影像科学与光化学 ›› 1992, Vol. 10 ›› Issue (4): 319-325.DOI: 10.7517/j.issn.1674-0475.1992.04.319

• 研究论文 • 上一篇    下一篇

1,3,5-三芳基-2-吡唑啉化合物光物理行为的研究

阎正林, 吴世康   

  1. 中国科学院感光化学研究所, 北京 100101
  • 收稿日期:1991-07-02 修回日期:1991-12-03 出版日期:1992-11-20 发布日期:1992-11-20
  • 通讯作者: 吴世康
  • 基金资助:
    863高技术专家委员会资助项目

A STUDY ON THE PHOTOPHYSICAL BEHAVIOR OF 1,3,5-TRIARYL-2-PYRAZOLINE COMPOUNDS

YAN ZHENG-LIN, WU SHI-KANG   

  1. Institute of Photographic Chemistry, Academia Sinica, Beijing 100101, P. R. China
  • Received:1991-07-02 Revised:1991-12-03 Online:1992-11-20 Published:1992-11-20

摘要: 合成了一组带不同取代基的三芳基吡唑啉化合物,对它们在不同极性溶剂中的光物理行为(如荧光量子产率,荧光寿命等)进行了测定指出:这类化合物在光的激发下除存在有分子内共轭条件下的电荷转移行为外,还存在着分子内非共轭条件下的电子转移,本工作还以三芳基吡唑啉化合物为猝灭剂对氧鎓盐的荧光猝灭能力进行了研究,并对所得结果作了讨论。

关键词: 三芳基-2-吡唑啉化合物, 氧鎓盐化合物, 分子内电荷转移, 荧光量子产率, 荧光寿命

Abstract: In this work, a series of triaryl pyrazoline compounds with different substituted groups have been synthesized.The photophysical behavior of these compounds including quantum yields and lifetime of fluorescence in solvents with different polarities has also been measured.Results indicated that except for the intramolecular conjugated charge transfer, there is intramolecular non-conjugated electron transfer existing in the excited state of these compounds.The fluorescence quenching of pyrylium salt has also been studied.The results obtained were discussed briefly.

Key words: triaryl-2-pyrazoline compound.pyrylium salt, intramolecular charge transfer, quantum yield and lifetime of fluorescence