficient of the poled polymer was 6.7 pm/V,which was measured by ATR method at 1315 nm.

Key words: poled polymer, cross-linking, NLO, EO, Attenuated Total Reflection(ATR)

CLC Number: