影像科学与光化学 ›› 1989, Vol. 7 ›› Issue (2): 42-46.DOI: 10.7517/j.issn.1674-0475.1989.02.42

• 研究论文 • 上一篇    下一篇

胶体颗粒大小的分布——Ⅱ.物理显影中胶体催化剂颗粒大小的分布函数

常青, 刘玉臣, 夏培杰   

  1. 中科院感光化学研究所, 北京 100012
  • 收稿日期:1988-01-05 修回日期:1988-08-27 出版日期:1989-05-20 发布日期:1989-05-20
  • 基金资助:
    国家自然科学基金

DISTRIBUTION FUNCTION FOR COLLOIDAL PARTICLES Ⅱ. THE DISTRIBUTION FUNCTION FOR THE COLLOIDS USED IN PHYSICAL DEVELOPMENT

CHANG QING, LIU YU-CHEN, XIA PEI-JIE   

  1. Institute of Photographic Chemistry, Academia Sinica, Beijing 100012, P. R. China
  • Received:1988-01-05 Revised:1988-08-27 Online:1989-05-20 Published:1989-05-20

摘要: 本文用对数正态分布对物理显影中常用的Au、Ag及Ag2s胶体催化剂的颗粒大小的实验分布进行了拟合。理论分布与实验分布的比较表明:本实验条件下制备的十二组胶体溶液其颗粒大小都服从了对数正态分布,并且不依赖于胶体的组成、大小及制备方法。因此,它们很可能遵从了同样的成核成长规律。

关键词: 胶体催化, 化学动力学, 计算机模拟, 颗粒大小分布

Abstract: In this paper the experiment distributions for Au, Ag, and Ag2S colloids used in physical development were fitted through logarithmic normal distribution. It is showed through the comparison of the theory distributions with the experiment distributions that the all distributions for these colloidal particles could be well described by the Logarithmic Normal Distribution, which might not depend on the composition of the colloids, the size, and the preparation method under these experiment conditions. Therefore, these colloids might follow the same-rules of nucleation and growth.

Key words: colloidal catalysis, chemical kinetics, computer simulation, grain size distribution